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Effect of the Cation Part of Imidazolium Ionic Liquids on Synthesis of Palladium Particle  

Kim, Chang Soo (Clean Energy Research Center, Korea Institute of Science & Technology)
Ahn, Byoung Sung (Clean Energy Research Center, Korea Institute of Science & Technology)
Tae, Hyunman (Department of Chemical Engineering, Seoul National University of Science & Technology)
Jeon, Seung Hye (Department of Chemical Engineering, Seoul National University of Science & Technology)
Yoo, Kye Sang (Department of Chemical Engineering, Seoul National University of Science & Technology)
Publication Information
Applied Chemistry for Engineering / v.23, no.5, 2012 , pp. 510-513 More about this Journal
Abstract
Palladium particles were synthesized by conventional chemical reduction method with ionic liquids. The size and shape of palladium particles were significantly affected by the cation parts of ionic liquids. This is mainly attributed to the different stabilities of the ionic liquid structure formed by the physical bond between the cation parts. Among ionic liquids with [$BF_{4}$] as an anion part, the hexyl substituent in the cation parts was more effective to synthesize palladium particles with the smaller size and more uniform shape.
Keywords
palladium particle; imidazolium ionic liquids; cation effect;
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