• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.05a
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• pp.155-158
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• 2009

This study was investigated to know the thermal decomposition and measure the reaction time and temperature by EIDS cook-off test for the propellant ingredients and 2 kinds of HTPE propellants. The thermal analysis of the propellant ingredients used in this study showed that the thermal stability of these materials decreases in the following order : AP > HTPE > AN > BuNENA. In addition, propellant HTPE 002 containing AN showed that an endothermic process at around $125^{\circ}C$ corresponding to the solid`solid phase change($II{\rightarrow}I$) of AN was followed by the exothermic process due to decomposition of BuNENA/AN until $200^{\circ}C$. HTPE 001 and HTPE 001 reacted at around $250^{\circ}C$ and $152^{\circ}C$ each other, and the temperature of them sharply increased at $115^{\circ}C$ from EIDS slow cook-off tests.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.6
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• pp.31-37
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• 2010

This study was carried out to investigate the thermal decomposition and execute EIDS slow cook-off test for the propellant ingredients and 2 kinds of HTPE propellants. The thermal analysis of the propellant ingredients used in this study showed that the thermal stability of these materials decreases in the following order : AP > HTPE > AN > BuNENA. In addition, propellant HTPE 002 containing AN showed that an endothermic process at around $125^{\circ}C$ corresponding to the solid phase change(II$\rightarrow$I) of AN was followed by the exothermic process of BuNENA/AN mixture up to $200^{\circ}C$. In EIDS slow cook-off tests, HTPE 001 and HTPE 002 reacted at around $250^{\circ}C$ and $152^{\circ}C$ respectively, and both of them showed sudden temperature increase curves at $115^{\circ}C$. The critical temperatures, $T_c$, of thermal explosion for the propellants HTPE 001 and HTPE 002, were obtained from both the non-isothermal curves at various heating rates and Semenov's thermal explosion theory. Kissinger's method that was used to calculate $T_c$ was also employed to obtain the activation energies for thermal decompositions.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.352-358
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• 2011

This paper describes on the study of mitigation technique in which a pyrosensor is automatically sensing the rate of risk of fire or explosion of solid rocket motor exposed to an unexpected fire and makes the rocket motor burn itself safely. SCO test was carried out with a rocket motor loaded with HTPB propellant, in which a thermal pyrosensor igniter was installed. The rocket motor in SCO test was located in an oven at $50^{\circ}C$ for 7 hours. The temperature was regulated to be elevated at the rate of $3.3^{\circ}C$ per hour. Results showed Type V(Burning) reaction in this SCO test.

• Journal of the Korean Society of Propulsion Engineers
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• v.16 no.6
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• pp.85-91
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• 2012

This paper describes the results of study on reaction of insensitive igniter in which a pyrosensor is automatically sensing the rate of risk of fire or explosion of solid rocket motor exposed to an unexpected fire and makes the rocket motor burn itself safely. The Slow Cook Off(SCO) test following the regulation of MIL-STD-2105D was carried out with a rocket motor loaded with HTPB propellant, in which a thermal pyrosensor igniter was installed. The auto-ignition temperature measured was approximately $140^{\circ}C$ and it corresponded to Type V(Burning) reaction in SCO test, while the temperature by Kissinger equation was calculated to be $165.5^{\circ}C$.

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.2
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• pp.46-55
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• 2016

The kinetic analysis of a heavily aluminized cyclotrimethylene-trinitramine(RDX) is conducted using differential scanning calorimetry(DSC), and the Friedman isoconversional method is applied to the DSC experimental data. The pre-exponential factor and activation energy are extracted as a function of the product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the complex response of energetic materials; instead, a set of multiple Arrhenius factors is constructed based on the local progress of the exothermic reaction. The resulting reaction kinetic scheme is applied to two thermal decomposition tests for validating the reactive flow response of a heavily aluminized RDX. The results support applicability of the present model to practical thermal explosion systems.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.05a
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• pp.77-80
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• 2006

Insensitive Munitions(IM) of solid propulsion system are defined as munitions that fulfil the performance and operational requirements, but will minimize the violence of a reaction when subjected to inadvertant stimuli. It should be clear that the reaction violence of rocket motor subjected to thermal stimuli can be mitigated by reducing confinement prior to propellant reaction. Devices designed to do this by venting the rocket motor case are commonly referred to as mitigation devices. The objective of this paper is to introduce the technical information related to the pyrotechnic mitigation devices for insensitive munition of solid rocket motor.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.307-310
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• 2005

This Study was performed for the Insensitive Munition Technology Program contract between Roxel and ADD. Two Slow Coo-off(SCO) tests and One fast Cook-off(FCO) test have been made based on MIL-STD-2105C. SCO and FCO tests were made in order to evaluate the behaviour of the hybrid rocker motor with insensitive igniter and two types of propellants of which burning rates were 9.8 mm/s and 21.2 mm/s @ 7 MPa each other. The Reaction level of the two rocker motors to SCO test was classified as type IV and that of FCO test was classified as type V.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.129-132
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• 2010

The objective of IM rocket motor is to minimize the probability of inadvertent initiation and severity of subsequent collateral damage, hence it is important to define personnel and equipment survivability to a rocket motor accident. The violent response probability associated with shock, impact and thermal effects be minimized. And during production, transportation/storage and stack of rocket motor, sympathetic detonation, giving severe effects of the propagation of adverse reaction on its surroundings, be reduced. Hence Reaction type also based on reaction results of the overpressure, fragment throw and heat flux.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.351-355
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• 2011

In this study, 2 kinds of HTPE insensitive propellants composed of HTPE/BuNENA binder, AP, AN and Al were investigated for combustion characteristics, ignition delay time, sensitivity and insensitive properties compared with HTPB propellant. HTPE propellant showed almost same sensitivity results as HTPB propellant, showed 2~3 times higher value than the value of HTPB propellant, ignition delay time respectively, and met the standard criteria, while HTPB propellant failed.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.1
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• pp.33-41
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• 2015

The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.