• Journal of Conservation Science
• /
• v.25 no.1
• /
• pp.25-38
• /
• 2009

The Gyeongju Seokbinggo (Treasure No. 66) is an ice-storing stone warehouse, consisting mainly of alkaligranite which shows milky white color and medium-grained textures with drusy cavities. As results of deterioration assessment, the deterioration rates were determined as crack (12.5%), disjoining (6.7%), breaking-out (25.1%), exfoliation (20.9%), efflorescence (6.5%), brown discoloration (9.8%), darkgray discoloration (2.0%) and biological discoloration (36.5%). Comprehensive physical deterioration rate and discoloration rate were calculated as 43.7% and 68.7%, respectively, that indicates the Seokbinggo has been severely weathered. Indoor relative humidity was above 90% except in winter season. Indoor microclimate was hardly fluctuating although indoor microclimate was dependent on the outdoor climate. The main cause of deterioration was high relative humidity and a long time of wetness due to penetration of rain, underground water and condensation. It was identified that the water brought out biological discoloration, dissolution of minerals, structural movement and efflorescence, and the dust from the ground soil in front of the entrance accelerated brown and dark gray discoloration on the stone surface.

• Korean Journal of Mineralogy and Petrology
• /
• v.34 no.3
• /
• pp.157-167
• /
• 2021

Lead (Pb) is one of the key trace elements, exhibiting a peculiar partitioning behavior into silicate melts in contact with minerals. Partitioning behaviors of Pb between silicate mineral and melt have been known to depend on melt composition and thus, the atomic structures of corresponding silicate liquids. Despite the importance, detailed structural studies of Pb-bearing silicate melts are still lacking due to experimental difficulties. Here, we explored the effect of lead content on the atomic structures, particularly the evolution of silicate networks in Pb-bearing sodium metasilicate ([(PbO)_x(Na₂O)_1-x]·SiO₂) glasses as a model system for trace metal bearing natural silicate melts, using ²⁹Si solid-state nuclear magnetic resonance (NMR) spectroscopy. As the PbO content increases, the ²⁹Si peak widths increase, and the maximum peak positions shift from -76.2, -77.8, -80.3, -81.5, -84.6, to -87.7 ppm with increasing PbO contents of 0, 0.25, 0.5, 0.67, 0.86, and 1, respectively. The ²⁹Si MAS NMR spectra for the glasses were simulated with Gaussian functions for Qⁿ species (SiO₄ tetrahedra with n BOs) for providing quantitative resolution. The simulation results reveal the evolution of each Qⁿ species with varying PbO content. Na-endmember Na₂SiO₃ glass consists of predominant Q² species together with equal proportions of Q¹ and Q³. As Pb replaces Na, the fraction of Q² species tends to decrease, while those for Q¹ and Q³ species increase indicating an increase in disproportionation among Qⁿ species. Simulation results on the ²⁹Si NMR spectrum showed increases in structural disorder and chemical disorder as evidenced by an increase in disproportionation factor with an increase in average cation field strengths of the network modifying cations. Changes in the topological and configurational disorder of the model silicate melt by Pb imply an intrinsic origin of macroscopic properties such as element partitioning behavior.

• The Journal of the Petrological Society of Korea
• /
• v.14 no.1
• /
• pp.1-11
• /
• 2005

Sphene U-Pb ages were determined for the granodiorites from Gimcheon, Seongju and Anui areas of the middle Yeongnam massif. The determined ages were in the narrow range of 195.7±2.4∼200.8±1.9(2σ) Ma that are approximately coincident with the boundary between Triassic and Jurassic. Even though the studed plutons are aerially separated, they reveal quite similar major element compositions and almost identical ages, suggesting that they were generated from the similar source materials under the identical tectonic environment and thus they can be considered to form a single suite. Considering the age and spatial distribution of the Triassic to Lower Jurassic plutons of the Yeongnam Massif and Okcheon Belt, it seems that there were episodic changes in tectonic environment in both areas with relatively short intervals. In general, the compressive environment of active continental margin was prevailed. However, the tensional environment of within-plate was also appeared several times intermittently. In conclusion, Yeongnam Massif and Okcheon Belt experienced distinct tectonic environments during Triassic to Lower Jurassic, providing important clue to reveal the crustal evolution of the Korean Peninsula.

• The Journal of the Petrological Society of Korea
• /
• v.24 no.3
• /
• pp.153-164
• /
• 2015

Jurassic granite from Geochang was analysed with respect to the characteristics of the rock cleavage. we have mainly discussed the structual anisotropy formed by microcracks. The phases of distribution of microcracks were well evidenced from the enlarged photomicrographs(${\times}6.7$) of the thin section. The planes of principal set of microcracks are parallel to the rift plane and those of secondary set are parallel to the grain plane. These rift and grain microcracks are mutually near-perpendicular on the hardway planes. From the directional angle(${\theta}$) - total length($L_t$), number(N) and density(${\rho}$) chart, the curve patterns of the above microcrack parameters reflect the phases of distribution of microcracks. Microcrack parameters such as number, length and density show an order of rift > grain > hardway. These results indicate a relative magnitude of the rock cleavage. Meanwhile, brazilian tensile strengths were measured with respect to the six directions. The results revealed a strong correlation between mechanical property with the above microcrack parameters. These general results correspond to those of the previous study for Jurassic granites from Pocheon and Hapcheon. Image processing technique for the enlarged photomicrograph of the thin section was carried out. The grain 1(G1) microcrack arrays developed in quartz and feldspar grains show excellent distribution on the photomicrograph. In particular, the directional angle of each microcrack set can be ascertained easily by brief image processing for the above photomicrograph.

• The Journal of the Petrological Society of Korea
• /
• v.20 no.2
• /
• pp.99-114
• /
• 2011

Precambrian gneiss complex in the Pyeongchang-Wonju area, which lies west of the Paleozoic sedimentary basin of the Yeongwol-Taebaek area, is being considered as a part of the Gyeonggi massif, but its ages of formation and metamorphic events are not well defined yet. In this study, SHRIMP zircon U-Pb ages were determined from the gneiss complex in the area, We obtained the discrete ages of magmatic (ca. 1960 Ma) and metamorphic (ca. 1860 Ma) events through the interpretation of the SHRIMP data based on the internal structures of zircons. These are almost the same to the ages of main intrusion and metamorphism reported from the Precambrian basements of Gyeonggi, Yeongnam and Nangnim massifs of the Korean Peninsula, Ages of 3200~3300 Ma, 2900 Ma, 2660 Ma, 2430 Ma, 2260 Ma, and 2080~2070 Ma obtained from inherited cores of studied zircons are also very similar to the frequently reported ages from the basement rocks of the Gyeonggi and Yeongnam massifs, Lower intercept age of about 270 Ma calculated from the rim data seems to indicate that the study area suffered from a late Paleozoic metamorphism (Okcheon Orogeny), but we need more reasonable and sufficient data to confirm it. According to the results of this study, it is suggested that the Bangnim group unconformably overlying the gneiss complex was deposited after the Paleoproterozoic granitic magmatism (ca. 1960 Ma) and metamorphism (ca. 1860 Ma).

• Tunnel and Underground Space
• /
• v.23 no.3
• /
• pp.219-227
• /
• 2013

Although Mohr-Coulomb failure criterion has limitations in that it is a linear criterion and the effect of the intermediate principal stress on failure is ignored, this criterion has been widely accepted in rock mechanics design. In order to overcome these shortcomings, the Hoek-Brown failure criterion was introduced and recently a number of 3-D failure criteria incorporating the effect of the intermediate principal stress on failure have been proposed. However, in many rock mechanics designs, the possible failure of rock mass is still evaluated based on Mohr-Coulomb criterion and most of practitioners are accustomed to understanding the strength of rock mass in terms of the internal friction angle and cohesion. Therefore, if the equivalent Mohr-Coulomb strength parameters of the advanced failure criteria are calculated, it is possible to take advantage of the advanced failure criteria in the framework of the Mohr-Coulomb criterion. In this study, a method expressing the tangential Mohr-Coulomb strength parameters in terms of the stress invariant is proposed and it is applied to the generalized Hoek-Brown criterion and the HB-WW criterion. In addition, a new approach describing the geometric meaning of the ${\sigma}_2$-dependency of failure criteria in 3-D principal stress space is proposed. Implementation examples of the proposed method show that the influence of the intermediate principal stress on the tangential friction angle and cohesion of the HB-WW criterion is considerable, which is not the case for the 2-D failure criterion.

• The Journal of the Petrological Society of Korea
• /
• v.20 no.2
• /
• pp.77-98
• /
• 2011

The igneous complex consisting of mangerite and gabbro in the Odaesan area, the eastem part of the Gyeonggi Massif, South Korea, intruded early Paleo-proterozoic migmatitic gneiss. The mangerite is composed of orthopyroxene, clinopyroxene, amphibole, biotite, plagioclase, pethitic K-feldspar, quartz. The gabbro has similar mineral assemblage but gabbro has minor amounts of amphibole and no perthitic K-feldspar. The gabbro occurs as enclave and irregular shaped body within the mangerite, and the boundary between the mangerite and gabbro is irregular. Leucocratic lenses with perthitic K-feldspar are included in the gabbro enclaves. These textures represent mixing of two different magmas in liquid state. SHRIMP U-Pb zircon age dating gave $234{\pm}1.2$ Ma and $231{\pm}1.3$ Ma for mangerite and gabbro, respectively. These ages are similar with the intrusion ages of post collision granitoids in the Hongseong (226~233 Ma) and Yangpyeong (227~231 Ma) areas in the Gyeonggi Massif. The mangerite and gabbro are high Ba-Sr granites, shoshonitic and formed in post collision tectonic setting. These rocks also show the characters of subduction-related igneous rock such as enrichment in LREE, LILE and negative Nb-Ta-P-Ti anomalies. These data represent that the mangerite and gabbro formed in the post collision tectonic setting by the partial melting of an enriched lithospheric mantle during subduction which occurred before collision. The heat for the partial melting was supplied by asthenospheric upwelling through the gab between continental and oceanic slabs formed by slab break-off after continental collision. The distribution of post-collisional igneous rocks (ca. 230 Ma) in the Gyeonggi Massif including Odaesan mangerite and gabbro strongly suggests that the tectonic boundary between the North and South China blocks in Korean peninsula passes the Hongseong area and futher exteneds into the area between the Yangpyeong-Odaesan line and Ogcheon metamorphic belt.

• Journal of the Korean earth science society
• /
• v.35 no.7
• /
• pp.501-517
• /
• 2014

Based on a summary of the previous studies on columnar joints, this study presents research strategies and subjects to understand a formation of columnar joints, and its application in South Korea as follows; geometry of colonnade and entablature, formation mechanism and pattern change, surface morphology and internal structure, platy joint at the top and the bottom of columnar joints, crack patterns in drying starch-water slurries, using numerical models and computer graphics on joint formation, scale and geometry concerned with occurrence of volcanic rock, petrological and mineralogical study of the host rock. Additionally, more research is needed, such as deformation of column pattern during the hot state, secondary landform by alteration and weathering on the Earth's surface such as rock stream, tor and tafoni. This study will take an active role in research of columnar joint and the Cenozoic lava flow of South Korea. Results of this study will be useful to the activation of geotourism and geological field study.

• Geophysics and Geophysical Exploration
• /
• v.13 no.4
• /
• pp.388-396
• /
• 2010

As a part of basic studies on monitoring and saturation estimation of carbon dioxide ($CO_2$) storage using resistivity survey, laboratory experiment has been conducted to measure the change of the electrical resistivity through repeated experiments of supercritical $CO_2$ and brine water injection into homogeneous and heterogeneous sandstones. The $CO_2$ saturation is estimated by using resistivity index based on the resistivity measurements. The experimental results of two types of sandstones show that the effect of pore structure in the rock and the effect of contained clay minerals in the rock can be affected to calculate the $CO_2$ saturation. The result can be useful to evaluate the $CO_2$ saturation based on resistivity survey at the site where $CO_2 sequestrates.

• Korean Journal of Mineralogy and Petrology
• /
• v.35 no.1
• /
• pp.65-73
• /
• 2022

The proper estimation of physical and chemical properties of Earth materials and their structures at high pressure and high temperature conditions is key to the full understanding of diverse geological processes in Earth and planetary interiors. Multi-anvil press - high-pressure generating device - provides unique information of Earth materials under compression, mainly relevant to Earth's upper mantle. The quantitative estimation of the relationship between the oil load within press and the actual pressure conditions within the sample needs to be established to infer the planetary processes. Such pressure-load calibration has often been based on the phase transitions of crystalline earth materials with known pressure conditions; however, unlike at high temperature conditions, phase transitions at low (or room) temperatures can be sluggish, making the calibration at such conditions challenging. In this study, we explored the changes in Al coordination environments of permanently densified pyrope glasses upon the cold compression using the high-resolution ²⁷Al MAS and 3QMAS NMR. The fractions of highly coordinated Al in the cold compressed pyrope glasses increase with increasing oil load and thus, the peak pressure condition. Based on known relationship between the peak pressure and the Al coordination environment in the compressed pyrope glasses at room temperature, we established a room temperature pressure-load calibration of the 14/8 HT assembly in 1,100-ton multi-anvil press. The current results highlight the first pressure-load calibration of any high pressure device using high-resolution NMR. Irreversible structural densification upon cold compression observed for the pyrope glasses provides insights into the deformation and densification mechanisms of amorphous earth materials at low temperature and high pressure conditions within the subducting slabs.