• Title/Summary/Keyword: 수소 발생기

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Investigation on Chilling Procedure for LOX Supply System for Liquid Rocket Engine (액체로켓엔진 산화제 공급부 냉각과정 고찰)

  • Cho, Nam-Kyung;Seo, Dae-Bahn;Yoo, Byung-Il;Kim, Seong-Han;Han, Yeoung-Min
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.3
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    • pp.119-126
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    • 2019
  • For rockets using cryogenic liquid hydrogen or liquid oxygen, chilling is required to avoid cavitation and surge problems. Chilling is categorized by the initial chilling/filling stage and the low-temperature maintenance stage. In addition, to improve satellite insertion capability, a multi-ignition capability is required and accordingly chilling to prepare for the next ignition during low-gravity coasting is also required. This paper describes the overall aspects of filling and low temperature maintain marinating for the booster and the upper stage engine including chilling for multi-ignition.

Characteristics of Al Alloy as a Material for Hydrolysis Reactor of NaBH4 (NaBH4 가수분해 반응기 소재로서 알루미늄 합금의 특성 연구)

  • Jung, Hyeon-Seong;Oh, Sung-June;Jeong, Jae-Jin;Na, Il-Chai;Chu, Cheun-Ho;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.677-681
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    • 2015
  • Aluminum alloy was examined as a material of low weight reactor for hydrolysis of $NaBH_4$. Aluminum is dissolved with alkali, but there is NaOH as a stabilizer in $NaBH_4$ solution. To decrease corrosion rate of aluminum, decrease NaOH concentration and this result in loss of $NaBH_4$ during storage of $NaBH_4$ solution. Therefore stability of $NaBH_4$ and corrosion of aluminum should be considered in determining the optimum NaOH concentration. $NaBH_4$ stability and corrosion rate of aluminum were measured by hydrogen evolution rate. $NaBH_4$ stability was tested at $20{\sim}50^{\circ}C$ and aluminum corrosion was measured at $60{\sim}90^{\circ}C$. The optimum concentration of NaOH was 0.3 wt%, considering both $NaBH_4$ stability and aluminun corrosion. $NaBH_4$ hydrolysis reaction continued 200min in aluminum No 6061 alloy reactor with 0.3 wt% NaOH at $80{\sim}90^{\circ}C$.

Amperometric Determination of Histamine using Immobilized Enzyme Reactors with Different Carriers (담체 고정화 효소 반응기를 이용한 Histamine의 전기화학적 측정)

  • Ji, Jung-Youn;Jeon, Yeon-Hee;Kim, Mee-Ra
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.1
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    • pp.88-94
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    • 2012
  • Histamine is a kind of primary biogenic amine arising from the decarboxylation of the amino acid L-histidine. The toxicology of histamine and its occurrence and formation in foods are especially emphasized in fermented foods. In this study, the biosensor for detection of histamine with functionalized multi-walled carbon nanotubes (MWCNT) was developed. We also searched for an appropriate insoluble substrate to immobilize the enzyme. The developed biosensor showed a detection limit of $0.1{\mu}M$ hydrogen peroxide. The enzyme reactor was prepared with diamine oxidase immobilized on insoluble carriers including CNBr-activated sepharose 4B, calcium alginate, and controlled pore size glass beads. The coupling efficiency of CNBr-activated sepharose 4B, calcium alginate, and controlled pore size glass beads were 48.5%, 40.3%, and 51.0%, respectively. In addition, the response currents on histamine with each immobilized enzyme reactor prepared with CNBr-activated sepharose 4B, calcium alginate, and controlled pore size glass beads were 120 nA, 110 nA, and 140 nA at $100{\mu}M$ of histamine concentration, respectively. Therefore, it is suggested that controlled pore size glass beads are the best carriers for immobilizing diamine oxidase to detect histamine in this biosensor.

A Study of Improving Combustion Stability with Sonic Wave Radiation (음파를 이용한 연소 안정성 개선에 관한 연구)

  • Min, Sun-ki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.8
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    • pp.401-406
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    • 2020
  • NOx (nitrogen oxide) in the exhaust gas engines causes severe air pollution. NOx is produced under high-temperature combustion conditions. EGR (exhaust gas recirculation) is normally used to reduce the combustion temperature and NOx production. As the EGR ratio increases, the NOx level becomes low. On the other hand, an excessively high EGR ratio makes the combustion unstable resulting in other air pollution problems, such as unburned hydrocarbon and higher CO levels. In this study, the improvement of fuel droplets moving by the radiation of sonic waves was studied for the stable combustion using analytic and experimental methods. For the analytical study, the effects of the radiation of a sonic wave on the fuel droplet velocity were studied using Fluent software. The results showed that the small droplet velocity increased more under high-frequency sonic wave conditions, and the large droplet velocity increased more under low-frequency sonic wave conditions. For the experimental study, the combustion chamber was made to measure the combustion pressure under the sonic wave effect. The measured pressure was used to calculate the heat release rate in the combustion chamber. With the heat release rate data, the heat release rate increased during the initial combustion process under low-frequency sonic wave conditions.

Full-scale EFC Study on Oil Recovery and Reuse from Discharge Gas of Tenter Facility in Textile Industry (Full-scale EFC (Electric Fume Collector)를 활용한 텐타공정 배출가스 정화 및 오일 회수)

  • Hwang, Yeal-Soon;Park, Hee-Jae;Chung, Gu-Hoi;Kim, Duk-Hyun;Na, Byung-Ki
    • Clean Technology
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    • v.17 no.3
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    • pp.259-265
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    • 2011
  • The textile industry is suffered from air pollution problems which must be resolved. In particular, white smoke and odor after the tenter process require abatement. The major air pollution problem in the textile industry occurs during the finishing stages, where various chemicals are used for coating the fabrics. Lubricating oils, plasticizers, and water repellent chemicals are the fabric treatment chemicals. The coated fabrics are cured by heating in tenter facility. In this process, most of air pollutants emitted into the air. White smoke is basically made up of tiny solid or liquid particles of VOCs less than one micron in size. The oil mist can be carried over long distance from their point of origin. The most effective method of removing odor from tenter process is to get rid of tiny oil mist at the emitted gas. For this reason, the full-scale EFC (Electric Fume Collector) of 700 CMM was tested for removing odorous substances emitted from tenter facility. As a result of this study, odor and white smoke can be eliminated effectively and quite large amounts of oil can be recovered.

Evaluation of Air Quality in the Compost Pilot Plant with Livestock Manure by Operation Types (축분 퇴비화시스템 운용방식에 따른 실내 대기오염 평가)

  • Kim, K.Y.;Choi, H.L.;Ko, H.J.;Kim, C.N.
    • Journal of Animal Science and Technology
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    • v.46 no.2
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    • pp.283-294
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    • 2004
  • Air quality in the livestock waste compost pilot plant at the Colligate Livestock Station was assessed to quantity the emissions of aerial contaminants and evaluate the degree of correlation between them for different operation strategies; with the ventilation types and agitation of compost pile, in this study. The parameters analyzed to reflect the level of air quality in the livestock waste compost pilot plant were the gaseous contaminants; ammonia, hydrogen sulfide, and odor concentration, the particulate contaminants; inhalable dust and respirable dust, and the biological contaminants; total airborne bacteria and fungi. The mean concentrations of ammonia, hydrogen sulfide, and odor concentration in the compost pilot plant without agitation were 2.45ppm, 19.96ppb, and 15.8 when it was naturally ventilated, and 7.61ppm, 31.36ppb, and 30.2 when mechanically ventilated. Those with agitation were 5.50ppm, 14.69ppb, and 46.4 when naturally ventilated, and 30.12ppm, 39.91ppb, and 205.5 when mechanically ventilated. The mean concentrations of inhalable and respirable dust in the compost pilot plant without agitation were 368.6${\mu}g$/$m^3$ and 96.0${\mu}g$/$m^3$ with natural ventilation, and 283.9${\mu}g$/$m^3$ and 119.5${\mu}g$/$m^3$ with mechanical ventilation. They were also observed with agitation to 208.7${\mu}g$/$m^3$ and 139.8${\mu}g$/$m^3$ with natural ventilation, and 209.2${\mu}g$/$m^3$ and 131.7${\mu}g$/$m^3$ with mechanical ventilation. Averaged concentrations of total airborne bacteria and fungi in the compost pilot plant without agitation were observed to 28,673cfu/$m^3$ and 22,507cfu/$m^3$ with natural ventilation, and 7,462cfu/$m^3$ and 3,228cfu/$m^3$ with mechanical ventilation. They were also observed with agitation to 19,592cfu/$m^3$ and 26,376cfu/$m^3$ with the natural ventilation, and 18,645cfu/$m^3$ and 24,581cfu/$m^3$ with the mechanical ventilation. It showed that the emission rates of gaseous pollutants, such as ammonia, hydrogen sulfide, and odor concentration, in the compost pilot plant operated with the mechanical ventilation and with the agitation of compost pile were higher than those with the natural ventilation and without the agitation. While the concentrations of inhalable dust and total airborne bacteria in the compost pilot plant with the natural ventilation and with the agitation, the concentrations of respirable dust and total airborne fungi in the compost pilot plant with the mechanical ventilation and agitation were higher than those with the natural ventilation and without the agitation of compost pile. It was statistically proved that indoor temperature and relative humidity affected the release of particulates and biological pollutants, and ammonia and hydrogen sulfide were believed primary malodorous compounds emitted from the compost pilot plant.

Comparison of the Mid-term Changes at the Remnant Distal Aorta after Aortic Arch Replacement or Ascending Aortic Replacement for Treating Type A Aortic Dissection (A형 급성대동맥박리증에서 대동맥궁치환술과 상행대동맥치환술 후 잔존 원위부 대동맥의 변화에 대한 중기 관찰 비교)

  • Cho, Kwang-Jo;Woo, Jong-Su;Bang, Jung-Hee;Choi, Pill-Jo
    • Journal of Chest Surgery
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    • v.40 no.6 s.275
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    • pp.414-419
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    • 2007
  • Background: Replacing the ascending aorta is a standard surgical option for treating acute type A aortic dissection. But replacing the aortic arch has recently been reported as an acceptable procedure for this disease. We compared the effects of aortic arch replacement for treating acute type A aortic dissection with the effects of ascending aortic replacement. Material and Method: From 2002 to 2006, 25 patients undewent surgical treatment for acute type A aortic dissection, 12 patients undewent ascending aortic replacement and 13 patients underwent aortic arch replacement. Among the aortic arch group, an additional distal stent-graft was inserted during the operation in 5 patients. 19 patients (11 arch replaced patients and 8 ascending aortic replaced patients) were followed up at the out patient clinic for an average of $756{\pm}373$ days. All the patients undewent CT scanning and we analyzed their distal aortic segments. Result: 4 patients who underwent ascending aortic replacement died, so the overall mortality rate was 16%. Among the 11 long term followed-up arch replacement patients, 2 patients (18.1 %) developed distal aortic dilatation and one of them underwent thoracoabdominal aortic replacement later on. However, among the 8 the ascending aortic replaced patients, 5 patients (62.5%) developed distal aortic dilatation. Conclusion: Aortic arch replacement is one of the safe options for treating acute type A aortic dissection. Aortic arch replacement for treating acute type A aortic dissection could contribute to a reduced distal aortic dilatation rate and fewer secondary aortic procedures.

Development of Land Fill Gas(LFG)-MGT Power Generation and Green House Design Technology (쓰레기 매립지 MGT 발전 및 유리온실 설계기술개발)

  • Hur, Kwang-Beom;Park, Jung-Keuk;Lee, Jung-Bin
    • Journal of Energy Engineering
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    • v.20 no.1
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    • pp.13-20
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    • 2011
  • The high fuel flexibility of Micro Gas Turbine(MGT) has boosted their use in a wide variety of applications. Recently, the demand for biogas generated from the digestion of organic wastes and landfill as a fuel for gas turbines has increased. We researched the influence of firing landfill gas(LFG) on the performance and operating characteristics of a micro gas turbine combined heat and power system. $CH_4$ and $CO_2$ simultaneous recovery process has been developed for field plant scale to provide an isothermal, low operating cost method for carrying out the contaminants removal in Land Fill Gas(LFG) by liquid phase catalyst for introduce into the green house for the purpose of $CO_2$ rich cultivation of the plants. Methane purification and carbon dioxide stripping by muti panel autocirculation bubble lift column reactor utilizing Fe-EDTA was conducted for evaluate optimum conditions for land fill gas. Based on inflow rate of LFG as 0.207 $m^3$/min, 5.5 kg/$cm^2$, we designed reactor system for 70% $CH_4$ and 27% $CO_2$ gas introduce into MGT system with $H_2S$ 99% removal efficiency. A green house designed for four different carbon dioxide concentration from ambient air to 1500 ppm by utilizing the exhaust gas and hot water from MGT system.

Study of Pyrolysis Behavior of Alberta Oil Sand by Continuous Operation of Fluidized-Bed Reactor (Alberta 오일샌드의 유동층 열분해 연속실험을 통한 열분해 특성 파악)

  • Shin, Jong-Seon;Sun, Yang Kuk;Park, Young Cheol;Bae, Dal-Hee;Jo, Sung-Ho;Shun, Dowon
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.68-74
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    • 2010
  • In this study, fluidized-bed pyrolysis has been conducted in order to recover the bitumen contained in the oil sand. Canada Alberta oil sand contains 11.9% of bitumen and the bitumen-derived heavy oil produced in fluidizedbed tends to be upgraded relative to the bitumen. The continuous operation has been performed using $N_2$ as a fluidization gas at 1 atm and $500^{\circ}C$ in a reactor of 170 cm height. The results showed 87.76% of bitumen conversion, where liquid products are 74.45% and gas products are 13.31%. $H_2$, $O_2$, CO, $CO_2$, $CH_4$, and NO and $C_1{\sim}C_4$ hydrocarbons in the gas products were analyzed by on-line gas analyzer and gas chromatography, respectively. The pyrolysis oil was analyzed by using proximate analysis, heavy metal analysis, SIMDIS, asphaltenes, and heating value. By SIMDIS analysis, naphtha was 11.50%, middle distillation was 44.83% and heavy oil was 43.66%. It was obvious that the pyrolysis oil was upgraded compared with bitumens.

Preparation and Characterization of Anion Exchange Membrane Based on Crosslinked Poly(2,6-dimethyl-1,4-phenylene oxide) with Spacer-type Conducting Group (Spacer-type 전도기가 도입된 가교형 poly(2,6-dimethyl-1,4-phenylene oxide) 음이온 교환막의 제조 및 특성평가)

  • Lim, Haeryang;Kim, Tae-Hyun
    • Membrane Journal
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    • v.27 no.5
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    • pp.425-433
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    • 2017
  • As the problems related to the environmental pollution such as carbon dioxide emission are emerging, the need for the renewable energy and environmentally friendly energy is getting intense. Fuel cells are eco-friendly energy generation devices that generate electrical energy and produce water as a sole by-product. Compared to the traditional proton exchange membrane fuel cell (PEMFC), anion exchange membrane alkaline fuel cell (AEMAFC) has a main advantage of possibility to use low cost metal catalysts due to its faster kinetics. The AEM, which conducts $OH^-$ ions, should possess high ion conductivity as well as high chemical stability at high pH conditions. We hereby introduce a crosslinked poly(2,6-dimethyl-1,4-phenylene oxide) having a spacer-type conducting group as novel AEM, and report a high ion conductivity ($67.9mScm^{-1}$ at $80^{\circ}C$) and mechanical properties (Young's modulus : 0.53 GPa) as well as chemical stability (6.8% IEC loss at $80^{\circ}C$ for 1,000 h,) for the developed membrane.