• Clean Technology
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• v.28 no.4
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• pp.316-322
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• 2022

The flow pattern at the inlet of the catalyst layer in a selective catalytic reduction (SCR) system is one of the key parameters influencing the performance of the denitrification process. In the curved diffusing parts between the ammonia injection grids and the catalyst layers, guide vanes are installed to improve flow uniformity. In the present study, a numerical simulation has been performed to investigate the effect of the geometrical configuration of the guide vanes on the aerodynamic characteristics of a denitrification facility. This application has been made to the existing SCR process in a large-scaled coal-fired power plant. The flow domain to be solved covers the whole region of the flow passages from the exit of the ammonia injection gun to the exit of the catalyst layers. ANSYS-Fluent was used to calculate the three-dimensional steady viscous flow fields with the proper turbulence model fitted to the flow characteristics. The root mean square of velocity and the pressure drop inside the flow passages were chosen as the key performance parameters. Four types of guides vanes were proposed to improve the flow quality compared to the current configuration. The numerical results showed that the type 4 configuration was the most effective at improving the aerodynamic performance in terms of flow uniformity and pressure loss.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.11
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• pp.7433-7438
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• 2015

Deactivation characteristics of $V_2O_5/TiO_2$ catalysts were studied for selective catalytic reduction(SCR) of NOx with ammonia in the presence of $SO_2$. Performance of catalyst was investigated for $deNO_x$ activity while changing temperature, $SO_2$ concentration. The activity of catalyst was decreased with the increase of $SO_2$ concentration and reaction time. Also, degree of activity drop was largely decreased with the increase of reaction temperature in the range of $250{\sim}300^{\circ}C$. Physicochemical properties of deactivated catalysts were characterized by BET, XRD, SEM, TPD analysis. According to the analysis results, deactivation phenomena occur due to the relatively high formation of ammonium sulfate salts, which created by unreacted ammonia and water in the presence of $SO_2$. It was revealed that ammonium sulfate cause the pore plogging of support and deposition of active matter.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.7
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• pp.1209-1215
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• 2022

The selective catalytic reduction (SCR) is known as a very efficient method to reduce nitrogen oxides (NOx) and the catalyst performs reduction from nitrogen oxides (NOx) to nitrogen (N₂) and water vapor (H2O). The catalyst, which is one of the factors determining the performance of the nitrogen oxide (NOx) ruduction method, is known to increase catalyst efficiency as cell density increases. In this study, the reduction characteristics of nitrogen oxides (NOx) under various engine loads investigated. A 100CPSI(60Cell) catalysts was studied through a laboratory-sized simulating device that can simulate the exhaust gas conditions from the power generation engine installed in the training ship SEGERO. The effect of 100CPSI(60Cell) cell density was compared with that of 25.8CPSI(30Cell) cell density that already had NOx reduction data from the SCR manufacturing. The experimental catalysts were honeycomb type and its compositions and materials of V₂O₅-WO₃-TiO₂ were retained, with only change on cell density. As a result, the NOx concentration reduction rate from 100CPSI(60Cell) catalyst was 88.5%, and IMO specific NOx emission was 0.99g/kwh satisfying the IMO Tier III NOx emission requirement. The NOx concentration reduction rate from 25.8CPSI(30Cell) was 78%, and IMO specific NOx emission was 2.00g/kwh. Comparing the NOx concentration reduction rate and emission of 100CPSI(60Cell) and 25.8CPSI(30Cell) catalysts, notably, the NOx concentration reduction rate of 100CPSI(60Cell) catalyst was 10.5% higher and its IMO specific NOx emission was about twice less than that of the 25.8CPSI(30Cell) catalysts. Therefore, an efficient NOx reduction effect can be expected by increasing the cell density of catalysts. In other words, effects to production cost reduction, efficient arrangement of engine room and cargo space can be estimated from the reduced catalyst volume.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.4
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• pp.412-417
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• 2015

The IMO MEPC has been increasingly strengthening the emission standard for marine environment protection. In particular, nitrogen oxide (NOx) emissions of all ocean-going ships built from 2016 will be required to comply with the Tier-III regulation. In this study, a vanadia based SCR (Selective Catalytic Reduction) system developed for ship application was installed on a diesel engine for power generation of the training ship T/S SAENURI in Mokpo National Maritime University. For the present study, the exhaust pipeline of the generator diesel engine was modified to fit the urea SCR system. This study investigated the NOx reduction performance according to the two kind of injection method of urea solution (40%): Auto mode through the PLC (Programable Logic Control) and Manual mode. We were able to find the ammonia slip conditions when in manual mode method. So, the optimal urea injection quantity can be controlled at each engine load (25, 35, 50%) condition. It was achieved 80% reduction on nitrogen oxide. Furthermore, we found that the NOx reduction performance was better with the load up-down (while down to 25% from 50%) than the load down-up (while up to 50% from 25%) test.

• Journal of Power System Engineering
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• v.15 no.4
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• pp.42-47
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• 2011

The purpose of this study is to investigate the best melting condition with various winding number of a heating pipe, supplying quantity of engine coolant and coolant temperature at the inlet of the heating pipe. Also, it is to suggest getting method of an appropriate quantity of the agent for the urea-SCR system within 10 minutes. For this matter, this study identifies the temperature distribution of inside of urea-tank while it is frozen at the low temperature condition, and suggests the best melting condition of the frozen urea within 10 minutes. From the results, it was found that 2L of melted urea was obtained by the coolant flow rate of 200L/hr at $70^{\circ}C$ for 10 minutes from the start of engine operating.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.3
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• pp.71-76
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• 2003

A numerical simulation of selective catalytic reduction (SCR) for NO with $NH_3$ is conducted over the $V_2O_5/TiO_2$ and $WO_3-V_2O_5/TiO_2$ catalysts. The governing $NH_3$ and NO transport equations are considered by using the time-dependent FCT (Flux-Corrected Transport) algorithm. After a validating simulation for $NH_3$ step feed and shut-off experiments is analyzed, transient behavior of $NH_3$ and NO concentration in a SCR catalyst is investigated by changing such parameters as inflow $NH_3$ concentration, temperature of the catalyst, and $NH_3$/NOx ratios.

• Special Issue of the Society of Naval Architects of Korea
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• 2017.10a
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• pp.54-58
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• 2017

The vessels which are operated in ECA (Emission Control Area) after $1^{st}$ January 2016 shall be complied with revised NOx emission requirement (Tier III). Effective solutions for NOx emission requirement are SCR (Selective Catalytic Reduction), EGR (Exhaust Gas Recirculation) and Installation of LNG Dual Fuel Engine. This study is considered the design modification as per application of LNG Ready notation. In case of LNG Ready - S notation, the vessel shall be retrofitted the Main engine with Dual fuel engine and LNG Fuel system after delivery. On this paper, the entire process for design modification was explained to meet the requirement for LNG Ready notation.

• Journal of the Korea Convergence Society
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• v.10 no.4
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• pp.131-138
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• 2019

Diesel engines have important advantages over its gasoline counterpart including high thermal efficiency, high fuel economy and low emissions of CO, HC and $CO_2$. However, NOx reducing is more difficult on diesel engines because of the high $O_2$ concentration in the exhaust, marking general three way catalytic converter ineffective. Two method available technologies for continuous NOx reduction onboard diesel engines are Urea-SCR and LNT. The implementation of the Urea-SCR systems in design engines have made it possible for 2.5l and over engines to meet the tightened NOx emission standard of Euro-6. In this study, we investigate the characteristics of NOx reduction with respect to engine speed, load, types of catalyst and the $NH_3$/NOx ratio and present the conditions which maximize NOx reduction. Also we provide detailed experimental data on Urea-SCR which can be used for the preparation for standards beyond Euro-6.

• 기계와재료
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• v.24 no.2
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• pp.6-17
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• 2012

최근 산업구조의 고도화에 따라 다양한 산업분야에서 화석연료 등의 에너지소모가 급증하면서 환경문제의 심각성이 대두되고 있다. 그중 질소산화물(NOx)은 산성비와 광화학 스모그의 원인이 되며 눈과 호흡기를 자극하고 식물을 고사시키는 등 주요 대기오염물질로 규제되고 있다. 이와 관련하여 국제해사기구(IMO)에서는 선박대기오염물질의 배출을 규제하는 규정을 만들었으며, 최근에는 배출규제를 강화하는 등 적극적인 규제활동을 벌이고 있다. 따라서 본 논문에서는 선박배기가스 질소산화물의 배출규제 현황과 배출 규제안에 대응하기 위해 본 연구원에서 연구개발 중인 배기가스 오염물질 저감장치의 선택적 촉매 환원(Selective Catalytic Reduction, SCR)시스템에 관하여 간략히 기술한다.

• Journal of Navigation and Port Research
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• v.40 no.4
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• pp.173-181
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• 2016

From 2016, controls on reduction of NOx and SOx emissions from the vessels that are operated in the emission control area were tightened. The selectivity catalytic reduction system of the denitrification equipment which NOx among the above controlled materials is very effective and used commercially very much. But it has the disadvantage that CSR is activated at high temperatures. Therefore, the SCR and SCR activation instrument that can react even at low temperatures by using micro-nano bubbles so that the above problems can be minimized were developed. And the computational fluid dynamics technique was used by ANSYS-CFX package to prepare the plan that improves the SCR system's efficiency. Simulation for the viscous flow analysis of the SCR system was executed by applying the Navier-Stokes equation to it as a governing equation. For the SCR system's shape, 3D modeling was done by using CATIA V5. SCR jet nozzle's position was checked by changing it to the intervals of 1/3, 1/2, and 2/3 from the inlet of the vent pipe to compare the SCR system's efficiency. And the number of nozzles was compared and analyzed by simulating 4, 6, and 8 holes to check an effect of the number on the SCR system's efficiency. The simulation result has found that the closer nozzles are to the inlet of the vent pipe and the more nozzles are, the more efficiency is improved.