• Journal of the Korean Chemical Society
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• v.35 no.4
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• pp.355-361
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• 1991

The separative preconcentration of trace mercury[Hg(II)] in a water sample was studied by a coprecipitation flotation technique. The trace Hg(II) was precipitated together with Ce(OH)$_3$ by adding 3.0 ml of 0.1M Ce$^{3+}$ solution to 1,000 ml of water sample and adjusting pH to 11.0 with 1.0M NaOH solution. The hydrophobic precipitate[Ce(OH)$_3$-Hg(OH)$_2$], which was formed by adding 2.0 ml of 0.1${\%}$ ethanolic sodium oleate solution, were floated on the surface with an aid of tiny nitrogen gas bubbles. The floated materials were quatitatively collected in a suction flask and dissolved with 5.0 ml of 2.0M HNO$_3$. The solution was marked to 25.00 ml with a deionized water. The content of Hg(II) was determined by cold vapor atomic absorption spectrophotometry. Any interferences of concomitants such as Ag$^+$, Br$^-$, I$^- $, etc. were not observed on the whole procedure. The analytical result showed that Hg(II) found in the wastewater of Seochang Campus, Korea University was 1.98 ng/ml with the relative standard deviation of 3.6${\%}$. And recoveries of Hg(II) in the wastewater into which 1.0 ng/ml and 2.0 ng/ml were added were 95${\%}$ and 91${\%}$, respectively. From such results, this procedure could be concluded to be tolerably accurate and reproducible for the determination of trace mercury in a water sample.

• 한국지구과학회:학술대회논문집
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• 2010.04a
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• pp.98-98
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• 2010

그라우팅은 지반의 공학적인 강도증가를 통한 지지력 향상 및 암반의 투수성 저감을 통해 지하수 유동을 억제하기 위하여 대규모 토목공사 현장의 균열암반 및 댐 또는 제방 등의 지역에서 많이 시행되고 있다. 본 연구는 균열암반지역에서 그라우팅 효과 확인을 위하여 보통 포틀랜드 시멘트(OPC)와 마이크로 시멘트(MC)를 사용하여 그라우팅을 수행하였으며, 그라우팅 전후에 물리검층(시추공영상촬영, 초음파 텔레뷰어검층)을 이용하여 그라우팅 효과 정도를 파악하였다. 연구지역은 경상북도 영주시 평은면 지역으로, 지질은 선캠브리아기 안구상편마암에 시대미상의 흑운모 화강암이 관입을 하였고, 이를 제4기의 충적층이 부정합으로 피복되어 있다. 그라우팅은 일반구간과 단층대구간으로 구분하여 실시하였으며, 두 구간의 이격거리는 서로의 간섭을 피하기 위해 약 40m 간격으로 선정하였다. 주입재(OPC, MC)는 5개의 주입공에서 triangle 방향으로 주입하였으며, 주입정도를 확인하기 위하여 각 구간에 2공씩 확인시추를 하였다. 두 개의 site중 일반구간의 보통 포틀랜드시멘트 주입결과 평균주입량은 48.2kg/공이며 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 1.62kg/m이며, 마이크로시멘트의 평균주입량은 49.6kg/공이며 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 3.86kg/m로 나타났다. 단층대 구간에서는 보통 포틀랜드시멘트의 평균주입량이 40.0kg/공이며, 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 2.75kg/m이며, 마이크로 시멘트는 평균주입량이 56.5kg/공, 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 3.15kg/m로 나타났다. 마이크로시멘트의 주입압은 보통 포틀랜드시멘트에 비해 상대적으로 낮았으며, 그라우팅 개선효과 역시 상대적으로 양호한 것으로 나타났다. 그라우팅 효과확인을 위한 물리검층의 초음파텔레뷰어 해석결과 상대암반강도는 주입전 $250{\sim}750\;kgf/cm^2$, 주입후는 $400{\sim}800\;kgf/cm^2$으로 그라우팅에 의한 암반강도의 상승을 확인할 수 있었고, 시추공영상촬영 분석에서는 시추코어만으로 얻기 힘든 시멘트 충진구간을 직접 확인할 수 있었다. 초음파텔레뷰어의 경우 파쇄대의 분포 및 암반강도 측정을 통한 그라우팅 파악은 가능하였으나 파쇄대 충진물을 확인할 수가 없는 단점이 있었고 이를 시추공영상촬영을 통해 보완할 수 있었다. 다만 물리검층의 경우 그라우팅에 의한 공의 손실로 동일공에 의한 반복 조사가 아닌 경우가 대부분이어서 그라우팅 효과에 대한 정확한 비교가 어려웠으며 추후 이를 보완하기 위한 계속적인 연구가 필요할 것으로 사료된다.

• Analytical Science and Technology
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• v.13 no.4
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• pp.446-452
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• 2000

The simulated nuclear spent fuel (SIMFUEL) containing the platinum group elements which will not be dissolved in a nitric acid was completely dissolved with a acid digestion bomb. The metallic elements separated in the SIMFUEL were measured by inductively coupled plasma atomic emission spectrometry (ICP-AES). Because the peaks of metallic elements were spectrally interfered by uranium spectrum, uranium and metallic elements were separated by cation exchange resin for Mo, Pd, Rh and Ru and by anion exchange resin for Ba, Ce, La, Nd, Rh, Sr, Y and Zr, respectively. The recovery of Mo, Pd, Rh and Ru after separation by cation exchange chromatography found to be 99-103% and anion exchange separation showed 96.5-107% of recovery except Y with the simulated solution whose concentration was similar to the spent nuclear fuel. The relative standard deviation of this method showed 1.3-6.7% in the SIMFUEL whose concentrations of metallic elements were between several $10^2-10^3$ppm.

• Journal of Astronomy and Space Sciences
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• v.19 no.4
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• pp.305-318
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• 2002

We have constructed two flight models of airglow photometer system (AGP) to be onboard Korea Sounding Rocket-III (KSR-III) for detection of MUV dayglow above the Korean peninsular. The AGP system is designed to detect dayglow emissions of OI 2972${\AA}$, $N_2$ VK(0,6) 2780${\AA}$, $N_2$ 2PG 3150${\AA}$ and background 3070${\AA}$ toward the horizon at altitudes between 100 km and 300 km. The AGP system consists of a photometer body, a baffle an electronic control unit and a battery unit. The MUV dayglow emissions enter through a narrow band interference filter and focusing lens of the photometer, which contains an ultraviolet sensitive photomultiplier tube. The photometer is equipped with an in-flight calibration light source on a circular plane that will rotate at the rocket's apogee. A bane tube is installed at the entry of the photometer in order to block strong scattering lights from the lower atmosphere. We have carried out laboratory measurements of sensitivity and in-flight calibration light source for the AGP flight models. Although absolute sensitivities of the AGP flight models could not be determined in the country, relative sensitivities among channels are well measured so that observation data during rocket flight in the future can be analyzed with confidence.

• Journal of The Korean Ophthalmological Society
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• v.59 no.11
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• pp.1097-1102
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• 2018

Purpose: To report a case of toxic optic neuropathy caused by chlorfenapyr ingestion accompanied by central nervous system involvement. Case summary: A 44-year-old female visited our clinic complaining of reduced visual acuity in both eyes for 7 days. She had ingested a mouthful of chlorfenapyr for a suicide attempt 2 weeks prior to the visit. Gastric lavage was performed immediately after ingestion at the other hospital. Her best-corrected visual acuity was finger count 30 cm in the right eye and hand motion in the left eye. Both pupils were dilated by 5.0 mm and the response to light was sluggish in both eyes. A relative afferent pupillary defect was detected in her left eye. Funduscopy revealed optic disc swelling in both eyes. Magnetic resonance imaging of the brain showed a symmetric hyper-intense signal in the white matter tract including the internal capsule, corpus callosum, middle cerebellar peduncle, and brainstem. The patient was diagnosed with toxic optic neuropathy induced by chlorfenapyr ingestion, and underwent high-dose intravenous corticosteroid pulse therapy. Three days later, the best-corrected visual acuity was no light perception in both eyes. Three months later, optic atrophy was observed in both eyes. Optical coherence tomography revealed a reduction in the thicknesses of the retinal nerve fiber layer and ganglion cell and inner plexiform layer in the macular area. Conclusions: Ingestion of even a small amount of chlorfenapyr can cause severe optic nerve damage through the latent period, despite prompt lavage and high-dose steroid treatment.

• Journal of the Korean GEO-environmental Society
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• v.12 no.1
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• pp.51-60
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• 2011

Electrical resistivity is applied for understanding details about layers and obtaining basic properties of soils to various measurement devices. The objective of this study is development of TRP(Temperature-compensated Resistivity Probe), analysis about effects of temperature changes during cone penetration test, and observation of characteristics of cone penetration. In order to observation of temperature changes according to a diameter difference of resistivity cone probe, the cone which has wedge type cone tip is made to two types, 2mm and 5mm. Temperature sensor is attached at 15mm below from cone tip because of an electrical interference with elecrical resistance probe. Delectrical connector is used to prevent electric disturbance between motor type penetrating machine and electrical resistivity cone probe. Application tests are carried out in acrylic cell whose diameter is 30cm with uniform Jumunjin sand according to densification caused by blows. The test results indicate that the temperature is increased uniformly during penetration and a tendency, characteristics of cone penetration, is discovered during altering state of soils. This study suggests that the temperature effects and characteristics of penetration should be considered in penetrating tests in order to conduct an accurate ground investigation using TRP(Temperature-compensated Resistivity Probe).

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.33 no.6
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• pp.275-286
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• 2021

In this study, the analytical solution for diffraction near a vertical detached breakwater was suggested by superposing the solutions of diffraction near a semi-infinite breakwater suggested previously using linear wave theory. The solutions of wave forces acting on front, lee and composed wave forces on both side were also derived. Relative wave amplitude changed periodically in space owing to the interactions between diffracting waves and standing waves on front side and the interactions between diffracting waves from both tips of a detached breakwater on lee side. The wave forces on a vertical detached breakwater were investigated with monochromatic, uni-directional random and multi-directional random waves. The maximum composed wave force considering the forces on front and lee side reached maximum 1.6 times of wave forces which doesn't consider diffraction. This value is larger than the maximum composed wave force of semi-infinite breakwater considering diffraction, 1.34 times, which was suggested by Jung et al. (2021). The maximum composed wave forces were calculated in the order of monochromatic, uni-directional random and multi-directional random waves in terms of intensity. It was also found that the maximum wave force of obliquely incident waves was sometimes larger than that of normally incident waves. It can be known that the considerations of diffraction, the composed wave force on both front and lee side and incident wave angle are important from this study.

• Journal of Korean Orthopaedic Sports Medicine
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• v.2 no.1
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• pp.28-36
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• 2003

Purpose: To determine and to compare the effects of cyclic loading on the fixation strength of different femoral fixation methods in ACL reconstruction. Materials and Methods: Biomechanical test using an Instron(R) machine (Model No.5569. Mass, U.S.A) were carried out to compare the pull out strength of six different femoral fixation techniques after a cyclic loading in 72 Yorkshire pig knees. The graft-bone complex was cyclically loaded between 30N and 150N at 50 mm/min rate for 1000 cycles and maximal tensile testing was performed. A preload of 30N was applied to the graft along the axis of the tunnel 15 minutes. ANOVA and the Duncan multiple comparison test was used for the statistical analysis. Results: The mean maximum tensile strength of femoral fixation before and after the cyclic loading test were 1003.4$\pm$145N and 601.1$\pm$154N in hamstring-LA screw(R) group, 595.5$\pm$104N and 360.7$\pm$56N in hamstring-Bioscrew(R) group, 1431.7$\pm$135N and 710.7$\pm$114N in hamstring-Semifix(R) group, 603.6$\pm$54N and 459.1$\pm$46N in hamstring-Endobutton(R) fixation group, 1067.4$\pm$145 and 601.8$\pm$134N in the BPTB-Titanium interference screw group, and 987.1$\pm$168N and 588.7$\pm$124N in the BPTB-Bioscrew(R) group. And these data illustrated that cyclic loading reduces the maximum tensile strength by 40 $\%$, 39 $\%$, 50 $\%$, 24 $\%$, 44 $\%$, 40 $\%$ respectively. Conclusions: With the results of these experiments it should be emphasized that rehabilitation exercises after anterior cruciate ligament reconstruction should be executed with precaution as the repetitive flexion and extension of the knee would compromise the maximum tensile strength of the graft tendon.

• Journal of Food Hygiene and Safety
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• v.36 no.3
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• pp.228-238
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• 2021

The aim of this research was to develop a rapid and easy multi-residue method for determining dimethipin, omethoate, dimethipin, chlorfenvinphos and azinphos-methyl in agricultural products (hulled rice, potato, soybean, mandarin and green pepper). Samples were prepared using QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) and analyzed using gas chromatography-tandem mass spectrometry (GC-MS/MS). Residual pesticides were extracted with 1% acetic acid in acetonitrile followed by addition of anhydrous magnesium sulfate (MgSO₄) and anhydrous sodium acetate. The extracts were cleaned up using MgSO₄, primary secondary amine (PSA) and octadecyl (C₁₈). The linearity of the calibration curves, which waas excellent by matrix-matched standards, ranged from 0.005 mg/kg to 0.3 mg/kg and yielded the coefficients of determination (R²) ≥ 0.9934 for all analytes. Average recoveries spiked at three levels (0.01, 0.1, 0.5 mg/kg) and were in the range of 74.2-119.3%, while standard deviation values were less than 14.6%, which is below the Codex guideline (CODEX CAC/GL 40).

• Analytical Science and Technology
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• v.35 no.3
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• pp.136-142
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• 2022

According to media reports, the carcasses of euthanized abandoned dogs were processed at high temperature and pressure to make powder, and then used as feed materials (meat and bone meal), raising the possibility of residuals in the feed of the anesthetic ketamine and dexmedetomidine used for euthanasia. Therefore, a simultaneous analysis method using QuEChERS combined with high-performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry was developed for rapid residue analysis. The method developed in this study exhibited linearity of 0.999 and higher. Selectivity was evaluated by analyzing blank and spiked samples at the limit of quantification. The MRM chromatograms of blank samples were compared with those of spiked samples with the analyte, and there were no interferences at the respective retention times of ketamine and dexmedetomidine. The detection and quantitation limits of the instrument were 0.6 ㎍/L and 2 ㎍/L, respectively. The limit of quantitation for the method was 10 ㎍/kg. The results of the recovery test on meat and bone meal, meat meal, and pet food showed ketamine in the range of 80.48-98.63 % with less than 5.00 % RSD, and dexmedetomidine in the range of 72.75-93.00 % with less than 4.83 % RSD. As a result of collecting and analyzing six feeds, such as meat and bone meal, prepared at the time the raw material was distributed, 10.8 ㎍/kg of ketamine was detected in one sample of meat and bone meal, while dexmedetomidine was found to have a concentration below the limit of quantitation. It was confirmed that the detected sample was distributed before the safety issue was known, and thereafter, all the meat and bone meal made with the carcasses of euthanized abandoned dogs was recalled and completely discarded. To ensure the safety of the meat and bone meal, 32 samples of the meat and bone meal as well as compound feed were collected, and additional residue investigations were conducted for ketamine and dexmedetomidine. As a result of the analysis, no component was detected. However, through this investigation, it was confirmed that some animal drugs, such as anesthetics, can remain without decomposition even at high temperature and pressure; therefore, there is a need for further investigation of other potentially hazardous substances not controlled in the feed.