• Title/Summary/Keyword: 불요 특성

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Preparation and Electrochemical Characterization of Activated Carbon Electrode by Amino-fluorination (아미노불소화 반응에 의한 활성탄소전극 제조 및 전기화학적 특성)

  • Lim, Jae Won;Jeong, Euigyung;Jung, Min Jung;Lee, Sang Ick;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.405-410
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    • 2011
  • High-performance of an electric double layer capacitance (EDLC) electrode was prepared by the amino-fluorination of activated carbon by using $NF_3$ gas. The pore structure and surface chemistry were investigated based on the specific capacitance of EDLC. The amino-fluorination of activated carbon introduced functional groups of nitrogen and fluorine which are beneficial for the specific capacitance of EDLC without the change of pore structures. The E-NF100AC electrode, which has nitrogen and fluorine functional groups less than 1 at%, showed the highly improved specific capacitance of 528 (${\pm}9$) F/g at 2 mV/s showing 122% improved value when comparing with that of non-functionalized E-RAC electrodes. Whereas, the E-NF200AC electrode, which has nitrogen and fluorine functional groups over 1 at%, showed the decreased specific capacitance because of perfluorinated introduction. So, it is concluded that the proper contents of nitrogen and fluorine groups improved the specific capacitance of EDLC.

Preparation and Characteristics of Heterogeneous Cation Exchange Membrane : 2. Characteristics Change on Post-treatment (PE계 불균질 양이온 교환막의 제조와 특성 : 2. 후처리에 따른 특성 변화)

  • Yang, Hyun S.;Cho, Byoung H.;Kim, Woong K.;Lee, Chang S.
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.67-75
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    • 1997
  • Heterogeneous cation exchange membrane consisting of cation exchange resin particles (diameter of less than $149{\mu}$) which are finely dispersed in a polyethylene matrix, were produced as forms of sheet. The characteristics were measured after treating hot water or saturated sodium chloride. When membranes were treated with hot water or saturated sodium chloride, cation exchange resin particles swell and expand pushing away the polyethylene matrix of membranes. The above treatment results the formation of narrow cavities between a cation exchange resin particles and polyethylene matrix, and the formation of fine micro-cracks on the polyethylene matrix. Thus, we were obtained good physical and electrochemical properties. On the treatment with hot water or saturated sodium chloride, the optimum conditions for good heterogeneous cation exchange membrane were treatment time of 30min and treatment temperature of $90^{\circ}C$.

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A STUDY ON PHYSICAL PROPERTIES OF FLOWABLE COMPOSITE RESINS (유동성 복합레진의 물리적 성질에 대한 연구)

  • Kim, Ji-Young;Jeong, Byung-Cho;Yang, Kyu-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.29 no.3
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    • pp.423-429
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    • 2002
  • Recently, the clinical uses of flowable composite resins have increased because of fast, convenient and excellent accessibility, but little has been reported about physical properties of flowable resins. The purpose of this study was to measure and compare the physical properties(compressive strength, relative flowability, relative radiopacity) of 4 contemporary flowable composite resins(Filtek flow, Tetric Flow, Revolution Palfique Estelite LV high flow). The results were as follows; 1. There were no significant differences between 4 flowable composite resins in compressive strength, but all were lower than that of traditional hybrid composite resin(p<0.001). 2. The relative flowability were increased in order of Palfique Estelite LV high flow, Revolution, Filtek flow, Tetric Flow and sealant(p<0.001), but there were no significant differences between Filtek flow and Tetric Flow. 3. There were significant differences between flowable composite resins in relative radiopacity and they showed similar or higher radiopacity than dentin(p<0.001), especially Tetric Flow and Filtek Flow showed higher radiopacity than enamel(p<0.001). This results suggested that the stress of application area have to be considered since flowable composite resins have lower compressive strength than hybrid composite, and the differences of flowability between these flowable composite resins can be considered when they are selected. All tested flowable composite resins showed optimal radiopacity to ISO's recommend.

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Effects of Oxyfluorination on Surface Graft Polymerization of Low Density Polyethylene Film and Its Surface Characteristics (함산소불소화가 저밀도 폴리에틸렌 표면의 그라프트 중합 및 그 표면 특성에 미치는 영향)

  • Yun, Seok-Min;Woo, Sang-Wook;Jeong, Eui-Gyung;Bai, Byong-Chol;Park, In-Jun;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.343-348
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    • 2010
  • The surface of low density polyethylene (LDPE) film was oxyfluorinated under different reaction conditions to introduce hydroperoxide groups and change surface characteristics. Hydroperoxide functional groups created by oxyfluorination were used as active sites for graft polymerization with hydrophobic monomer, acryl amide (AM), and hydrophilic monomer, methyl methacrylate (MMA) to carry out the second modification of the LDPE film surface. The surface properties of the OFPE films and grafted OFPE films were characterized by 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging method, ATR-IR, contact angle measurement and DSC. From the results of DPPH method, the amount of hydroperoxide groups on the oxyfluorinated LDPE film continuously increased as the total pressure in the oxyfluorination and the partial pressure of fluorine gas increased. The water contact angle and surface free energy measurements showed that hydrophilic liquid (water) contact angle on LDPE film surface decreased with hydrophilic AM grafting and hydrophobic liquid (methylene diiodide) contact angle on LDPE film surface decreased with hydrophobic MMA grafting. These were attributed to AM or MMA monomer grafting and the wettability of LDPE filmsurface to hydrophilic and hydrophobic liquids were improved.

Upper Mantle Heterogeneity Recorded by Microstructures and Fluid Inclusions from Peridotite Xenoliths Beneath the Rio Grande Rift, USA (미국 리오 그란데 리프트 페리도타이트 포획암의 미구조와 유체포유물에 기록된 상부맨틀의 불균질성)

  • Park, Munjae
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.273-281
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    • 2022
  • Mantle heterogeneity is closely related to the distribution and circulation of volatile components in the Earth's interior, and the behavior of volatiles in the mantle strongly influences the rheological properties of silicate rocks. In mantle xenoliths, these physicochemical properties of the upper mantle can be recorded in the form of microstructures and fluid inclusions. In this paper, I summarized and reviewed the results of previous studies related to the characteristics of microstructures and fluid inclusions from peridotite xenoliths beneath the Rio Grande Rift (RGR) in order to understand the evolution and heterogeneity of upper mantle. In the RGR, the mantle peridotites are mainly reported in the rift axis (EB: Elephant Butte, KB: Kilbourne Hole) and rift flank (AD: Adam's Diggings) regions. In the case of the former (EB and KB peridotites), the type-A lattice preferred orientation (LPO), formed under low-stress and low-water content, was reported. In the case of the latter (AD peridotites), the type-C LPO, formed under low-stress and high-water content, was reported. In particular, in the case of AD peridotites, at least two fluid infiltration events, such as early (type-1: CO2-N2) and late (type-2: CO2-H2O), have been recorded in orthopyroxene. The upper mantle heterogeneity recorded by these microstructures and fluid inclusions is considered to be due to the interaction between the North American plate and the Farallon plate.

Daeungbojeon Hall of Bulyeongsa Temple, Uljin and the Architectural Technique of the Features (울진 불영사(佛影寺) 대웅보전(大雄寶殿)의 특징(特徵)과 건축술(建築術))

  • Oh, Se-deok
    • Korean Journal of Heritage: History & Science
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    • v.47 no.1
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    • pp.46-65
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    • 2014
  • This study, under the title of Daeungbojeon Hall of Bulyeongsa Temple, Uljin and the architectural technique of the architect, aimed to make a comprehensive speculation on Daeungbojeon Hall of Bulyeongsa Temple whose accurate construction year was confirmed in 1725. While existing studies dealt with it separately between construction and Buddhist art history this study attempted to sort out it in one perspective by means of comparison with compatible objects in the area. The results are as follows. 1st, by means of comparison of wall painting of Daeungbojeon Hall of Bulyeongsa Temple and other wall paintings of Gyeongsang-do Province, it was estimated to be created before and after 1725, the founding year of the building. 2nd, the stylobate of Daeungbojeon Hall is the only and unique case that Guibu was supported by the bottom. Such stylobate was estimated to be built in the early period of Goryeo stylobate of PostLintel Construction which was more simplified than that of the traditional unified Silla period considering specific techniques. Lastly, by means of comparison of the architectural technique of Daeungbojeon Hall of Bulyeongsa Temple with other temples in Gyeongsang-do Province, the characteristics of the building were found. In particular, the same architectural technique was confirmed by direct comparison of style with Yeongsanjeon Hall of Tongdosa Temple in 1714 which was constructed by the same architect.

Influence of Inert Gas on the Configuration Characteristics of Premixed Turbulent Propagating Flames of Hydrogen Mixtures (수소 예혼합 난류전파화염의 화염형상 특성에 미치는 불활성 가스의 영향)

  • 나까하라마사야;키도히로유끼;김준효
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.4
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    • pp.632-640
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    • 2004
  • The purpose of this study is to clarify the influence of inert gas on the configuration characteristics of premixed turbulent propagating flames of hydrogen mixtures. Inert gas is changed to $N_2$, Ar, $CO_2$ and He keeping the laminar burning velocity of mixtures nearly the same value. A laser tomography technique was used to obtain the flame shape, and quantitative analyses were performed. The result shows that in the wrinkled laminar flame region, the surface area of turbulent flame is slightly dependent on the equivalence ratio and the kind of inert gas. It is also shown the region of convex part of flame toward the unburned gas is greater than that of toward the burned gas regardless of the kind of inert gas.

A Study on the Flame Extinguishing Characteristics of Inerting Gaseous Agents (불활성가스계 소화약제의 불꽃소화 특성에 관한 연구)

  • Kim, Sung-Min;Shin, Chang-Sub;Park, Jae-Man
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.04a
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    • pp.148-150
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    • 2008
  • Halon gas agent has been widely used as the extinguishing agent for B class and C class fires because of its excellent extinguishing power. But Halon was found to contribute to the ozone layer destruction, eventually Halon designated as one of ozone-layer-destroying materials in the Montreal Protocol in 1987, In this study, in the context of such researches, we measured the characteristics of flame concentrations of inert gaseous agents by Cup-burner method.

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A Study on the Characteristics of Impervious Area from Urban Watershed through Medium and Small Stream (중소하천을 통과하는 도시유역의 불투수면적 특성 연구)

  • Kim, Ik Hwan;Yang, Wan Seok;Song, Young Seok;Park, Moo Jong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.582-582
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    • 2015
  • 최근 하천에서 발생하는 침수피해는 대규모 하천보다는 중소규모의 하천이 전체의 약 50%이상 발생하고 있으며, 기후변화에 따른 강우량의 증가와 도시화에 따른 불투수층의증가로 인하여 도시유역을 통과하는 중소규모 하천에서의 침수피해는 증가하고 있다. 특히, 도시를 통과하는 중소하천의 경우 강우발생시 짧은 도달시간으로 갑작스런 침수피해가 발생하며, 최근 급격한 인구의 증가, 산업화 및 도시화로 인한 불투수면적의 증가로 도시유역의 유출특성이 변화되고 있다. 기존의 선행된 하천 연구는 주로 유역단위의 연구가 진행되었지만 하천이 통과하는 도시유역의 경우 대부분 합류지점에 도시지역이 밀집되어 있어 하천유역을 기반으로 하는 도시지역의 구분은 어려움이 있다. 따라서 본 연구에서는 기존 하천분류인 국가하천, 지방하천, 소하천에서 침수피해가 발생하는 지방하천과 소하천사이의 중소하천에 대한 구분 기준을 제시하고 중소하천의 유역의 불투수면적뿐만 아니라 하천 선을 중심으로 하천폭에 대한 불투수면적에 대하여 비교 분석하고자 한다.

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A Study on the Conservation of the Seated Stone Buddha and Its Scientific Characteristics (석조불좌상(石造佛坐像)의 보존과 과학적 특성 연구)

  • Jo, Yeontae
    • Conservation Science in Museum
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    • v.12
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    • pp.1-7
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    • 2011
  • The seated stone Buddha(Bon5190) of National Museum of Korea initially consisted of some 90 fragments, making it difficult to guess its overall appearance. Under a restoration work which lasted four months, the fragments were joined together, giving shape to a seated Stone Buddha in Bhumisparsa(earth touching) mudra and an associated figure of Bodhisattva missing the face. The statue was made from a single stone block by digging out the center. Traces of lacquer coating and a gilded layer above the lacquer coat were found in various parts. Polarizing microscopy and XRD analysis revealed that the stone was zeolite, a mineral formed through diagenesis of volcanic glassy ashes from trachytic tuff (Nuldaeri) and dacitic tuff (Guryongpo). In Korea, zeolite deposit found mostly in Gyeongsangbuk-do, in places like Yeonil, Guryongpo, Gampo and Ulsan. The restored statue of seated Buddha proved very similar in appearance to the seated stone Buddha of Deoksa Temple in Cheongdo-gun, Gyeongsangbuk-do (housed in Yeongsanjeon Hall). The scroll inside the statue, containing information about the background and circumstances of creation of this Buddhist sculpture, indicates that the monk Seung-ho took part in it as the head sculptor-monk.