• Journal of Life Science
• /
• v.15 no.1 s.68
• /
• pp.147-151
• /
• 2005

A$(-)-\alpha$-narcotine from Papaver sommiferum was refluxed with ethyl chloroformate to give the diastereomeric chloro-carbamate mixture and the Z/E-enol lactones as Z:E=1:1.1 ratio in HPLC analysis. After photoisomerization with UV (254 nm), the Z/E ratio was drastically changed to Z:E=7:1, which may indicate that the E-isomer was easily converted to the Z-isomer due to photoisomerization. The photoisomerization of the Z/E-enol lactones and the different stereochemistry of the degradation product of $\beta-narcotine$, deuterated $\beta-narcotine$ and $\beta-narcotine$ with ethyl chloroformate will also be discussed.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.36 no.2
• /
• pp.179-186
• /
• 2012

In the automobile industry, reducing the weight is the most important objective for reducing air pollution and improving the fuel efficiency. For this reason, the application of aluminum sheets is increasing. When the sheets are applied to the automobile, using inappropriate variables for the material, product design, and press processing can generate tearing, wrinkling, and spring-back problems, which are the main types of failure in the manufacturing process. Therefore, it is necessary to reduce these failures by harmonizing the many variables and strictly managing the processes. In this research, we study the theoretical plasticity instability of Al5454 and obtain the forming limit diagram (FLD) using MATLAB. Moreover, we compare the theoretical FLD with an experimental FLD obtained from a stretching test.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.34 no.4
• /
• pp.25-32
• /
• 2006

An advanced method of Relaxed Static Stability (RSS) is utilized for improving the aerodynamic performance of modern version supersonic jet fighter aircraft. The flight control system utilize RSS criteria in both longitudinal and lateral-directional axes to achieve performance enhancements and improve stability. The T-50 advanced trainer employs the RSS concept in order to improve the aerodynamic performance and the flight control law in order to guarantee aircraft stability. The longitudinal two modes are the short period with high frequency and the phugoid mode with low frequency. The design goals of longitudinal control laws is concerned with the short period damping and frequency optimization using lower order equivalent system and utilizing the requirement of MIL-F-8785C. Analysis of short period mode has been and continues to be performed This paper addresses the analysis of aircraft phugoid node characteristics such as damping, natural frequency, and analysis of aircraft pitch motion that impacted by angle of attack limiter and auto pitch attitude control law.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.33 no.1
• /
• pp.69-77
• /
• 2005

To optimize and limit the axial length of the baffle of the KSR-III engine, stability rating tests using pulse gun as one of artificial disturbance devices have been done. Generally a rocket engine can be considered to be dynamically stable if a certain imposed external perturbation or pressure oscillation in rocket combustion chamber could be suppressed within a short time period. Decay time and other parameters for the evaluation of stabilization ability of an engine to external perturbation have been analyzed to quantify stabilization capacity of engine, in other words, dynamic stability margin. Baffle not covering flame zone enough which can be considered as collision region of injector wasn't be able to suppress external perturbation sufficiently. The limit of combustion stability margin of engine is assumed to be 50 mm length baffle of the KSR-III engine.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.22 no.3
• /
• pp.46-52
• /
• 2018

A simple Crocco's $n-{\tau}$ time delay model and linear analysis of fluid flow coupled with acoustics are combined to investigate the high frequency combustion instability in the combustion chamber of LOX/hydrocarbon engines. The partial differential equation of the velocity potential is separated into ordinary differential equations, and eigenvalues that correspond to tangential resonance modes in the cylindrical chamber are determined. A general solution is obtained by solving the differential equation in the axial direction, and boundary conditions at the injector face and nozzle entrance are applied in order to calculate the chamber admittance. Frequency analysis of the transfer function is used to evaluate the stability of system. Stability margin is determined from the system gain and phase angle for the desired frequency range of 1T mode. The chamber model with variable baffle length and configurations are also considered in order to enhance the 1T mode stability of the combustion chamber.

• Polymer(Korea)
• /
• v.25 no.4
• /
• pp.536-544
• /
• 2001

We investigate, in the viewpoint of mathematical stability, the validity of the time-strain separability hypothesis employed in polymer viscoelasticity on the basis of experimental results. There have been suggested two distinct stability criteria such as Hadamard related to quick response and dissipative stability conditions, and in the limit of high deformation rate we have proved that separable constitutive equations are either Hadamard or dissipative unstable. The fact that the separability is not valid in the short time region in stress relaxation experiments exactly coincides with the results of our analysis. Therefore, since the application of the separability hypothesis incurs thermodynamic inconsistency as well as mathematical instability, such application should be avoided in the formulation of constitutive equations. In addition, careful attention should be paid to the limit of its validity even in experiments. It is also proved that there is neither theoretical nor physical validity of using the damping function.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.29 no.3B
• /
• pp.231-237
• /
• 2009

This study presents a numerical model to simulate density currents developing two dimensionally. The ${\kappa}-{\varepsilon}$ model is used for the turbulence closure. Elliptic flow equations are solved by the finite volume method. In order to investigate the applicability of the numerical model, discontinuous density currents are simulated numerically. The vortices due to the instability at the interface are simulated, showing a good agreement with the experimental visualizations in the literature. It is also investigated that the transition from slumping phase to inertial phase occurs when a bore generated at the end wall overtakes the front. However, the propagation of the density current is retarded compared with the experimental results. Two-dimensional modeling seems to have an effect on underestimating the front velocity of the density current.

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.04a
• /
• pp.64-67
• /
• 2003

Poly(trimethylene terephthalate)(이하 PTT)는 1941년 Caligo Printing Ink사의 Whinfield와 Dickson에 의해 중합 방법이 보고[1]된 이후 상업화를 위한 많은 학문적 연구가 이어져왔다. 그럼에도 불구하고 아직 PET에 비하여 기초 연구가 미비하며 상업적으로 사용하기에는 많은 불안정한 요소들을 가지고 있다. 앞선 연구자들이 밝힌바와 같이 PTT의 결정구조는 2개의 단량체가 1개의 unit cell을 이루면서 결정격자 내에서 O-C $H_2$-C $H_2$-C $H_2$-O가 trans-gauche-gauche-trans형의 coiled spring처럼 형성되어 좋은 elastic recovery와 뛰어난 신축성, 염색성 등 우수한 물성을 가지며 전반적인 성질은 PET와 Nylon의 중간성질을 뛰고 있지만 [2,3] 유리전이온도 (Tg : dir 4$0^{\circ}C$)와 냉결정화오도 ( $T_{ c cold}$ : dir 55$^{\circ}C$)사이의 차이가 15$^{\circ}C$ 정도이므로 섬유상에 많은 경시변화가 일으켜 구조적 불안정성을 가지게 한다 [4]. (중략)

• Proceedings of the Korean Society of Computer Information Conference
• /
• 2016.07a
• /
• pp.9-12
• /
• 2016

본 논문에서는 지진 및 재난상황을 신속하게 대중에게 전파하기 위해 상황실에서의 통제에 따라 정해진 경보방송을 수행하고, 대용량 스피커를 통해 출력할 수 있는 장치를 소개한다. 통신망은 VHF와 위성을 이용하는 이중화로 구성하여 재난발생 시 통신장애에 대한 서비스를 안정화하고, 통신부/제어부/입출력부/앰프부/전원부 등을 유니트로 설계하여 유지보수를 수월하게 할 수 있도록 구성하였다. 야외 환경에서 동작되는 장비는 먼지로부터 보호하고 방수기능이 포함되어 있으므로 밀폐형 함체 내부에 장착된다. 혹한 및 혹서의 날씨에도 장비 운영에 문제가 없도록 장비 내부에 히팅을 하고, 팬을 이용하여 공기 배출을 통해 온도 조절 기능을 수행한다. 배터리를 내장하여 불안정한 상용 전원 공급 조건에서도 안정적으로 운영될 수 있도록 설계하였다.

• Journal of Korean Association for Spatial Structures
• /
• v.20 no.2
• /
• pp.77-85
• /
• 2020

This paper examined the dynamic instability of a shallow arch according to the response characteristics when nearing critical loads. The frequency changing feathers of the time-domain increasing the loads are analyzed using Fast Fourier Transformation (FFT), while the response signal around the critical loads are analyzed using Hilbert-Huang Transformation (HHT). This study reveals that the models with an arch shape of h = 3 or higher exhibit buckling, which is very sensitive to the asymmetric initial conditions. Also, the critical buckling load increases as the shape increases, with its feather varying depending on the asymmetric initial conditions. Decomposition results show the decrease in predominant frequency before the threshold as the load increases, and the predominant period doubles at the critical level. In the vicinity of the critical level, sections rapidly manifest the displacement increase, with the changes in Instantaneous Frequency (IF) and Instant Energy (IE) becoming apparent.