• Title/Summary/Keyword: 불안정 조건

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A Study on the Stabilization of Monomeric MDI and Purification of Crude MDI (Crude MDI의 정제 및 Monomeric MDI의 안정화에 관한 연구)

  • Jung, Jong-Won;Kim, Young-Chul;Park, Nam-Cook
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.588-596
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    • 1996
  • The optimum conditions of the 1st and 2nd distillation had been investigated to obtaine a high quality monomeric MDI and fire reactive polymeric MDI by purification of crude MDI. Effect of additives on the monomeric MDI's color change, dimerization and the reactivity of polymeric MDI with standard polyol system has been tested. When the monomeric MDI yield is approximately 32%, 4,4'-MDI content is above 98% in the monomeric MDI at the 1st distillation. When the separation ratio of initial portion and residue percentage, reflux ratio are set at respectively, approximately 20wt%, 9wt%, above 2 in order to minimize the content of 2,4'-MDI in monomeric MDI, the freezing point of final distilled monomeric MDI is above $38.4^{\circ}C$. Since the monomeric MDI is inherently unstable in the room condition, monomeric MDI easily changes it's color and conducts self-polymerization reaction. To increase the stability of monomeric MDI, the composition of antioxidant, which is composed of phenolic 1st antioxidant, phosphorus 2nd antioxidant, UV absorbent and Hindered amine light stabilizer are used, and benzoyl chloride as antipolymerization agent test are that APHA color is less than 20, dimer content is remained less than 0.36wt% after 45 days storage of monomeric MDI.

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Analysis of the Structural Safety of a Wind-Protecting Wall Using ANSYS/CFX (ANSYS와 CFX를 이용한 방풍벽의 구조 안전성 분석)

  • Yum Sung-Hyun;Kim Chul-Soo;Choi Young-Don
    • Journal of Bio-Environment Control
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    • v.15 no.2
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    • pp.138-148
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    • 2006
  • This study was carried out to evaluate the structural safety fur both the attached wind-protecting wall in greenhouse and the detached one installed outside. Regarding the attached wind-protecting wall in greenhouse, the analysis was conducted by doing a fluid-structure coupled field analysis using both CFX-5.7 and ANSYS 8.1 and also under the design condition of an instantaneous maximum wind velocity of $30.9m{\cdot}s^{-1}$. Three kinds of the width ranged from 30 to 90cm were considered in this study. With regard to the detached wind-protecting wall, the structural saffty was analyzed under the pressure difference of 1,117 Pa which corresponded to a wind velocity of $50m{\cdot}s^{-1}$ and the analytical results were also compared with theoretical ones. The result showed that there was little difference in the distribution of velocity overall and total pressure on the lateral side according to the width of the attached wind-protecting wall, but greenhouse with wind-protecting widths of 30 to 60cm has been reinforced to the extent of about 11% when compared with the case of being without the wall. The result also showed that the detached wind-protecting wall with a main-column interval of 3m was not stable so that it was necessary for the detached wind-protecting wall to be adequately reinforced to secure structural stability. Finally, there was great difference between analytical results and theoretical studies. The difference meant that there was some possibility of including errors when a theoretical study was done in three dimensional structure.

Numerical Analysis of Vortex Induced Vibration of Circular Cylinder in Lock-in Regime (Lock-in 영역에서 원형실린더의 와류유기진동 전산해석)

  • Lee, Sungsu;Hwang, Kyu-Kwan;Son, Hyun-A;Jung, Dong-Ho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.29 no.1
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    • pp.9-18
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    • 2016
  • The slender structures such as high rise building or marine riser are highly susceptible to dynamic force exerted by fluid-structure interactions among which vortex-induced vibration(VIV) is the main cause of dynamic unstability of the structural system. If VIV occurs in natural frequency regime of the structure, fatigue failure likely happens by so-called lock-in phenomenon. This study presents the numerical analysis of dynamic behavior of both structure and fluid in the lock-in regimes and investigates the subjacent phenomena to hold the resonance frequency in spite of the change of flow condition. Unsteady and laminar flow was considered for a two-dimensional circular cylinder which was assumed to move freely in 1 degree of freedom in the direction orthogonal to the uniform inflow. Fluid-structure interaction was implemented by solving both unsteady flow and dynamic motion of the structure sequentially in each time step where the fluid domain was remeshed considering the movement of the body. The results show reasonable agreements with previous studies and reveal characteristic features of the lock-in phenomena. Not only the lift force but also drag force are drastically increasing during the lock-in regime, the vertical displacement of the cylinder reaches up to 20% of the diameter of the cylinder. The correlation analysis between lift and vertical displacement clearly show the dramatic change of the phase difference from in-phase to out-of-phase when the cylinder experiences lock-in. From the results, it can be postulated that the change of phase difference and flow condition is responsible for the resonating behavior of the structure during lock-in.

ESR Study on Paramagnetic Defects of the ${\gamma}$-Irradiated Sodium Thiosulfate Single Crystal (${\gamma}$-선에 조사된 티오황산나트륨 단결정의 상자성 결함에 관한 전자스핀공명 연구)

  • Jung Sung Yang
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.244-254
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    • 1983
  • Single crystals of sodium thiosulfate $(Na_2S_2O_3) have been grown from the saturated solution by the evaporation method at the optimum condition. Radiation damages in the crystal by ${\gamma}$-irradiation of $20{\times}10^6$ Rontgen have given rise to paramagnetic centers. The anisotropic spectra of each paramagnetic species have been obtained with the X-band EPR spectrometer at room temperature. When an isotropic D.P.P.H. at g value of 2.0036 is based on. ESR Spectra of the single crystal are recorded for each rotation about the perpendicular a, b and c axis with intervals of $10^{\circ}$ from $0^{\circ}$to $180^{\circ}$ in order to find out the properties of the crystal for anglar variation of the anisotropic peaks. The g values are calculated from the line position between the anisotropic peaks and the isotropic peaks of D.P.P.H. and then principal g values and their direction cosines of the species is obtained by the diagonalization of 9 matrix elements of the corresponding g values. From the analysis of the characteristic principal g values and direction cosines for ${\gamma}$-irradiated $Na_2S_2O_3$ crystal, anisotropic peaks corresponding to $SO_2^+, SO_2^- $are identified and the existences of unidentified and unstable paramagnetic defects are verified.

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Functional analysis of isolated posterior cruciate ligament deficient subjects (후방 십자 인대 단독 손상 환자의 기능적 분석)

  • Kim Jin Goo
    • Journal of Korean Orthopaedic Sports Medicine
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    • v.3 no.1
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    • pp.66-72
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    • 2004
  • Purpose: To evaluate the compensatory mechanism in vivo and develop the treatment guide by performing the comprehensive functional tests of the posterior cruciate ligament (PCL) deficient subjects. Material and Methods: 10 PCL deficient subjects and 10 healthy control group were evaluated. Performed functional tests were range of motion, posterior drawer test, Telos, 30$^{\circ}$ flexion wt-bearing view, KT-1000 arthrometer, gait analysis, EMG test and isokinetic tests. Results: Physical, KT-1000, Telos posterior tests showed significant differences, but 300 full weight bearing lateral view, muscle strength test revealed no difference between two groups. Less knee flexion at initial contact and reduced maximum valgus moment were observed in PCL deficient group. In vertical drop landing, PCL group had increased plantar flexion angle at initial contact. Conclusion: Compensatory mechanisms such as reduced unstable components and absorbing the maximal load of the joint were occurred after PCL insufficiency, which result in good clinical and functional outcomes. Further investigations would be needed to understand the functional adaptations of PCL deficient subjects.

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The Present State of Occupational Injuries and Prevention on East Side of Korea Fishing (동해안 연근해 어업의 산재현황과 예방대책)

  • Song, Jae-Seok;Choi, Hong-Soon;Seo, Jong-Chul;Kwak, Youn-Hee;Park, Woong-Sub;Kim, Sang-Ah;Yoon, Yi-Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.2
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    • pp.78-82
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    • 2005
  • Fishermen have higher risk of occupational injuries and disease due to frequent machine usage and direct contact to live biological materials. Moreover, growing elderly workers makes the susceptibility to occupational injuries and disease higher. This study was performed to investigate the occupational safety and health status among fishermen. The interview was carried out at Jumunjin and Geojin ports which were representative port at North East side of Korea. The structured questionnaire were used to interview the fishermen from AM 6:00 to PM 11:00 and total respondent were 97 workers. The results were followed; 7 fishermen of all respondents experienced occupational injuries during their work, 5 fishermen were needed to admission longer than 4 days. The injury types were contusion(4 persons), fracture(1 persons) and amputation(2 persons). The cause of injury might be the lack of caution and the unstability of working condition. These results suggested the ergonomical evaluation of working condition and proper management. But there was limited concern and studies on the policy on occupational safety and health on fishermen. So, further study was required to establish the sound policy of fishermen's occupational safety and health.

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Community Analysis of Oribatid Mites(Acari: Oribatida) in Namsan and Kwangreung Coniferous Forests (남산과 광릉 침엽수림의 날개응애 군집분석)

  • 박홍현;이준호
    • Korean journal of applied entomology
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    • v.39 no.1
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    • pp.31-41
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    • 2000
  • Community analysis of oribatid mites was conducted in Namsan and Kwangreung coniferous forests which have been received by different degrees of environmental pressures through urbanization processes. Oribatid mites were sampled in the litter and soil layer of study sites from May 1993 to October 1994. Although two sites have been under similar weather condition, seasonal changes in oribatid mites density did not show a synchronized pattern. Density in spring and summer showed stable pattern with low fluctuations, but unstable pattern in autumn between 1993 and 1994. And these patterns were highly correlated with precipitation. The density and species number were higher in the litter layer than in the soil layer and showed no typical seasonal changes. The dominant species were Scheloribates latipes (1 l.78%), Pergalumna altera (8.92%), Eohypochthonius crassisetiger (7.58%), Scheloribates sp. (6.89%) and Suctobelbella yezoensis (5.04%) in Namsan, and Ceratozetes japonicus (25.72%), Punctoribates punctum (14.15%), Trichogalumna nipponica (10.96%) and Ramusella sengbuschi (5.08%) in Kwangreung. The number of species with high constany were 10 and 18 in Namsan and Kwangreung, respectively. Namsan showed the feature of urban forests. In analysis of species diversity, species richness was significantly higher in Kwangreung than in Namsan, while shannon (H') and evenness index (J') were higher in Namsan than in Kwangreung. The values of shannon index (H') in Namsan and Kwangreugn were 2.83 and 2.62, respectively and evenness index (J') were 0.78 and 0.67, respectively. The value of similarity index between two sites was 0.68.

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The Stabilization of 20.0% Ascorbic Acid in Aqueous Cosmetic Formulation (아스코빅애씨드 고함량 안정화 수계 조성물 제조 방법)

  • Park, Jeong Mi;Eun, So Hee;Ko, Eun Ah;Han, Sang Keun;Kang, Hak Hee;Hyun, Seung Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.2
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    • pp.125-131
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    • 2018
  • Ascorbic acid (Vitamin C) has been widely used in skin care formulations. Due to its remarkable effects on anti-oxidation, collagen biosynthesis and whitening, ascorbic acid is considered as an effectible anti-aging active ingredient. But, the instability problems of ascorbic acid in cosmetic formulation such as oxidation, browning and changes in smell is the difficult issue to be overcome for the application of high concentration of ascorbic acid. We tried to stabilize the ascorbic acid in non-aqueous liquid formulation that contains polyol solvent at first. The non-aqueous system was effectible to reduce oxidation. But, ascorbic acid was crystallized in the non-aqueous formulation at the low temperature below $5^{\circ}C$. We tried to develop way to stabilize the ascorbic acid in aqueous solutions to solve the crystallizing problem. In this study, we search the optimal ratio of antioxidant combination, such as zinc sulfate, glutathione and curcuma longa (turmeric) root extract. Formulations were stored at - $16^{\circ}C$, $5^{\circ}C$, $25^{\circ}C$, $40^{\circ}C$, $50^{\circ}C$ and cycle($5-40^{\circ}C$) (in incubator) for a period of eight weeks to investigate their stability. In the stability analysis, the test parameters consisted of color, scent, phase separation and sedimentation. Ascorbic acid stability was checked by HPLC analysis.

C2H5OH-CH2OHCH2OH-Ca(OH)2-CO2계에서의 비정질탄산칼슘의 결정화 연구

  • Kim, Hwan;Ahn, Ji-Whan
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.3-27
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    • 1996
  • 분체의 입자 배열이 불규칙한 경우뿐만 아니라 입자 크기가 극미세하여 X선회절분석이 불가능한 경우에도 비정질물질이라 한다. 수용액 속에서 이런 비정질 물질을 합성하기 위해서는 합성용액의 과포화도를 높여 계속 유지시킴에 따라 극미세 1차핵 생성의 지속적인 유도에 따른 입자 성장을 최대한 억제시켜야만 한다. 본 연구에서는 흡습제, 칼슘제 및 식품 첨가제 등으로 이용되는 비정질 탄산칼슘을 계에서 합성하고, 이때 생성된 비정질 상태의 겔을 수용액 환경을 변화시켜가면서 따라 결정화를 유도하고 탄산칼슘의 동질이상을 관찰하였다. CO2의 유속을 11/min, 교반속도를 600rpm으로 고정시키고, Ca(OH)2의 양을 10g에서 50g까지 변화시켜가면서 겔 상태의 비정질 탄산칼슘을 합성하였다. 이때 전기전도도는 CO2의 용해와 더불어 Ca(OH)2의 용해도가 증가함에 따라 변화하였으며, 반응종반부에는 겔화가 시작될 때까지 거의 일정하였다. 따라서, 이러한 사실들로부터 현탁액 내에서의 전기전도도의 변화는 Ca이온의 영향을 받는 것으로 사료된다. 비정질 탄산칼슘은 수용액에서 불안정하여 CO2 가스를 방출하면서 급격히 결정화되는데, 본 연구에서는 Ca(OH)2의 양을 20g으로 하여 위의 방법에 의해 얻어진 겔을 수용액의 종류와 농도 및 결정화 온도, 교반속도를 달리하면서 결정화시켰다. 교반속도를 100rpm으로 하여 물의 온도변화에 다라 결정화시킨 경우 전 온도범위에서 칼사이트상이었으며, 물의 온도가 5$^{\circ}C$일 경우에는 미세한 입자들이 응집된 형태였으나, 그 외의 온도변화조건에서는 모두 평균입경 0.4$\mu\textrm{m}$정도의 비교적 균일하 능면체 형태였다. 또한 교반속도를 500rpm으로 증가시켰을 경우에는 8$0^{\circ}C$에서 침상의 아라코나이트가 소량생성되었음을 SEM사진으로 관찰할 수 있었으며, 소량의 바테라이트도 혼재되어 결정화되었음을 XRD결과로 알 수 있었다. 교반속도를 100rpm으로 한 NH4Cl 0.5mol/l 수용액에서는 입자의 형태와 크기가 불규칙한 칼사이트로 결정화되었으며, MgCl2 0.05mol/l 수용액의 경우에는 순수한 H2O의 경우에서와는 달리 2$0^{\circ}C$에서는 모서리가 무딘 매우 균일한 크기의 칼사이트 입자가 관찰되었으며, 6$0^{\circ}C$부터는 아라고나이트가 생성됨을 관찰할 수 있었다. 따라서, 고온(8$0^{\circ}C$)의 농도 MgCl2 수용액(0.1, 0.2 mol/l)에서 교반속도를 높여(800rpm) 겔을 결정화시킨 결과 아라고나이트의 생성수율이 증가되는 것을 확인할 수 있었다.

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A Study on Effect of Temperature on Particle Size Distribution of Nickel Ferrite (온도의 영향에 따른 니켈페라이트의 입자 크기 분포 연구)

  • Ahn, Hyung-Kyoung;Lee, In-Hyoung;Jeong, Hyun-Jun;Park, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1768-1774
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    • 2008
  • The particulate behaviors of nickel ferrite were investigated under the simulated PWR shutdown chemistry conditions. Temperature of the simulated water with concentration of 0.1 ppm Li and 2,000 ppm B was dropped from $300^{\circ}C$ to $150^{\circ}C$ with a rate of $0.625^{\circ}C/min$ and then constantly maintained at $150^{\circ}C$ under the pressure of 2,500 psi. The on-line particle counting and the concentration measurement of nickel dissolved were performed under 5, 15 and 25 cc/kg $H_2O$ dissolved hydrogen. Experimental results showed that total particle count in the simulated water was not greatly changed for three hydrogen concentrations as temperature was decreased. However, particles were smaller as temperature was decreased and then maintained constantly. The degree of variation in particle size distribution was greater at 15 cc/kg $H_2O$ dissolved hydrogen than any other dissolved hydrogen concentrations. Concentration of nickel ion was increased as temperature was decreased and was higher at 15 cc/kg $H_2O$ dissolved hydrogen than any other dissolved hydrogen concentrations. Theses results show that nickel ferrite is unstable with temperature variation and at dissolved hydrogen concentration of 15 cc/kg $H_2O$.