• KSBB Journal
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• v.15 no.5
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• pp.497-500
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• 2000

Liposomes and proteoliposomes, artificial membranes, can interact with many solutes, such as drugs, peptides and proteins. The immobilization of (prot대)liposomes as supramolecular aggregates on gold surfaces have potential applications in nano and biosensor technology. We demonstrated a quartz crystal analyzer (QCA) based method to monitor the construction of multi-layers of unilamellar liposomes based on avidin-biotin binding on gold surfaces using a quartz crystal microbalance (QCM). Thus, the QCA provides an on line and efficient method of detecting the construction of protein membranes, which has applications in biosensing systems.

• Journal of Korea Foresty Energy
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• v.17 no.1
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• pp.47-55
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• 1998

In the search for broadband damping composites, it is desirable to have polymers with a broad and high loss region, covering the entire temperature and frequency range of interest. Interpenetrating polymer networks, IPN's, are materials composed of two or more crosslinked polymers intimately and irrevocably interwinded. The resulting distribution of microenviron-ments can result in a materials with a high mechanical loss broad end over that of either polymer component alone. In this study, several series of copolymer, crosslinked copolymer and copolymer/copolymer IPN's were synthesized for possible use as broadband damping materials. Then their dynamic tensile properties were measured and compared with the damping properties of sandwich composites. Dynamic mechanical analysis showed that the temperature of loss peak may be varied over a wide temperature range with formulation. The compatibility of IPN`s was depended on the compatibility of A and B polymers as well as crosslink density. The damping factor(tan ${\delta}_c$) of composites became greater when a polymer of approximate storage module(E`) range of 5X10$^7$ to 10$^9$ dyne/cm$^2$ and large tan ${\delta}$ at the same time was used. The damping properities of poly (2-EHA80-co-St20)/poly(2-EHA20-co-St80) IPN`s crosslinked with 3%-DEGDM were relatively better over a broad temperature range.

• Journal of the Mineralogical Society of Korea
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• v.30 no.4
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• pp.161-172
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• 2017

Clay minerals play a major role in the geochemical cycles of metals in the Critical Zone, the Earth surface-layer ranging from the groundwater bottom to the tree tops. Atomistic scale research of the very fine particles can help understand the fundamental mechanisms of the important geochemical processes and possibly apply to development of hybrid nanomaterials. Molecular dynamics (MD) simulations can provide atomistic level insights into the crystal structures of clay minerals and the chemical reactivity. Classical MD simulations use a force field which is a parameter set of interatomic pair potentials. The ClayFF force field has been widely used in the MD simulations of dioctahedral clay minerals as the force field was developed mainly based on dioctahedral phyllosilicates. The ClayFF is often used also for trioctahedral mineral simulations, but disagreement exits in selection of the interatomic potential parameters, particularly for Mg atom-types of the octahedral sheet. In this study, MD simulations were performed for trioctahedral clay minerals such as brucite, lizardite, and talc, to test how the two different Mg atom types (i.e., 'mgo' or 'mgh') affect the simulation results. The structural parameters such as lattice parameters and interatomic distances were relatively insensitive to the choice of the parameter, but the vibrational power spectra of hydroxyls were more sensitive to the choice of the parameter particularly for lizardite.

• Journal of the Korean Chemical Society
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• v.47 no.5
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• pp.439-446
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• 2003

Surface-enhanced Raman(SER) spectroscopy was utilized to investigate the adorption orientation of the 4-biphenylcarboxylic acid(BPCA) derivatives, such as 4'-cyano-BPCA(c-BPCA), 4'-mercapto-BPCA(m-BPCA), and 4'-amino-BPCA(a-BPCA), which were adsorbed on Au and Ag colloid monolayers. For the systematic approach, information regarding the adsorption behavior of benzoic acid, biphenyl, and BPCA was applied to the target molecules. From the spectral behaviors of benzene ring, C-H stretching, carboxylate anion, and the other finger printing vibrational modes, it was concluded that only the m-BPCA was adsorbed tilt with thiol group being adsorbed on Au surface, whereas the other molecules were adsorbed flat on both Au and Ag surfaces.

• Journal of the Korean Chemical Society
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• v.54 no.6
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• pp.671-679
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• 2010

The geometrical parameters and binding energies of the benzene ion-water complex [$C_6H_6^+-(H_2O)_n$(n=1-5)] have been investigated using ab initio (MP2) and density functional theory (DFT) with large basis sets. The harmonic vibrational frequencies and IR intensities are also determined to confirm that all the optimized geometries are true minima. Also zero-point vibrational energies have been considered to predict the binding energies. The predicted binding energy of 8.6 kcal/mol for $C_6H_6^+-(H_2O)$ at the MP2/aug-cc-pVTZ level of theory is in excellent agreement with recent experimental result of $8.5{\pm}1$ kcal/mol.

• Journal of the Korean Chemical Society
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• v.55 no.6
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• pp.905-911
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• 2011

The possible minimum structures of $C_{60}(CH_2)_nOH$ (n=0~2) and $C_{60}(OH)_2$have been optimized using density functional theory (DFT) with the 6-311G (d,f) basis set. The harmonic vibrational frequencies and IR intensities are also determined to confirm that all the optimized geometries are true minima. Also zero-point vibrational energies (ZPVE) have been considered to predict the binding energies. The predicted binding energy of $C_{60}CH_2OH$ is about 10 kcal/mol more stable than the binding energy of $C_{60}OH$.

• Nuclear Engineering and Technology
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• v.5 no.4
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• pp.265-278
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• 1973

The incoherent neutron scattering cross section of molecular liquids is analyzed using a damping function model for correlation functions of molecular translations and rotations. The present approach is different from recent works in that the scattering function is evaluated directly, not through the intermediate scattering function. The damping fuction is determined from a simple relation between its long-wavelength limit and the generalized frequency distribution function, and translation-rotation couplings are assumed to be neglected. A physical model is used for the translational motions of center-of-mass of a molecule, including properly its short-time and long-time behaviors. A simple model for the rotational motions is suggested which relates the damping function to the Fourier transform of the dipole correlation function, or equivalently, the infrared vibrational absorption spectrum. Theoretical absolute scattering intensities are computed for liquid methane and shown to be in satisfactory agreement with both thermal and cold neutron measurements.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.05a
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• pp.63-64
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• 2006

본 연구에서는 광에너지를 화학적인 에너지로 변환할 때, 디바이스의 전하전달 매개를 위한 electron transfer mediator로서 널리 이용되는 Viologen이 자기조립화된 수정진동자률 전기화학법의 하나인 순환전압전류법(Cyclic Voltammetry)을 이용하여 산화 환원 반응 (redox reaction) 특성과 주사속도와 피크전류와의 상관관계를 분석하였다. 먼저 수정진동자를 친수 처리한 후, 메탄올 용액과 아세토니트릴 용액을 섞은 용매에 Viologen 분자를 자기조립 (self-assembly)하여, 전해질 용액의 농도 변화에 따른 산화 환원반응 특성과 피크전류의 값을 측정하였다 주사 속도를 2 배씩 증가하여 피크전류와의 상관관계를 조사한 결과, 선형적인 증가를 보였으며, 이를 통해 가역적인 반응(reversible reaction)이 일어났음을 확인할 수 있었다. 또한, 산화 환원 반응과 동시에 측정된 수정진동자의 공진 주파수(resonant frequency) 변화로부터 전하이동(charge transfer) 특성에 의해 반응에 참가한 이온의 질량을 알 수 있었다.

• Korean Journal of Optics and Photonics
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• v.15 no.2
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• pp.177-182
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• 2004

We have observed the saturated absorption spectrum of the P(16) line of the V$_1$＋V$_3$ band of $^{13}$ C$_2$H$_2$ molecule by using the external cavity spectroscopy method. The frequency of laser has been stabilized to the saturated absorption spectrum. The relative contrast of the saturation spectrum is about 7 % with respect to the linear absorption and the linewidth is about 1.8 MHz. The frequency fluctuation of the stabilized LD is about $\pm$20 KHz during the sampling time 100 S.

• 한국생물공학회:학술대회논문집
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• 2000.04a
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• pp.546-549
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• 2000

Liposomes and proteoliposomes, artificial membranes, can interact with many solutes, such as drugs, peptides and proteins. Immobilization of (proteo)liposomes as supramolecular aggregates on gold surfaces have potential applications in nanotechnology and biosensors. We demonstrate a quartz crystal analyzer (QCA) method to monitor the construction of multi layers of unilamellar liposomes based on avidin-biotin binding on gold surface using quartz crystal microbalance(QCM). Thus, QCA provides an on line and efficient method to detect the protein membranes construction and have applications to biosensing system.