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http://dx.doi.org/10.5012/jkcs.2003.47.5.439

Raman Spectroscopy Study on the Adsorption Orientation of Biphenylcarboxlic Acid Derivatives  

Heay Ran Choi (Department of Chemistry, Kunsan National University)
Kyu Seok Choi (Department of Chemistry, Kunsan National University)
Il Ki Jung (Department of Chemistry, Kunsan National University)
Hong Seok Song (Department of Chemistry, Kunsan National University)
Keun Ok Han (Department of Chemistry, Kunsan National University)
Ho Seob Choi (Department of Chemistry, Kunsan National University)
Sang Hee Lee (Department of Chemistry, Kunsan National University)
Soo-Chang Yu (Department of Chemistry, Kunsan National University)
Publication Information
Journal of the Korean Chemical Society / v.47, no.5, 2003 , pp. 439-446 More about this Journal
Abstract
Surface-enhanced Raman(SER) spectroscopy was utilized to investigate the adorption orientation of the 4-biphenylcarboxylic acid(BPCA) derivatives, such as 4'-cyano-BPCA(c-BPCA), 4'-mercapto-BPCA(m-BPCA), and 4'-amino-BPCA(a-BPCA), which were adsorbed on Au and Ag colloid monolayers. For the systematic approach, information regarding the adsorption behavior of benzoic acid, biphenyl, and BPCA was applied to the target molecules. From the spectral behaviors of benzene ring, C-H stretching, carboxylate anion, and the other finger printing vibrational modes, it was concluded that only the m-BPCA was adsorbed tilt with thiol group being adsorbed on Au surface, whereas the other molecules were adsorbed flat on both Au and Ag surfaces.
Keywords
SERS; Monolayer,; BPCA; Adsorption Orientation; Au; Ag;
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