• Title/Summary/Keyword: 발수성

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A Study on Insulation·Fire Proof Materials Using Silica Aerogels (실리카 에어로젤을 이용한 단열·내화재 개발에 관한 연구)

  • Cho, Myung Ho;Hong, Sungchul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6816-6822
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    • 2015
  • In this study, silica aerogel-glass wool composites were developed for improvement of thermal conductivity and overcoming the water adsorption of glass wool boards. Silica aerogel-glass wool composites were prepared by glass wool and silica aerogel with liquid binder. Mixtures with binder were composed of CMC (carboxymethyl cellulose) and silica aerogel for glass wool board. Silica aerogel-glass wool composite boards were had $0.065g/cm^3$ density by impregnation silica aerogel where from origin glass wool board at $0.048g/cm^3$ density. Thermal conductivity of silica aerogel-glass wool composites were 0.0315 W/mK (up to 7.4% thermal resistance) and fire penetration time came to 362 seconds (up to 2.7 times stronger than origin glass wool board). In addition, hydrophobic aerogel characteristics prevented the adsorption of water onto silica aerogel-glass wool composite boards that was good for lightweight.

Study on Application of Urethane Materials for Hardening of Metal Artifacts (금속유물 강화처리를 위한 우레탄 수지의 적용성 연구)

  • Lee, Ho-Yeon;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.415-420
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    • 2011
  • Urethane coating agent was made up in order to prevent corrosion on metal relics. This urethane coating agent was designed to solve problems linked to gloss and discoloration caused by existing acrylic coating agent which is mainly applied to metal relics. For the purpose, the urethane coating agent was made up which has lower gloss and slight color change. This coating agent formed thinner coating layer with excellent adhesion compared to the existing agent and has outstanding resistance to the surface oxidization of metal relics and water repellent on the surface. In addition, the agent is considered a stable coating agent replacing current acrylic coating agent with showing easy dissolution in organic solvents such as acetone, toluene and xylene with excellent result in reversible reaction.

Reaction Path Modeling of Granitic Cultural Properties and Its Implication for Preservation (화강암질 석조문화재의 풍화반응경로 특성과 보존에 대한 제언)

  • Park Maeng-Eon;Sung Kyu-Youl
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.83-92
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    • 2005
  • Dissolution rate of minerals may differ from climates configuration, but weathering rate of feldspars is generally proved to be relatively higher The result of geochemical reaction modeling indicates the acid water of pH 4.5 excluding any other variables, was 2.3 times higher than that in ordinary rain of pH 5.7. This result proved that pH is very important factor in preservation of granite cultural properties. To prevent the weathering of stone cultural properties, weathering characteristics of stones should be studied first and constitution of dry environments, using water repellent or oil coating, isolating water which cause chemical weathering reaction like hydration and oxidization should be considered. Considering the long-term reactions between granite and rain, selection of materials, which can bring neutralization and non-oxidization conditions, are very important in using cleaning agents and biological controls.

Preliminary Study of the Leaching Resistance of Boron from Borate Treated Wood by the Dual Treatment with Water-Repellent Preservative and Methyl Metacrylate (방부성(防腐性) 발수제(撥水劑)와 methyl metacrylate 이중처리(二重處理)에 의(依)한 붕소화합물(硼素化合物) 처리재(處理材)로부터 붕소(硼素)의 용탈(溶脫) 저항성(抵抗性)에 관(關)한 기초연구(基礎硏究))

  • Kim, Gyu-Hyeok;Ra, Jong-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.4
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    • pp.13-18
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    • 1994
  • Sapwood samples of pitch pine were treated with disodium octaborate alone by dip-diffusion, or in combination with water-repellent preservative(WRP) and methyl metacrylate(MMA). Treated samples were subjected to an accelerated leaching test for determining the improvement of leaching resistance and to soft rot and mold tests for evaluating the increase in bioefficacy, due to the addition of WRP and MMA applied as a second treatment. The addition of WRP and MMA retarded leaching of boron to some extent from treated samples and this retardation can be explained by improved water repellency of WRP and MMA treated samples. Borate /WRP and borate /MMA systems will not qualify borate treated wood for ground and fresh water contact use but may improve performance of borate treated wood in above-ground applications not subjected to continuous wetting conditions. Bioefficacy against soft rot fungi and mold fungi was improved by a second treatment with WRP. However, improvement in the performance of borate /MMA systems was not observed. Considering improvement in both resistance of leaching and bioefficacy against micro fungi by the treatment of WRP and MMA, simultaneously, the dual treatment of borate treated wood by MMA containing co-biocides might be believed as an ideal treatment system.

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Influence of Painting Materials based on Wasted Oil and Applying Timing on Carbonation and Chloride Resistances of High Volume SCM Concrete (폐유지류를 중심으로 한 도포제 종류 및 도포시기 변화가 혼화재 다량치환 콘크리트의 탄산화 및 염해저항성에 미치는 영향)

  • Han, Cheon-Goo;Choi, Young-Doo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.228-236
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    • 2015
  • In this research, the influence of painting materials and applying timing on carbonation and chloride resistances of high volume SCMs concrete was evaluated. As a durability improving method, comparative tests were conducted with painting materials of ERCO (emulsified refined cooking oil), RCO (refined cooking oil), WR (water repellent agent), and ERCO + WR and with painting timings of right after demolding, and 28 days after the wet curing. From the experiment results, in the case of carbonation and chloride resistance, the carbonation depth and chloride penetration depth were decreased when the painting materials were applied in 28 days of wet curing. Additionally, for painting materials, with the order of ERCO, RCO, ERCO+WR, and WR, the carbonation and chloride penentration was delayed. Hence it is considered that ERCO shows the most favorable performance of resistance against carbonation and chloride penetration.

Mobility of Nitrate and Phosphate through Small Lysimeter with Three Physico-chemically Different Soils (소형 라이시메터시험을 통한 토양특성에 따른 질산과 인산의 이동성 비교)

  • Han, Kyung-Hwa;Ro, Hee-Myong;Cho, Hyun-Jun;Kim, Lee-Yul;Hwang, Seon-Woong;Cho, Hee-Rae;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.4
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    • pp.260-266
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    • 2008
  • Small lysimeter experiment under rain shelter plastic film house was conducted to investigate the effect of soil characteristics on the leaching and soil solution concentration of nitrate and phosphate. Three soils were obtained from different agricultural sites of Korea: Soil A (mesic family of Typic Dystrudepts), Soil B (mixed, mesic family of Typic Udifluvents), and Soil C (artificially disturbed soils under greenhouse). Organic-C contents were in the order of Soil C ($32.4g\;kg^{-1}$) > Soil B ($15.0g\;kg^{-1}$) > Soil A ($8.1g\;kg^{-1}$). Inorganic-N concentration also differed significantly among soils, decreasing in the order of Soil B > Soil C > Soil A. Degree of P saturation (DPS) of Soil C was 178%, about three and fifteen times of Soil B (38%) and Soil A (6%). Prior to treatment, soils in lysimeters (dia. 300 mm, soil length 450 mm) were tabilized by repeated drying and wetting procedures for two weeks. After urea at $150kg\;N\;ha^{-1}$ and $KH_2PO_4$ at $100kg\;P_2O_5\;ha^{-1}$ were applied on the surface of each soil, total volume of irrigation was 213 mm at seven occasions for 65 days. At 13, 25, 35, 37, and 65 days after treatment, soil solution was sampled using rhizosampler at 10, 20, and 30 cm depth and leachate was sampled by free drain out of lysimeter. The volume of leachate was the highest in Soil C, and followed by the order of Soils A and B, whereas the amount of leached nitrate had a reverse trend, i.e. Soil B > Soil A > Soil C. Soil A and B had a significant increase of the nitrate concentration of soil solution at depth of 10 cm after urea-N treatment, but Soil C did not. High nitrate mobility of Soil B, compared to other soils, is presumably due to relatively high clay content, which could induce high extraction of nitrate of soil matrix by anion exclusion effect and slow rate of water flow. Contrary to Soil B, high organic matter content of Soil C could be responsible for its low mobility of nitrate, inducing preferential flow by water-repellency and rapid immobilization of nitrate by a microbial community. Leached phosphate was detected in Soil C only, and continuously increased with increasing amount of leachate. The phosphate concentration of soil solution in Soil B was much lower than in Soil C, and Soil A was below detection limit ($0.01mg\;L^{-1}$), overall similar to the order of degree of P saturation of soils. Phosphate mobility, therefore, could be largely influenced by degree of P saturation of soils but connect with apparent leaching loss only more than any threshold of P accumulation.

The effect of air quality and humidity on aged characteristics of beeswax-treated paper during artificial aging (인공열화 시 공기질 및 습도가 밀랍지의 열화에 미치는 영향)

  • Yang, Eun Jeong;Choi, Kyoung Hwa;Kang, Yeong Seok;Cho, Jung hye;Jeong, Hye Young
    • 보존과학연구
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    • s.33
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    • pp.45-55
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    • 2012
  • A beeswax-treated paper has no air permeability but has the water repellency compared with a general Hanji. Because of these properties, the differences of the aging factors and mechanisms between the outer partition of beeswax-treated paper that is affected by the surrounding conservation environment and the inner partition of it that is not affected are bigger than general books. In this research, we analyzed and compared the aging characteristics through the accelerated aging of the beeswax-treated paper by some air and humidity conditions. The results of the physical and optical analysis after the artificial aging, it was shown that the oxygen accelerates the aging of the beeswax-treated paper and the condition with the humidity 50% RH is more stable than the condition with the humidity 0% RH. The results of the CG/MS analysis that was conducted to figure out the decomposition charateristics of the beeswax according to the air quality and the humidity, a low molecular weight compound that the number of carbon is C9-C20 including a fatty acid such as a palmitic acid was increased as the aging was progressed. However, under the same environment, a compound that the number of carbon is C21-C36 including a hydrocarbon and a aliphatic alcohol and a high molecular weight compound that the number of carbon is more than C34 including a wax ester were decreased. A rate of change according to the air quality and the humidity was similar to the beeswax-treated papers.

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A Study on Stability of Inorganic Binder for Application as Conservation Material for Stone Monuments (석조문화재 보수물질로의 적용을 위한 무기질 바인더 안정성 연구)

  • Kim, Dae Sik;Do, Jin Young;Cho, Hyen Goo
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.4
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    • pp.251-262
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    • 2014
  • Inorganic binders were studied in order to apply a conservation material for stone monument. A pure inorganic binder and 3 species of inorganic binder which contain additives on the basis of a pure inorganic binder were selected as test samples. Through the application of inorganic binders on Geochang granite investigate their influences on stone. pH 4.0 and 5.6 acid solution, respectively were manufactured on the basis of the acidity of domestic rainfall. Alkaline water with pH 8.0 and deionized water with pH 6.85 were prepared as control group. Changes in weights of inorganic binders were not definite according to the acidity of water while weight losses in inorganic binder type were greater after reaction with the water. The compressive strengths of pure inorganic binder was largest before the test but its decrease rate were larger after reaction with the water. Water absorption rate of inorganic binders are 6.72 to $12.44kg/m^2{\cdot}t^{1/2}$ after reaction with the water. Such high absorption was considered that it forced water to move deep into inorganic binder and made the components of inorganic binder dissolve. Acidities of the water of pH 4.0, 5.6, 6.85 and 8.0, respectively were changed to pH 9.0-10.0 after reaction with the inorganic binders. Ion concentrations in the water changed after reaction with the inorganic binders and $Mg^{2+}$, and $K^+$ significantly increased, dissolved from the binder. The high concentration of ions detected showed that the binder reacted with water and formed white salts with high solubility such as $MgSO_4{\cdot}nH_2O$, $KNO_3$. Ion concentrations significantly decreased from the binder after treatment with consolidant and water repellent.

Prognosis of Replanted Permanent Incisors after Avulsion Injury: A Retrospective Study (완전탈구 후 재식한 영구 절치의 예후에 대한 후향적 연구)

  • Lee, Hyungsub;Kim, Youngjin;Kim, Hyunjung;Kim, Sohyun;Nam, Soonhyeun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.43 no.3
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    • pp.254-263
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    • 2016
  • Many studies on the prognosis of avulsed teeth were published but follow-up studies on Korean children and adolescents are insufficient. The aim of this study was to identify clinical factors determining the healing and prognosis of permanent incisors that were replanted after avulsion injury. This study included 184 permanent teeth in 142 patients aged 6-14 years. The clinical and radiographic data of the patients were analyzed from electronic medical records. Immature teeth had a higher probability of pulp revascularization than mature teeth. When extra-alveolar time was longer than 60 minutes, the incidence of inflammatory root resorption (IRR) was higher in immature teeth than mature teeth. However, the incidence of replacement root resorption (RR) was higher in mature teeth than immature teeth under the same condition. The incidence of IRR was increased when pulp was extirpated more than 20 days after replantation. IRR had a more significant influence on the decrease of survival expectation than RR. There was no significant correlation between the root development stage and survival expectation. However, when RR occurred, immature teeth survived shorter than mature teeth. Long term follow-up results from this study are expected to be used as fundamental data for the treatment guidelines and evaluation of the prognosis of replanted teeth.

Enhanced Flame Retardancy of Cotton Fabric by Functionalized Graphene Oxide and Ammonium Polyphosphate (기능성화 산화 그래핀과 폴리인산암모늄을 이용한 직물 난연성 향상)

  • Ka, Dongwon;Jang, Seongon;Jung, Hyunsook;Jin, Youngho
    • Composites Research
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    • v.33 no.4
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    • pp.177-184
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    • 2020
  • Flame retardant(FR) clothes prohibit additional fire diffusion and make the personnel do their tasks without a hitch in a flammable environment. The existing FR clothes, however, are heavy and give high thermal fatigue. Therefore, it is strongly demanded to develop a light, convenient, and eco-friendly clothes. Recently, many works have been reported to make FR fabrics with phosphorus compounds, but their performance could not satisfy the specified criteria in appraisal standards of domestic and American FR clothes or combat uniforms. In this paper, two kinds of phosphorus compounds were applied to cotton fabric. Graphene oxide functionalized with a phosphorus-rich deep eutectic solvent and ammonium polyphosphate were coated on cotton fabric by eco-friendly padding procedure. The coated fabrics were analyzed with thermogravimetric analysis, vertical flame resistance test(ASTM D6413), cone calorimeter test(ISO 5660-1), and method of test for limited flame spread(ISO 15025). It was revealed that the as-made cotton with those two materials simultaneously had better flame resistance than the cottons with each one. Furthermore, an additional coating for hydrophobicity on the FR cotton was tried for better washing fastness.