• Elastomers and Composites
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• v.14 no.3
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• pp.161-168
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• 1979

이 논문(論文)의 목적(目的)은 열적안정성(熱的安定性) 및 내노화성면(耐老化性面)에 있어서 디엔제3성분단위체(第三成分單位體)(diene termonomer)의 각각(各各)의 종류(種類)가 EPDM의 중합체(重合體)의 성질(性質)에 미치는 효과(效果)를 구명(究明)하는데 있다. 제3성분단위체(第三成分單位體) 5종(種)으로 각각(各各) 다음과 같다. 즉, ethylidene norbonene(ENB), butadiene(BD), dicyclopentadiene(DCPD), methyltetrahydroindene (MTHI) 및 1,4-hexadiene(HD)이다. 이들을 써서 만든 각각(各各)의 EPDM은 동(同)몰의 불포화도(不飽和度)로 만들어졌다. 또한 가황계(加黃系)는 동일(同一)한 황/촉진제계(黃/促進劑系)를 사용(使用)하였다. ENB-EPDM이 순(純)고무배합체(配合體) 및 충전제함유배합체(充塡劑含有配合體)의 가황(加黃)에 있어서 모두 함께 가장 빠른 가황속도(加黃速度)를 보였다. HD-EPDM은 순(純)고무배합체(配合體)에서 가황속도(加黃速度)가 가장느렸으나 충전제함유배합물(充塡劑含有配合物)에서는 DCPD-EPDM보다는 발랐다. BD-EPDM을 제외(除外)한 이들 중합체(重合禮)는 거의 같은 초기가교밀도(初期架橋密度)를 갖는다. 가교밀도(架橋密度) 및 가교형(架橋型)을 분석(分析)하여 보면 BD-EPDM 쇄(鎖)에서 부타디엔 단위(單位)는 블럭을 이루고 있다. 또한 HD-EPDM은 순(純)고무가황체(加黃體) 및 충전제배합가황체(充塡劑配合加黃體)에 있어서 원가교결합(原架橋結合)의 50%가 monosulfide의 구조(構造)를 가지고있다. 이외(外)의 4종(四種)의 EPDM 폴리머는 보다 낮은 monosulfide구조를 가진다. $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 ENB 및 HD폴리머는 약(約) 65% monosulfide 가교(架橋) 및 거의 동일(同一)한 파괴에너지값$(E_b)$을 가진다. 그러나 1,4HD의 원가교(原架橋)의 monosulfide 구조함량(含量)이 보다 높다고 해서 그의 내노화성(耐老化性)이 다른 폴리머보다 더 좋다고는 생각되지 않는다. DCPD는 $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 똑같은 monosulfide가교(架橋)를 가지나 노화온도(老化溫度)가 $259^{\circ}C(500^{\circ}F)$로 높아짐에 따라 monosulfide 함량(含量)도 증가(增加)한다. $550^{\circ}F(287.7^{\circ}C)$의 노화온도(老化溫度)에서는 EPDM폴리머의 모든 가교(架橋)가 monosulfide구조가 되나 전가교밀도(全架橋密度) 및 $E_b$ (신장률(伸長率), 절단시(切斷時)의)는 대단(大端)히 낮은 것으로 나타나는데 이것은 산화(酸化)에 의한 노화(劣化)에 기인(基因)되는 것으로 보인다. 질소기류(窒素氣流)속에서의 TGA의 분석결과(分析結果)를 보면 EPDM 가황체(加黃體)는 $800\sim935^{\circ}F(427\sim502^{\circ}C)$의 온도범위(溫度範圍)에서 분해(分解)되며 공기중(空氣中)에서는 $750\sim935^{\circ}F$ 범위(範圍)에서 분해(分解)한다.

• Journal of Korea Water Resources Association
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• v.47 no.5
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• pp.483-490
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• 2014

The design procedures for a biological reactor and a secondary settling tank (SST) of an activated sludge system are based on the steady state design method (Ekama et al., 1986; WRC, 1984) and the 1-D flux theory design method (Ekama et al., 1997), respectively. This study combined both of the design procedures, to determine the optimum sludge concentration in the reactor and the best design with the lowest cost. The best design of the reactor volume and the SST diameter at the optimum sludge concentration were specified with varying wastewater and sludge characteristics, temperature, sludge retention time (SRT) and peak flow rate. The effects of the influent wastewater characteristics, such as substrate concentration and unbiodegradable particulate fraction, were found to be considerable, but the effect of unbiodegradable soluble fraction was to be negligible. The effects of sludge settling characteristics, were also significant. SRT, as an operating parameter, was found to be an important factor for determining the optimum sludge concentration. However, the effect of temperature was found to be small. Furthermore, for designing a large scale wastewater treatment plant, the number of reactors or SSTs could be estimated, by dividing the total reactor volume or SST area. The new combined design procedure, proposed in this research, will be able to allow engineers to provide the best design of an activated sludge system with the lowest cost.

• Journal of the Korean Vacuum Society
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• v.10 no.2
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• pp.241-246
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• 2001

Single or dual ion implantations were performed onto the transparent polyethylene terephthalate(PET) sheet, and the surface hardness and the light transmittance in the visual-UV range were examined. Nanoindentation showed that the surface hardness was the highest at about 50 nm depth from the surface and was increased by about 3 times when nitrogen ions were implanted with energy and dose of 90 keV and $1\times10^{15}\textrm{/cm}^2$ respectively. When dual ions such as He+N and N+C ions were implanted into PET, the hardness was increased even more than the case only N ions were implanted. Especially, when PET were implanted with N+C dual ions, the surface hardness of PET increased 5 times more as compared to when implanted with N ions alone. The light at the 550 nm wavelength(visual range) transmitted more than 85%, which is close to that of as-received PET, and at the wavelength below 300 nm(UV range) the rays were absorbed more than 95% as traveling through the sheet. implying that there are processing parameters which the ion implanted PET maintains the transparency and absorbs the UV rays. It can be considered that the increase in the hardness of polymeric materials is attributed to not only cross linking but also forming hard inclusions such as hard C-N compounds, as evidenced by the formation of the highest hardness when both N and C ions are implanted onto PET.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.420-429
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• 2002

The amount of $CO_2$-silicate bonded waste foundry sand(WFS) occurred in Korea is over 800,000 ton per year. WFS, as a by-product, is generated through manufacturing process of foundry may affect our environmental contamination, The reason is that WFS has been buried itself not less than 90％ out of total WFS. So, it can give damage on the ground of contamination in soil and underwater. Therefore, it is necessary to establish the method recycling WFS because of being intensified waste management law. In this study, we performed the research with respect to harmful component analysis, the qualities of WFS mortar and concrete mixed with WFS. As the results the specific gravity of WFS is the same as that of natural aggregate while unit weight and percentage of solids of WFS are smaller than those of it. But it is found that WFS can be used by substituting WFS for natural aggregate after control of poor grade of WFS. The flowability of mortar and concrete with WFS is inferior to those of natural aggregate, and the setting time of concrete with WFS is faster than that with only natural aggregate, On the contrary, the bleeding of concrete with WFS is shown good result, and compressive and tensile strength of concrete substituted WFS for 30％ are higher than those with only natural aggregate regardless of elapsed time.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.291-298
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• 2002

Recently, construction of reinforced concrete tall buildings is widely increased according to the improvement of material quality and design technology. Therefore, differential shortenings of columns due to elastic, creep, and shrinkage have been an important issue. But it has been neglected to predict the Inelastic behavior of RC structures even though those deformations make a serious problem on the partition wall, external cladding, duct, etc. In this paper, analysis system for prediction and compensation of the differential column shortenings considering time-dependent deformations and construction sequence is developed using the objected-oriented technique. Developed analysis system considers the construction sequence, especially time-dependent deformation in early days, and is composed of input module, database module, database store module, analysis module, and analysis result generation module. Graphic user interface(GUI) is supported for user's convenience. After performing the analysis, the output results like deflections and member forces according to the time can be observed in the generation module using the graphic diagram, table, and chart supported by the integrated environment.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.449-456
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• 2002

Recently, the application of high strength and high performance concrete has been gradually increased as an important construction material for high rise and huge scaled construction. However, high performance concrete has undesirable characteristics of spalling subjected to high temperature due to its dense microstructure content. A spalling by fire brings surface failure and falling off concrete member. It is considered that spalling by fire should be taken into account for the safety of the concrete structure under fire. Therefore, in this paper, tests are carried out using high performance concrete containing polypropylene(PP) fiber in order to improve the fire resistance performance. PP fiber contents and member sizes are varied. According to experimental results, as for the influence of PP fiber contents, all the test specimens without PP fiber show entire failure in W/C of 35％, while they show nearly sound shape except some kinds of surface fracture in W/C of 55％. When PP fiber is contained more than 0.07％, favorable prevention effects of spatting by fire are obtained. As for the effects of test specimens size, it tends to increase the possibilities of spatting by fire as test specimens become larger. And spatting by fire at the edge of test specimens occurs more frequently than at the surface of test specimens. Residual compressive and tensile strength shows 45∼65 ％ of its original strength at W/C of 35％, and 30∼40％ at W/C of 55 ％.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.121-127
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• 2011

In this study, possible use of indigenous natural loess (Hwangtoh) as a new binding material via geopolymerization process is examined. Hwangtoh pastes with four different mix proportions of varying alkali liquid concentrations (6 M, 8 M) and the constituents of the binder as well as the alkali liquid at a constant liquid-to-binder ratio of 0.55 were prepared. Analysis of the natural loess (Hwangtoh) paste was carried out as follows : 1) Measurement of compressive strength and weight of cubic specimens versus curing time; 2) Analysis by X-ray diffraction (XRD) and scanning electron microscope (SEM) about reaction product; 3) Porosity analysis of hardened Hwangtoh paste. The result showed that it is possible to prepare Hwangtoh paste with 29.1 MPa at the age of 7 day by using alkali solution (made as 1 : 4.5 the mass ratio of liquefied $Na_2SiO_3$ and NaOH solution and applying the curing temperature of $60^{\circ}C$). Compressive strength development with respect to the degree of moisture evaporation from the paste seems to be independent of curing temperature. Therefore, it seems that higher early strength of the paste specimens cured at higher temperature can be attributed to both higher rate of reaction and moisture evaporation.

• Journal of the Korea Concrete Institute
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• v.22 no.2
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• pp.179-186
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• 2010

The bond between steel and concrete in reinforced concrete members is essential to resist external load, but the bond mechanism in reinforced concrete beams deteriorated by steel corrosion has not been clearly known yet. Most existing researches have dealt with the bond behavior of corroded steel under monotonic loading, but scarce are researches dealing with bond behavior of corroded steel under repeated loading. This study includes the experimental investigation on the bond behavior with respect to the various degrees of steel corrosion under repeated loading. According to the test results, the bond strength of corroded steel under monotonic loading increases as the rate of steel corrosion increases unless the splitting crack occurs. The slip versus number of load cycles relation was found to be approximately linear in double logarithmic scale, not only in specimens without steel corrosion but also in specimens with steel corrosion. The test results also show that the steel corrosion does not negatively affect the bond strength of corroded steel after repeated loading unless the splitting crack occurs. But the fatigue life decreases sharply after splitting crack occurs. This research will be helpful for the realistic durability design and condition assessment of reinforced concrete structures.

• 한국지구과학회:학술대회논문집
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• 2010.04a
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• pp.98-98
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• 2010

그라우팅은 지반의 공학적인 강도증가를 통한 지지력 향상 및 암반의 투수성 저감을 통해 지하수 유동을 억제하기 위하여 대규모 토목공사 현장의 균열암반 및 댐 또는 제방 등의 지역에서 많이 시행되고 있다. 본 연구는 균열암반지역에서 그라우팅 효과 확인을 위하여 보통 포틀랜드 시멘트(OPC)와 마이크로 시멘트(MC)를 사용하여 그라우팅을 수행하였으며, 그라우팅 전후에 물리검층(시추공영상촬영, 초음파 텔레뷰어검층)을 이용하여 그라우팅 효과 정도를 파악하였다. 연구지역은 경상북도 영주시 평은면 지역으로, 지질은 선캠브리아기 안구상편마암에 시대미상의 흑운모 화강암이 관입을 하였고, 이를 제4기의 충적층이 부정합으로 피복되어 있다. 그라우팅은 일반구간과 단층대구간으로 구분하여 실시하였으며, 두 구간의 이격거리는 서로의 간섭을 피하기 위해 약 40m 간격으로 선정하였다. 주입재(OPC, MC)는 5개의 주입공에서 triangle 방향으로 주입하였으며, 주입정도를 확인하기 위하여 각 구간에 2공씩 확인시추를 하였다. 두 개의 site중 일반구간의 보통 포틀랜드시멘트 주입결과 평균주입량은 48.2kg/공이며 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 1.62kg/m이며, 마이크로시멘트의 평균주입량은 49.6kg/공이며 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 3.86kg/m로 나타났다. 단층대 구간에서는 보통 포틀랜드시멘트의 평균주입량이 40.0kg/공이며, 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 2.75kg/m이며, 마이크로 시멘트는 평균주입량이 56.5kg/공, 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 3.15kg/m로 나타났다. 마이크로시멘트의 주입압은 보통 포틀랜드시멘트에 비해 상대적으로 낮았으며, 그라우팅 개선효과 역시 상대적으로 양호한 것으로 나타났다. 그라우팅 효과확인을 위한 물리검층의 초음파텔레뷰어 해석결과 상대암반강도는 주입전 $250{\sim}750\;kgf/cm^2$, 주입후는 $400{\sim}800\;kgf/cm^2$으로 그라우팅에 의한 암반강도의 상승을 확인할 수 있었고, 시추공영상촬영 분석에서는 시추코어만으로 얻기 힘든 시멘트 충진구간을 직접 확인할 수 있었다. 초음파텔레뷰어의 경우 파쇄대의 분포 및 암반강도 측정을 통한 그라우팅 파악은 가능하였으나 파쇄대 충진물을 확인할 수가 없는 단점이 있었고 이를 시추공영상촬영을 통해 보완할 수 있었다. 다만 물리검층의 경우 그라우팅에 의한 공의 손실로 동일공에 의한 반복 조사가 아닌 경우가 대부분이어서 그라우팅 효과에 대한 정확한 비교가 어려웠으며 추후 이를 보완하기 위한 계속적인 연구가 필요할 것으로 사료된다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.3
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• pp.261-267
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• 2015

To develop high-strength high-volume ground granulated blast-furnace slag (GGBFS) concrete, this study investigated the characteristics of strength development and durability of concrete with the water-to-binder ratio of 23% and the GGBFS replacement ratio of up to 65%. The results show that the compressive strength of GGBFS blended concrete is lower than that of ordinary Portland cement (OPC) concrete up to 3-day age, but the becomes higher after 7-day age. Together with strength increase, the pore structure becomes tighter, and thus the resistance to chloride ion penetration increases. Therefore, the GGBFS blended concrete has high resistance to freezing and thawing without additional air-entraining, and high resistance to carbonation despite low amount of calcium hydroxide ($Ca(OH)_2$). On the other hand, if silica fume (SF) is blended with GGBFS, the strength becomes lower than that of the concrete blended with GGBFS only, and the resistance to chloride ion penetration deceases. Therefore, it needs further studies on the reaction of SF in high-strength high-volume GGBFS concrete.