• Title/Summary/Keyword: 기구합성

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A Study on Electromagnetic Environment of Marine Ship (해상 선박의 전자파환경에 대한 연구)

  • Kim Dong-Seek;Park Young-Hwan;Cho Hyung-Rae;Min Kyeong-Sik
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.3 no.2 s.5
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    • pp.119-128
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    • 2004
  • Recently, the accidents on the sea have arisen due to the increase of the nautical traffic and the digitization of equipments for marine. Therefore, IMO(International Maritime Organization) have provided the recommendation of EMI and EMS for radio communication and equipments of marine from SOLAS convention at July 1st 2002. In this paper, we measured EMC environment on the Hanbada, which is Korea Maritime University training ship, for basic EMC environment of ship. The measuring point was Bridge and Engine Control Room of the ship, we measured at the test point that was set at random. Measured Band is from 30 MHz to 2 GHz, polarization measurement is processed both vertical and horizontal polarization. We analysed the results in consideration of permissible criteria.

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Solvent Extraction of Cu(II) by 2,4-Heptadione in Chloroform (2, 4-Heptadione에 의한 Cu(II)의 용매추출특성)

  • Shin, Jeong-Ho;Jeong, Kap-Seop;Lee, Sang-Hoon;Park, Sang-Wook;Park, Dae-Weon
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.672-682
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    • 1993
  • 2, 4-Heptadione(abbreviated to 24HTD) was synthesized from methylpropyl ketone and ethyl acetate with sodium amide, and the equilibrium and the kinetic characteristics of copper extraction by 24HTD-chloroform were investigated. Equilibrium constants such as the dissociation constant and the distribution coefficient of 24HTD and the stability constant of the 24HTD-Cu chelate were evaluated from the spectrophotometry, and the overall equilibrium constant of the extraction was also determined. The extracted species of the 24HTD-Cu chelate was found to be $CuR_2$ and the initial rate of the extraction of coupper by 24HTD in chloroform was expressed by $R_0=k[\bar{HR}]([Cu^{2+}]/[H^+])^{0.5}$.

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An efficient hardware implementation of 64-bit block cipher algorithm HIGHT (64비트 블록암호 알고리듬 HIGHT의 효율적인 하드웨어 구현)

  • Park, Hae-Won;Shin, Kyung-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.9
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    • pp.1993-1999
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    • 2011
  • This paper describes a design of area-efficient/low-power cryptographic processor for HIGHT block cipher algorithm, which was approved as standard of cryptographic algorithm by KATS(Korean Agency for Technology and Standards) and ISO/IEC. The HIGHT algorithm, which is suitable for ubiquitous computing devices such as a sensor in USN or a RFID tag, encrypts a 64-bit data block with a 128-bit cipher key to make a 64-bit cipher text, and vice versa. For area-efficient and low-power implementation, we optimize round transform block and key scheduler to share hardware resources for encryption and decryption. The HIGHT64 core synthesized using a 0.35-${\mu}m$ CMOS cell library consists of 3,226 gates, and the estimated throughput is 150-Mbps with 80-MHz@2.5-V clock.

Synthesis of TiN/TiB2/Ti-silicides Nanocomposite Powders by Mechanochemical Reaction and its Reaction Mechanism (기계화학반응에 의한 TiN/TiB2/Ti-silicides 나노복합분말의 합성과 반응기구)

  • Cho Young-Whan;Kim Ji-Woo;Shim Jae-Hyeok;Ahn Jae-Pyoung;Oh Kyu-Hwan
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.273-278
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    • 2005
  • Nanostructured TiN/$TiB_2$/$TiSi_2$ and TiN/$TiB_2$/$Ti_5Si_2$ composite powders have been prepared by mechanochemical reaction from mixtures of Ti, BN, and $Si_3N_4$ powders. The raw materials have reacted to form a uniform mixture of TiN, $TiB_2$ and $TiSi_2$ or $Ti_5Si_3$ depending on the amount of $Si_3N_4$ used in the starting mixtures, and the reaction proceeded through so-called mechanically activated self-sustaining reaction (MSR). Fine TiN and $TiB_2$ crystallites less than a few tens of nanometer were homogeneously dispersed in the amorphous $TiSi_2$ or $Ti_5Si_3$ matrix after milling for 12 hours. These amorphous matrices became crystalline phases after annealing at high temperatures as expected, but the original microstructure did not change significantly.

A Study in EMC Environment Measuring of Marine Ship (선박의 EMC 환경 측정에 관한 연구)

  • Kim, Dong-Seek;Cho, Hyung-Rae;Min, Kyeong-Sik
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.141-146
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    • 2005
  • Recently, the accidents on the sea have arisen due to the increase of the nautical traffic and the digitization of equipments for marine. Therefore, IMO(International Maritime Organization) have provided the recommendation of EMI and EMS for radio communication and equipments of marine from SOLAS cobvention at July 1st 2002. In this paper, we measured EMC environment on the HANBADA, which is Korea Maritime University training ship, for basic EMC environment of a ship. The measuring point was Bridge and Engine Control Room of the ship, we measured the test point that was set at random. Measured Band is from 30 MHz to 2 GHz, polarization measurement is processed both vertical and horizontal polarizaion. We analysed the results in consideration of permissible criteria.

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An implementation of block cipher algorithm HIGHT for mobile applications (모바일용 블록암호 알고리듬 HIGHT의 하드웨어 구현)

  • Park, Hae-Won;Shin, Kyung-Wook
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.125-128
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    • 2011
  • This paper describes an efficient hardware implementation of HIGHT block cipher algorithm, which was approved as standard of cryptographic algorithm by KATS(Korean Agency for Technology and Standards) and ISO/IEC. The HIGHT algorithm, which is suitable for ubiquitous computing devices such as a sensor in USN or a RFID tag, encrypts a 64-bit data block with a 128-bit cipher key to make a 64-bit cipher text, and vice versa. For area-efficient and low-power implementation, we optimize round transform block and key scheduler to share hardware resources for encryption and decryption. The HIGHT64 core synthesized using a $0.35-{\mu}m$ CMOS cell library consists of 3,226 gates, and the estimated throughput is 150-Mbps with 80-MHz@2.5-V clock.

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Synthesis and Formation Mechanism of Cobalt Doped Willemite Blue Pigments (Co-Doped Willemite 파란색 안료의 합성과 생성기구)

  • Hwang, Dong-Ha;Han, Kyong-Sop;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.603-607
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    • 2010
  • Turquoise blue pigment of Vanadium-zircon blue (DCMA number 14-42-2), which was already commercialized, was stable to be reproduced but insufficient to give strong blue. However, it possible to obtain more intense blue by partially substituting cobalt ions into the willemite($Zn_2SiO_4$) lattice classified into DCMA number 7-10-2 for blue ceramic pigment. By the composition of willemite $Co_xZn_{2-x}SiO_4$(X=0.01, 0.03, 0.05, 0.07, 0.09 mole), this study used reagent grade zinc oxide, cobalt oxide and silicon dioxide as starting materials, carrying out the synthesis with solid reaction method by adding $H_3BO_3$ as a mineralizer. The firing temperature was between $1200^{\circ}C$ and $1400^{\circ}C$. The characteristics of synthesized pigment were analyzed by X-ray diffraction, Raman spectroscopy and SEM and the characteristics of color tones were analyzed by UV-Vis spectroscopy and CIE-$L^*a^*b^*$ measurement. As a result, the optimal composition was $Zn_{1.95}Co_{0.05}$ with 1wt% of $H_3BO_3$ as a mineralizer and firing condition was $1350^{\circ}C$/3 h. $L^*a^*b^*$ value was 29.25, 41.03, -59.93 for on glaze pigment and 37.03, 36.41, -60.03 for under glaze pigment.

Synthesis and Formation Mechanism of ZrTiO4 Gray Pigment (ZrTiO4계 Gray 안료 합성과 형성기구)

  • Hwang, Dong-Ha;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.84-89
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    • 2012
  • Attempts were made to develop a stable gray pigment at reducing atmosphere, substituting Ti in $ZrTiO_4$ with Mn, Fe, Co and Cu The pigment synthesized at $1300~1500^{\circ}C$ by solid state method with the composition of $ZrTi_{1-x-y}A_xB_yO_4$ (x = y = 0.005, 0.015, 0.035, 0.055, 0.075, 0.095, 0.115, 0.135, 0.155, 0.175 and 0.195 mole, A = Mn(III), Fe(III), Co(II, III) and Cu(II) (chromophores), B = Sb (counterion). The pigments were fired at $1400^{\circ}C$ for 3 h with substitute amount changes of Mn, Fe, Co and Cu to $ZrTiO_4$ crystals, and analyzed by Raman spectroscopy to figure out substitute limits. Results indicated 0.035 mole for Mn, 0.115 mole for Fe, 0.015 mole for Co and 0.015 mole for Cu as substitute limits, respectively. Figs. 1, 2, 3, and 4 represent each substitute pigments of Mn, Fe, Co and Cu. Synthesized pigment was applied to a lime and a lime-magnesia glaze at 7 wt% each, and fired at reducing atmosphere of $1240^{\circ}C$, soaking time 1h. Gray color was obtained with CIE-$L^*a^*b^*$ values at 44.55, -0.65, 1.19(Mn), 40.36, -0.90, 0.30(Fe), 42.63, -0.03, -1.49(Cu) and -40.79, -0.28, -0.91(Co), respectively.

Growth mechanism of InP and InP/ZnS synthesis using colloidal synthesis (반응 용기법을 이용한 InP/ZnS 양자점 합성과정에서 InP 코어의 성장기구)

  • Seo, Han wook;Jeong, Da-woon;Lee, Bin;Hyun, Seoung kyun;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.24 no.1
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    • pp.6-10
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    • 2017
  • This study investigates the main growth mechanism of InP during InP/ZnS reaction of quantum dots (QDs). The size of the InP core, considering a synthesis time of 1-30 min, increased from the initial 2.56 nm to 3.97 nm. As a result of applying the proposed particle growth model, the migration mechanism, with time index 7, was found to be the main reaction. In addition, after the removal of unreacted In and P precursors from bath, further InP growth (of up to 4.19 nm (5%)), was observed when ZnS was added. The full width at half maximum (FWHM) of the synthesized InP/ZnS quantum dots was found to be relatively uniform, measuring about 59 nm. However, kinetic growth mechanism provides limited information for InP / ZnS core shell QDs, because the surface state of InP changes with reaction time. Further study is necessary, in order to clearly determine the kinetic growth mechanism of InP / ZnS core shell QDs.

Design of the Fixed-Bed Catalytic Reactor for the Maleic Anhydride Production (무수마레인산 생산을 위한 고정층 촉매 반응기 설계)

  • Yoon, Young Sam;Koo, Eun Hwa;Park, Pan Wook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.467-476
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    • 1999
  • This paper analyzed the behavior of fixed-bed catalytic reactor (FBCR) which synthesizing maleic anhydride(MA) from the selective oxidation of n-butane. The behavior of FBCR describing convection-diffusion-reaction mechanism is examined by using two-dimensional pseudohomogeneous plug-flow transient model, with the kinetics of Langmuir-Hinshelwood type. Prediction model is composed by optimum parameter estimation from temperature profile, yield and conversion of single FBCR on operating condition variations of Sharma's pilot-plant experiment. A double FBCR with same yield and conversion for single FBCR generated a $8.96^{\circ}C$ lower hot spot temperature than a single FBCR. We could predict parametric sensitivity according to the variation of possible operating condition (temperature, concentration, volumetric flow of feed reactant and coolant flow rate) of single and double FBCR. Double FBCR showed the behavior of more operating range than single FBCR. Double FBCR with nonuniform activities could assure safety operation condition for the possible variation of operating condition. Also, double FBCR had slightly higher than the single FBCR in conversion and yield.

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