Browse > Article
http://dx.doi.org/10.4191/kcers.2012.49.1.084

Synthesis and Formation Mechanism of ZrTiO4 Gray Pigment  

Hwang, Dong-Ha (Department of Material Science & Engineering, Myongji University)
Lee, Byung-Ha (Department of Material Science & Engineering, Myongji University)
Publication Information
Journal of the Korean Ceramic Society / v.49, no.1, 2012 , pp. 84-89 More about this Journal
Abstract
Attempts were made to develop a stable gray pigment at reducing atmosphere, substituting Ti in $ZrTiO_4$ with Mn, Fe, Co and Cu The pigment synthesized at $1300~1500^{\circ}C$ by solid state method with the composition of $ZrTi_{1-x-y}A_xB_yO_4$ (x = y = 0.005, 0.015, 0.035, 0.055, 0.075, 0.095, 0.115, 0.135, 0.155, 0.175 and 0.195 mole, A = Mn(III), Fe(III), Co(II, III) and Cu(II) (chromophores), B = Sb (counterion). The pigments were fired at $1400^{\circ}C$ for 3 h with substitute amount changes of Mn, Fe, Co and Cu to $ZrTiO_4$ crystals, and analyzed by Raman spectroscopy to figure out substitute limits. Results indicated 0.035 mole for Mn, 0.115 mole for Fe, 0.015 mole for Co and 0.015 mole for Cu as substitute limits, respectively. Figs. 1, 2, 3, and 4 represent each substitute pigments of Mn, Fe, Co and Cu. Synthesized pigment was applied to a lime and a lime-magnesia glaze at 7 wt% each, and fired at reducing atmosphere of $1240^{\circ}C$, soaking time 1h. Gray color was obtained with CIE-$L^*a^*b^*$ values at 44.55, -0.65, 1.19(Mn), 40.36, -0.90, 0.30(Fe), 42.63, -0.03, -1.49(Cu) and -40.79, -0.28, -0.91(Co), respectively.
Keywords
Zirconium titatnate; $ZrTiO_4$; Color properties; Gray ceramic pigment; Co; Cu; Mn; Fe;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 B. D. Hosterman, "Micro-Raman Spectroscopic Study of the Corrosion of Stainless Steel by Lead-Bismutheutectic(in America)," pp. 1-60, Ph. D. Thesis, University of Nevada, Las Vegas, Las Vegas, 2001.
2 D. L. A. Faria, S. V. Silva, and M. T. Oliveira, "Raman Microspectroscopy of Some Iron Oxides and Oxyhdroxides," J. Raman. Spectrosc., 28 873-78 (1997).   DOI   ScienceOn
3 H. F. Goldstein, D. S. Kim, P. Y. Yu, and L. C. Bourne, "Raman Study of CuO Single Crystals", Phys. Rev. B., 41 [10] 7192-94 (1990).   DOI   ScienceOn
4 C. W. Tang, T. Y. Leu, W. Y. Yu, C. B. Wang, and S. H. Chien, "Characterization of Cobalt oxides Studied by FT-IR, Raman, TPR and TG-MS", Appl. Catal. B, 48 267-74 (2004).   DOI   ScienceOn
5 A. S. Marfunin, "Mineralogical Chemistry; Chemistry, Physical and Theoretical; Chemistry, Inorganic," pp. xii-340, Springer-Verlag, Berlin and New York, 1979.
6 M. Z. C. Hu, E. A. Payzant, K. R. Booth, C. J. Rawn, R. D. Hunt, and L. F. Allard, "Ultrafine Microsphere Particles of Zirconium Titanate Produced by Homogeneous Dielectric-Tuning Coprecipitation," J. Mater. Sci., 38 [18] 3831-44 (2003).   DOI   ScienceOn
7 M. E. Zorn, D. T. Tompkins, W. A. Zeltner, and M. A. Anderson, "Photocatalytic Oxidation of Acetone Vapor on $TiO_2/ZrO_2$ Thin Films," Appl. Catal. B: Environmental, 23 [1] 1-8 (1999).   DOI   ScienceOn
8 J. L. Lakshmi, N. J. Ihasz, and J. M. Miller, "Synthesis Characterization and Ethanol Partial Oxidation Studies of $V_2O_5$ Catalysts Supported on $TiO_2-SiO_2$ and $TiO_2-ZrO_2$ Sol-Gel Mixed Oxides", J. Mol. Catal. A: Chem., 165 [1-2] 199-209 (2001).   DOI
9 L. Pandolfi, S. Kaciulis, G. Padeletti, A. Cusma', and M. Viticoli, "Deposition and Characterization of $ZrTiO_4$ Thin Films," Surf. Interf. Anal., 36 1159-62 (2004).   DOI   ScienceOn
10 F. Hund, "$ZrTiO_4$-Mischphasenpigment," Z. Anor. Allg. Chem., 525 [6] 221-29 (1985).   DOI
11 D. H. Hwang, K. S. Han, and B. H. Lee, "Synthesis and Formation Mechanism of Cobalt Doped Willemite Blue Pigments," J. Kor. Ceram. Soc., 47 [6] 603-7 (2010).   DOI
12 C. D. Kim, K. S. Hong, and G. T. Joo, "Raman Spectroscopy of the Solid Solution Limit in $Li_{1-x}Al_2XTa_{1-x}O_3$ System", J. Kor. Soc. Anal. Sci., 5 [1] 115-120 (1992).
13 P. R. Lucenaa, E. R. Leitea, F. M. Pontesb, E. L. Paulo, and S. P. Jose, "Photoluminescence: A Probe for Short, Medium and Long-Range Self-Organization Order in $ZrTiO_4$ Oxide," J. Solid. State. Chem., 179 3997-4002 (2006).   DOI   ScienceOn
14 F. Hund, "$ZrTiO_4$-Mischphasenpigment," Z. Anor. Allg. Chem., 525 [6] 221-9 (1985).   DOI
15 Y. F. Han, F. Chen, K. Ramesh, Z. Zhong, E. Widjaja, and L. Chen, "Preparation of Nanosized $Mn_3O_4$/SBA-15 Catalyst for Complete Oxidation of Low Concentration EtOH in Aqueous Solution with $H_2O_2$," Appl. Catal. B: Environmental., 76 [3-4] 227-34 (2007).   DOI
16 M. Dondi, F. Matteucci, and G. Cruciani, "Zirconium Titanate Ceramic Pigments: Crystal Structure, Optical Spectroscopy and Technological Properties," J. Solid. State. Chem., 179 [1] 233-46 (2006).   DOI   ScienceOn
17 A. Cocco and G. Torriano, "Relations between the Solid Phases in the System $TiO_2-ZrO_2$," Ann. Chim.(Rome), 55 [3] 153-63 (1965).
18 A. Bianco, G. Gusmano, R. Freer, and P. Smith, "Zirconium Titanate Microwave Dielectrics Prepared Via Polymeric Precursor Route," J. Eur. Ceram. Soc., 19 [6-7] 959-63 (1999).   DOI   ScienceOn