• Title/Summary/Keyword: 고분자 복합소재

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Review on Membrane Materials to Improve Plasticization Resistance for Gas Separations (가소화 저항 향상을 위한 기체분리막 소재 개발 동향)

  • Jo, Jin Hui;Chi, Won Seok
    • Membrane Journal
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    • v.30 no.6
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    • pp.385-394
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    • 2020
  • In the gas separation process, the separation membranes have to not only show high gas transport and selectivity but also exhibit exceptional stability at high temperature and pressure. However, when the polymeric membranes (particularly, glassy polymers) are exposed to the condensable gases (i.e., CO2, H2S, hydrocarbon, etc.), the polymer chains are prone to swell, leading to low stability. As a result, the plasticization behavior reduces the gas selectivity in the separation of mixture gases at high pressures and thus results in limited applications to the separation processes. To address these issues, many strategies have been studied such as thermal treatment, polymer blending, thermally rearrangement, mixed-matrix membranes, cross-linking, etc. In this review, we will understand the plasticization behavior and suggest potential methods based on the previously reported studies.

Development trend of composite insulator for distribution and transmission lines (송배전용 composite insulator개발 동향)

  • 강동필
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.410-414
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    • 1996
  • 기존의 초고압 옥외절연물은 세라믹을 소재로한 porcelain이었지만 최근 신소재기술의 발달로 내열성, 내후성, 내트래킹성 등이 우수한 고분자 재료들이 개발됨에 따라 구미 선진국을 중심으로 이들의 전기절연물분야 적용이 크게 증가하고 있다. 인발(pultrusion)공법으로 glass fiber와 수지를 결합시켜 고강도 무결점의 FRP절연봉이나 tube를 만들 수가 있다. 절연물에서 요구되는 구조재로서의 기계적 특성은 FRP복합재료가 충족시킬 수 있는데 이러한 봉을 core재로 하여 절연물의 표면전기특성을 만족하도록 고무로 된 shed를 씌우고 양쪽 끝에 금구류를 부착하여 composite insulator를 만들 수가 있다. composite insulator는 여러개의 shed를 한번에 진공사출하거나 shed를 금형에서 찍어 조립하여 제작할 수가 있는데 지금까지 검토되어 온 어떤 고분자 절연물보다 특성이 우수하고 장점이 많기 때문에 상업적 가치를 인정받고 있다. 본 고에서는 옥외용 절연물의 절연성능과 섬락사고기구를 요약하고 고분자신소재 절연물인 composite insulator의 장점, 국내외 개발현황, 평가방법등을 정리하였다.

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Technology Trend on Commercial Polymeric Membranes for Water Treatment (수처리용 상용 고분자 분리막 제품 기술동향)

  • Jang, Haenam
    • Membrane Journal
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    • v.29 no.1
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    • pp.11-17
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    • 2019
  • In the field of water treatment membranes, polymers are used together with ceramics as the most important materials. In this review, I tried to analyze the technology trends of polymer membrane materials based on commercial products. For this purpose, according to the types of water treatment membranes such as MF (Microfiltration), UF (Ultrafiltration) and NF (Nanofiltration), the trends of polymer membrane products were investigated by countries, materials, and companies. Through this, we were able to classify the types of materials that are mainly used for each type of membrane, and at the same time, identify the companies that are dominant in the market, and analyze which materials constitute the product portfolio. Based on these results, we have presented the characteristics of the material market according to each type of membrane, and proposed a technology development strategy to enter each market based on these characteristics.

Effect of Acrylic Acid-modified Polyethylene Wax Using Sequential Reaction on Properties of Polyamide/Glass Fiber Composite (폴리아미드/유리섬유 복합재료의 물성에 대한 연속반응 아크릴산 변성 폴리에틸렌 왁스의 영향)

  • Kim, Hyochul;Kim, Hyung-Il;Han, Won-Hee;Hong, Min-Hyuk;Lee, Hyunwoo
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.198-204
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    • 2019
  • Polymer composites are widely used as industrial materials requiring high mechanical properties. Glass fibers and fillers, which are used as a reinforcement in composites, usually have some problems such as nonuniform dispersion and poor interfacial adhesion. In this study, an acrylic acid-modified polyethylene wax was synthesized by the sequential reaction of pyrolysis of polyethylene followed by grafting with a polar acrylic acid. The acrylic acid-modified polyethylene wax was applied to polymer composites of the polyamide matrix and glass fiber reinforcement. The effect of acrylic acid-modified polyethylene wax on physical properties of polyamide based composites was thoroughly investigated.

The Effects of Silica in Polymeric Membrane On Gas Transport (고분자중 실리카가 기체투과에 미치는 영향)

  • 송병준;김건중;남세종
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.44-45
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    • 1998
  • 1. 서론 : 공기의 산소/질소 분리용 고분자막은 높은 선택도와 높은 투과도를 동시에 요구한다. 이 두가지 조건을 만족시키는 새로운 소재 개발과 기존의 고분자물질을 수식하는 연구가 진행되고 있으나 trade-off 현상으로 인하여 선택도가 증가되면 투과계수가 감소되고, 투과계수가 증가되면 선택도가 감소되는 경향이 있다. 다공성 지지체의 표면에 selective thin layer를 coating한 복합막은 투과저항을 줄여 투과속도는 증가시킬 수 있으나 선택도는 고분자 고유의 80%정도까지 감소되는 것으로 알려져 있다. (생략)

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Recent Trends in Composite Materials for Aircrafts (항공기용 복합소재의 개발 및 연구동향)

  • Kim, Deuk Ju;Oh, Dae Youn;Jeong, Moon Ki;Nam, Sang Yong
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.252-258
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    • 2016
  • The weight reduction and improved mechanical property are one of the prime factors to develop new materials for the aerospace industry. Composite materials have thus become the most attractive candidate for aircraft and other means of transportations due to their excellent property and light weight. In particular, fiber reinforced polymer (FRP) composite materials have been used as an alternative to metals in the aircraft. The composite materials have shown improved properties compared to those of metal and polymeric materials, which made the composites being used as the skin structure of the airplane. This review introduces different types of materials which have been developed from the FRP composite material and also one of the most advantageous ways to employ the composites in aircraft.

Gas Transport Behavior of Polydopamine-Coated Composite Membranes (폴리도파민/미세다공성 복합막의 기체투과특성)

  • Kim, Hyo Won;Park, Ho Bum
    • Membrane Journal
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    • v.23 no.2
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    • pp.136-143
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    • 2013
  • Recently, a novel coating method using an aqueous doapmine solution was proposed, the deposited coating was found to have extraordinarily strong-adhesion to numerous materials such as metal and polymers. However, it has suffered from many controversy in scientific fields due to its final structure and deposited mechanisms. Here, we have proposed a new structure for final dopamine product coupling with solid state spectroscopic, thermal behavior, and gas transport behaviors of dopamine coated microporous polyethersulfone membranes. In its final analysis, the results represented that it is a supramolecular aggregated of monomers consisting of 5,6-dihydroxyindoline and its derivative in contrast to previously proposed polymeric structure.

Fabrication of Triboelectric Nanogenerator based on a Composite of P(VDF-TrFE)/Graphene Flower (P(VDF-TrFE)/그래핀플라워 복합소재 기반 마찰전기 나노발전기 제작)

  • Muhammad Saqib;Woo Young Kim
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.4
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    • pp.913-923
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    • 2023
  • In this study, a triboelectric nanogenerator was fabricated using the composite of teflon-based polymer and graphene flower, which are stable in air and have relatively high electronegativity. The composite was used to fabricate an electronegative layer of a nanogenerator using a spin-coating method. For the electropositive layer, a zinc oxide film was prepared using a sol-gel method. The fabricated triboelectric nanogenerator produced a maximum power of about 44 ㎼. In conclusion, since all the active layers of the triboelectric nanogenerator was made by the solution process, it is scalable to a large area.

Graphene Oxide/Polyimide Nanocomposites for Gas Barrier Applications (산화그래핀이 함유된 폴리이미드 나노복합막의 기체차단성 평가 및 활용)

  • Yoo, Byung Min;Lee, Min Yong;Park, Ho Bum
    • Membrane Journal
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    • v.27 no.2
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    • pp.154-166
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    • 2017
  • Polymeric films for gas barrier applications such as food packaging and electronic devices have attracted great interest due to their cheap, light and easy processability among gas barrier materials. Especially in electronic devices, extremely low gas permeance is necessary for maintaining the device performance. However, current polymeric barrier films still suffer from relatively high gas permeance than other materials. Therefore, there have been strong needs to enhance the gas barrier performance of polymeric barrier films while keep their own advantages. Recently, graphene is highlighted as a 2D-layered material for gas barrier applications. However, owing to the poor workability and difficulty to produce in engineering scale, graphene oxide (GO) is on the rise. GO consists of oxygen-containing functional groups on surface with intrinsic 2D-layered structure and high aspect ratio, and it can be well-dispersed in aqueous polar solvents like water, resulting in scalable mass production. Here, we prepared GO incorporated polyimide (PI) nanocomposites. PI is widely used barrier polymer with high mechanical strength and thermal and chemical stability. We demonstrated that PI/GO nanocomposites could perform as a gas barrier. Furthermore, surfactants (Triton X-100 (TX) and Sodium deoxycholate (SDC)) are introduced to enhance the gas barrier performance by improving the degree of dispersion of GO in PI matrix. As a result, TX enhanced the gas barrier performance of PI/GO nanocomposites which is similar to predicted value. This finding will provide new insight to polymer nanocomposites for gas barrier applications.