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Analysis of activated colloidal crud in advanced and modular reactor under pump coastdown with kinetic corrosion

  • Khurram Mehboob;Yahya A. Al-Zahrani
    • Nuclear Engineering and Technology
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    • 제54권12호
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    • pp.4571-4584
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    • 2022
  • The analysis of rapid flow transients in Reactor Coolant Pumps (RCP) is essential for a reactor safety study. An accurate and precise analysis of the RCP coastdown is necessary for the reactor design. The coastdown of RCP affects the coolant temperature and the colloidal crud in the primary coolant. A realistic and kinetic model has been used to investigate the behavior of activated colloidal crud in the primary coolant and steam generator that solves the pump speed analytically. The analytic solution of the non-dimensional flow rate has been determined by the energy ratio β. The kinetic energy of the coolant fluid and the kinetic energy stored in the rotating parts of a pump are two essential parameters in the form of β. Under normal operation, the pump's speed and moment of inertia are constant. However, in a coastdown situation, kinetic damping in the interval has been implemented. A dynamic model ACCP-SMART has been developed for System Integrated Modular and Advanced Reactor (SMART) to investigate the corrosion due to activated colloidal crud. The Fickian diffusion model has been implemented as the reference corrosion model for the constituent component of the primary loop of the SMART reactor. The activated colloidal crud activity in the primary coolant and steam generator of the SMART reactor has been studied for different equilibrium corrosion rates, linear increase in corrosion rate, and dynamic RCP coastdown situation energy ratio b. The coolant specific activity of SMART reactor equilibrium corrosion (4.0 mg s-1) has been found 9.63×10-3 µCi cm-3, 3.53×10-3 µC cm-3, 2.39×10-2 µC cm-3, 8.10×10-3 µC cm-3, 6.77× 10-3 µC cm-3, 4.95×10-4 µC cm-3, 1.19×10-3 µC cm-3, and 7.87×10-4 µC cm-3 for 24Na, 54Mn, 56Mn, 59Fe, 58Co, 60Co, 99Mo, and 51Cr which are 14.95%, 5.48%, 37.08%, 12.57%, 10.51%, 0.77%, 18.50%, and 0.12% respectively. For linear and exponential coastdown with a constant corrosion rate, the total coolant and steam generator activity approaches a higher saturation value than the normal values. The coolant and steam generator activity changes considerably with kinetic corrosion rate, equilibrium corrosion, growth of corrosion rate (ΔC/Δt), and RCP coastdown situations. The effect of the RCP coastdown on the specific activity of the steam generators is smeared by linearly rising corrosion rates, equilibrium corrosion, and rapid coasting down of the RCP. However, the time taken to reach the saturation activity is also influenced by the slope of corrosion rate, coastdown situation, equilibrium corrosion rate, and energy ratio β.

Comparative study of 82Sr separation/purification methods used at Brookhaven National Laboratory and ARRONAX

  • Ha, Yeong Su;Yoon, Sang-Pil;Kim, Han-Sung;Kim, Kye-Ryung
    • 대한방사성의약품학회지
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    • 제5권2호
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    • pp.71-78
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    • 2019
  • Nuclear imaging is one of the most powerful measures for non-invasive diagnosis of myocardial vascular disease. Radionuclide such as 13N, 15O, 201Tl and 82Rb is used for the measurement of cardiac blood flow. 13N, 15O and 201Tl are produced in cyclotrons while 82Rb is obtained from generator. Rubidium (Rb), an alkali ion, behaves biologically like potassium, and accumulates in myocardial tissue. Rb has rapid blood clearance profile which allows the use of 82Rb with a short physical half-life of 75 s for non-invasive evaluation of regional myocardial perfusion. There are several advantages of 82Rb over other radioisotopes. An ultra-short half-life significantly reduces the exposure of patients to radiation and allows to repeat injections for studying the effects of medical intervention. As a positron emitter, 82Rb allows positron emission tomography (PET) imaging which have shown superior diagnostic performances. 82Rb can be produced from generator by decay of its parent 82Sr. However, the preparation of 82Sr is difficult, because appropriate purity is required to meet the specification of the product. Recently reported procedure from ARRONAX research institute showed that a Chelex-100 resin is sufficient for this purpose and additional column is not necessary. Whereas Brookhaven National Laboratory (BNL) procedure contains three ion exchange resin separation, including Chelex-100 resin. Currently, since 82Sr production site is non-existent in Korea, Korea Atomic Energy Research Institute (KAERI) has plan to produce 82Sr within specifications. We compared 82Sr purification procedures reported from ARRONAX and BNL to investigate the most suitable procedure for our conditions.

제주 스코리아로부터 합성한 제올라이트에 의한 Ni2+, Zn2+ 및 Cr3+의 흡착 특성 (Adsorption Characteristics of Ni2+, Zn2+ and Cr3+ by Zeolite Synthesized from Jeju Scoria)

  • 김정태;이창한;감상규
    • 한국환경과학회지
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    • 제29권7호
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    • pp.739-748
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    • 2020
  • The characteristics of heavy metal ion (Ni2+, Zn2+, and Cr3+) adsorption by zeolite synthesized from Jeju scoria using the fusion and hydrothermal method, were studied. The synthetic zeolite was identified as a Na-A zeolite by X-ray diffraction analysis and scanning electron microscopy images. The equilibrium of heavy metal ion adsorption by synthetic zeolite was reached within 60 min for Ni2+ and Zn2+, and 90 min for Cr3+. The uptake of heavy metal ions increased with increasing pH in the range of pH 3-6 and the uptake decreased in the order of Cr3+ > Zn2+ > Ni2+. For initial heavy metal concentrations of 20-250 mg/L at nonadjusted pH, the adsoption of heavy metal ions was well described by the pseudo second-order kinetic model and was well fitted by the Langmuir isotherm model. The maximum uptake of heavy metal ions obtained from the Langmuir model, decreased in the order of Zn2+ > Ni2+ > Cr3+, differing from the effect of pH on the uptake, which was mainly based on the different pH of the solutions.

이온교환수지를 이용한 알칼리 금속 이온 및 염소 이온의 제거 (Removal of Alkali Metal Ion and Chlorine Ion Using the Ion Exchange Resin)

  • 이경한;길보민;유철휘;황갑진
    • 멤브레인
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    • 제30권4호
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    • pp.276-281
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    • 2020
  • 알칼리 금속 이온과 염소 이온이 포함된 용액으로부터 이온교환수지를 이용한 이온 제거에 대한 연구를 진행하였다. 양이온인 금속이온(Na+와 K+)의 제거에는 양이온교환수지를, 음이온인 염소 이온(Cl-)의 제거에는 음이온교환수지를 사용하였다. 용액 A (Na+를 36,633 ppm, Cl-를 57,921 ppm 함유)의 경우, Na+ 이온과 Cl- 이온은 20분 이내에 99% 이상 제거되었다. 용액 B (K+를 1,638 ppm 함유)의 경우, K+ 이온은 3분 이내에 99% 이상 제거되었다.

스컬용융법에 의한 CaZrO3:Pr3+ 형광체 합성 및 특성분석 (Synthesis and characterization of CaZrO3:Pr3+ phosphor by skull melting method)

  • 최현민;김영출;석정원
    • 한국결정성장학회지
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    • 제31권5호
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    • pp.228-232
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    • 2021
  • 페로브스카이트 구조를 가지는 Ca1-xZrO3:xPr 형광체를 스컬용융법으로 합성하였다. 합성한 형광체의 결정구조, 형태 및 광학적 특성은 XRD, SEM, 자외선 형광반응 및 광발광을 통해 분석하였다. XRD 측정에서는 CaZrO3:Pr3+의 단결정이 페로브스카이트 구조의 사방정계로 분석되었다. 합성된 형광체는 254 nm의 UV 광에 의해 여기 될 수 있고 방출 스펙트럼 결과는 506, 536 및 548 nm에서 전하전이 3P03H4, 3P13H53P03H5로 인해 CaZrO3:Pr3+는 녹색 발광이 우세하였다.

Immunological mechanism of postherpetic neuralgia and effect of pregabalin treatment on the mechanism: a prospective single-arm observational study

  • Mercan, Aysel;Uzun, Sema Tuncer;Keles, Sevgi;Hacibeyoglu, Gulcin;Yilmaz, Resul;Reisli, Ruhiye
    • The Korean Journal of Pain
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    • 제34권4호
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    • pp.463-470
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    • 2021
  • Background: Although neuropathic pain is a severe and common pain, its pathophysiology has not been elucidated yet. Studies in recent years have focused on the immune system's role in the pathogenesis of neuropathic pain. The aim of this study was to investigate the role of immunological mechanisms in neuropathic pain and the effect of pregabalin by measuring immunological marker levels in peripheral blood before and after pregabalin treatment in postherpetic neuralgia (PHN) patients with neuropathic pain. Methods: Forty patients diagnosed with PHN were included in the study. CD4, T follicular cells (Tfh: CD4+CXCR5+PD1+), Th17 (CD4+CCR6+ and CD4+IL17A+), regulatory T cells (Treg: CD4+ CD25+foxp3+), Th1 (CD4+ CXCR3+ and CD4+ IFN-γ+) and Th2 (CD4+ IL-4+) cell ratios were measured in peripheral blood samples before treatment and after 3 months of treatment. Results: When immunological marker and inflammation parameter levels were compared before and after treatment, the helper T cell ratio (CD3+, CD4+) was 30.28 ± 12.27% before treatment and 34.93 ± 11.70% after treatment, so there was a statistically significant increase (P = 0.028). Th17 was 4.75 ± 5.02% before treatment and 5.80 ± 3.13% after treatment, and there was a statistically significant increase (P = 0.036). Conclusions: Immunological mechanisms play an essential role in the pathogenesis of neuropathic pain, immunologically based treatment approach will be the critical point of treatment.

Voltage Dependent N Type Calcium Channel in Mouse Egg Fertilization

  • Eum, Jin Hee;Park, Miseon;Yoon, Jung Ah;Yoon, Sook Young
    • 한국발생생물학회지:발생과생식
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    • 제24권4호
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    • pp.297-306
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    • 2020
  • Repetitive changes in the intracellular calcium concentration ([Ca2+]i) triggers egg activation, including cortical granule exocytosis, resumption of second meiosis, block to polyspermy, and initiating embryonic development. [Ca2+]i oscillations that continue for several hours, are required for the early events of egg activation and possibly connected to further development to the blastocyst stage. The sources of Ca2+ ion elevation during [Ca2+]i oscillations are Ca2+ release from endoplasmic reticulum through inositol 1,4,5 tri-phosphate receptor and Ca2+ ion influx through Ca2+ channel on the plasma membrane. Ca2+ channels have been characterized into voltage-dependent Ca2+ channels (VDCCs), ligand-gated Ca2+ channel, and leak-channel. VDCCs expressed on muscle cell or neuron is specified into L, T, N, P, Q, and R type VDCs by their activation threshold or their sensitivity to peptide toxins isolated from cone snails and spiders. The present study was aimed to investigate the localization pattern of N and P/Q type voltage-dependent calcium channels in mouse eggs and the role in fertilization. [Ca2+]i oscillation was observed in a Ca2+ contained medium with sperm factor or adenophostin A injection but disappeared in Ca2+ free medium. Ca2+ influx was decreased by Lat A. N-VDCC specific inhibitor, ω-Conotoxin CVIIA induced abnormal [Ca2+]i oscillation profiles in SrCl2 treatment. N or P/Q type VDC were distributed on the plasma membrane in cortical cluster form, not in the cytoplasm. Ca2+ influx is essential for [Ca2+]i oscillation during mammalian fertilization. This Ca2+ influx might be controlled through the N or P/Q type VDCCs. Abnormal VDCCs expression of eggs could be tested in fertilization failure or low fertilization eggs in subfertility women.

Application of nickel hexacyanoferrate and manganese dioxide-polyacrylonitrile (NM-PAN) for the removal of Co2+, Sr2+ and Cs+ from radioactive wastewater

  • Md Abdullah Al Masud;Won Sik Shin
    • Membrane and Water Treatment
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    • 제15권2호
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    • pp.67-78
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    • 2024
  • In this study, a nickel hexacyanoferrate and manganese dioxide-polyacrylonitrile (NM-PAN) composite was synthesized and used for the sorptive removal of Co2+, Sr2+, and Cs+ Cs+ in radioactive laundry wastewater. Single- and multi-solute competitive sorptions onto NM-PAN were investigated. The Freundlich (Fr), Langmuir (Lang), Kargi-Ozmıhci (K-O), Koble-Corrigan (K-C), and Langmuir-Freundlich (Lang-Fr) models satisfactorily predicted all the single sorption data. The sorption isotherms were nonlinearly favorable (Freundlich coefficient, NF = 0.385-0.426). Cs+ has the highest maximum sorption capacity (qmL = 0.855 mmol g-1) for NM-PAN compared to Co2+ and Sr2+, wherein the primary mechanism was the physical process (mainly ion-exchange). The competition between the metal ions in the binary and ternary systems reduced the respective sorption capacities. Binary and ternary sorption models, such as the ideal adsorbed solution theory (IAST) model coupled with single sorption models of IAST-Fr, IAST-K-O, IAST-K-C and IAST-Lang-Fr, were fitted to the experimental data; among these, the IAST-Freundlich model showed the most satisfactory prediction for the binary and ternary systems. The presence of cationic surfactants highly affected the sorption on NM-PAN due to the increase in distribution coefficients (Kd) of Co2+ and Cs+.

MULTIPLIERS OF DIRICHLET-TYPE SUBSPACES OF BLOCH SPACE

  • Li, Songxiao;Lou, Zengjian;Shen, Conghui
    • 대한수학회보
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    • 제57권2호
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    • pp.429-441
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    • 2020
  • Let M(X, Y) denote the space of multipliers from X to Y, where X and Y are analytic function spaces. As we known, for Dirichlet-type spaces 𝓓αp, M(𝓓p-1p, 𝓓q-1q) = {0}, if p ≠ q, 0 < p, q < ∞. If 0 < p, q < ∞, p ≠ q, 0 < s < 1 such that p + s, q + s > 1, then M(𝓓p-2+sp, 𝓓q-2+sq) = {0}. However, X ∩ 𝓓p-1p ⊆ X ∩ 𝓓q-1q and X ∩ 𝓓p-2+sp ⊆ X ∩ 𝓓q-2+sp whenever X is a subspace of the Bloch space 𝓑 and 0 < p ≤ q < ∞. This says that the set of multipliers M(X ∩ 𝓓 p-2+sp, X∩𝓓q-2+sq) is nontrivial. In this paper, we study the multipliers M(X ∩ 𝓓p-2+sp, X ∩ 𝓓q-2+sq) for distinct classical subspaces X of the Bloch space 𝓑, where X = 𝓑, BMOA or 𝓗.

Investigation of Endurance Degradation in a CTF NOR Array Using Charge Pumping Methods

  • An, Ho-Myoung;Kim, Byungcheul
    • Transactions on Electrical and Electronic Materials
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    • 제17권1호
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    • pp.25-28
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    • 2016
  • We investigate the effect of interface states on the endurance of a charge trap flash (CTF) NOR array using charge pumping methods. The endurance test was completed from one cell selected randomly from 128 bit cells, where the memory window value after 102 program/erase (P/E) cycles decreased slightly from 2.2 V to 1.7 V. However, the memory window closure abruptly accelerated after 103 P/E cycles or more (i.e. 0.97 V or 0.7 V) due to a degraded programming speed. On the other hand, the interface trap density (Nit) gradually increased from 3.13×1011 cm−2 for the initial state to 4×1012 cm−2 for 102 P/E cycles. Over 103 P/E cycles, the Nit increased dramatically from 5.51×1012 cm−2 for 103 P/E cycles to 5.79×1012 cm−2 for 104 P/E cycles due to tunnel oxide damages. These results show good correlation between the interface traps and endurance degradation of CTF devices in actual flash cell arrays.