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http://dx.doi.org/10.5322/JESI.2020.29.7.739

Adsorption Characteristics of Ni2+, Zn2+ and Cr3+ by Zeolite Synthesized from Jeju Scoria  

Kim, Jung-Tae (Jeju Livestock Research Center)
Lee, Chang-Han (Department of Environmental Administration, Catholic University of Pusan)
Kam, Sang-Kyu (Department of Environmental Engineering, Jeju National University)
Publication Information
Journal of Environmental Science International / v.29, no.7, 2020 , pp. 739-748 More about this Journal
Abstract
The characteristics of heavy metal ion (Ni2+, Zn2+, and Cr3+) adsorption by zeolite synthesized from Jeju scoria using the fusion and hydrothermal method, were studied. The synthetic zeolite was identified as a Na-A zeolite by X-ray diffraction analysis and scanning electron microscopy images. The equilibrium of heavy metal ion adsorption by synthetic zeolite was reached within 60 min for Ni2+ and Zn2+, and 90 min for Cr3+. The uptake of heavy metal ions increased with increasing pH in the range of pH 3-6 and the uptake decreased in the order of Cr3+ > Zn2+ > Ni2+. For initial heavy metal concentrations of 20-250 mg/L at nonadjusted pH, the adsoption of heavy metal ions was well described by the pseudo second-order kinetic model and was well fitted by the Langmuir isotherm model. The maximum uptake of heavy metal ions obtained from the Langmuir model, decreased in the order of Zn2+ > Ni2+ > Cr3+, differing from the effect of pH on the uptake, which was mainly based on the different pH of the solutions.
Keywords
Scoria; Synthetic zeolite; Adsorption; Heavy metal ions;
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