• Title/Summary/Keyword: $ZrO_2-8%Y_2O_3$

검색결과 449건 처리시간 0.024초

Temporal variation of magma chemistry in association with extinction of spreading, the fossil Antarctic-Phoenix Ridge, Drake Passage, Antarctica

  • Choe, Won-Hie;Lee, Jong-Ik;Lee, Mi-Jung;Hur, Soon-Do;Jin, Young-Keun
    • 한국지구과학회:학술대회논문집
    • /
    • 한국지구과학회 2005년도 추계학술발표회 논문집
    • /
    • pp.136-141
    • /
    • 2005
  • The K Ar ages, whole rock geochemistry and Sr Nd Pb isotopes have been determined for the submarine basalts dredged from the P2 and P3 segments of the Antarctic-Phoenix Ridge (APR), Drake Passage, Antarctica, for better understanding on temporal variation of magma chemistry in association with extinction of seafloor spreading. The fossilized APR is distant from the known hot spots, and consists of older N-MORB prior to extinction of spreading and younger E-MORB after extinction. The older N-MORB (3.5-6.4 Ma) occur in the southeast flank of the P3 segment (PR3) and the younger E-MORB (1.4-3.1 Ma) comprise a huge seamount at the P3 segment (SPR) and a big volcanic edifice at the P2 segment (PR2). The N-type PR3 basalts have higher Mg#, K/Ba, and CaO/Al2O3 and lower Zr/Y, Sr, and Na8.0 with slight enrichment in incompatible elements and almost flat REE patterns. The E-type SPR and PR2 basalts are highly enriched in incompatible elements and LREE. The extinction of spreading occurring at 3.3 Ma seems to have led to a temporal magma oversupply with E-MORB signatures. Geochemical signatures such as Ba/TiO2, Ba/La, and Sm/La suggest heterogeneity of upper mantle and formation of E-MORB by higher contribution of enriched materials to mantle melting, compared to N-MORB environment. E-MORB magmas beneath the APR seem to have been produced by low melting degree (up to 1% or more) at deeper low-temperature regime, where metasomatized veins consisting of pyroxenites have preferentially participated in the melting. The occurrence of E-MORB at the APR is a good example to better understand what kinds of magmatism would occur in association with extinction of spreading.

  • PDF

PMN-PNN-PZT 세라믹스의 미세구조 및 압전 특성 (Microstructure and Piezoelectric Properties of PMN-PNN-PZT Ceramics)

  • 류주현;김승원
    • 한국전기전자재료학회논문지
    • /
    • 제30권8호
    • /
    • pp.496-500
    • /
    • 2017
  • $Pb(Mn_{1/3}Nb_{2/3})_{0.07}(Ni_{1/3}Nb_{2/3})_{0.10}(Zr_{0.5}Ti_{0.5})_{0.83}O_3$ composition ceramics with high piezoelectric properties were fabricated by the columbite precursor method for ultrasonic generators, and the effects of sintering temperature on microstructure and piezoelectric properties were systematically investigated. It was found that the tetragonality of the ceramics decreased with increase in sintering temperature. Moreover, excellent physical properties such as $d_{33}=447pC/N$, ${\varepsilon}_r=1,843$, $k_p=0.641$, and $Q_m=1,207$ were obtained for an ultrasonic generator when the second calcination temperature and sintering temperature were $720^{\circ}C$ and $920^{\circ}C$, respectively.

HIP처리가 플라즈마 용사된 열차폐 코팅층의 접착강도와 고온특성에 미치는 영향 (Effects of Hot Isostatic Pressing on Bond Strength and Elevated Temperature Characteristics of Plasma sprayed TBC)

  • 박영규;김성휘;김두수;이영찬;최철;정진성;김길무;김재철
    • 한국재료학회지
    • /
    • 제10권4호
    • /
    • pp.312-316
    • /
    • 2000
  • HIP처리가 가스터빈 고정익 등 고온부품에 적용되는 열차폐 코팅층의 접착강도 및 고온특성에 미치는 영향을 조사하였다. 시편은 IN738LC 초합금 표면에 8wt%Y$_2$O$_3$-$ZrO_2$분말을 플라즈마 용사법으로 코팅한 후 $1200^{\circ}C$, 100MPa의 고온, 고압에서 4시간 동안 HIP 처리하여 준비하였다. 실험결과 HIP 처리된 코팅의 경우 미세균열과 기공이 상당량 감소하였으며 EDX분석을 통해 계면에서 원자간 상호확산이 발생한 것을 확인하였다. 이러한 코팅층의 치밀화 및 상호확산으로 인해 HIP처리된 코팅층의 접착강도는 48% 이상 크게 증가하였으며 조직 또한 균질화 되었다. 반면 가열과 냉각이 반복되는 환경에서 코팅층의 내구력은 HIP 처리된 경우가 다소 저하되었다. 이는 코팅과 모재와의 열팽창 차이로 인한 변형을 완화시켜주는 기공과 미세균열이 감소되었기 때문으로 판단된다.

  • PDF

압전 에너지 하베스트를 위한 마이크로 필라 공정 연구 (Processing Study for the Micro Pillar for Piezoelectric Energy Harvest)

  • 윤석우;이규탁;이경수;정순종;김민수;조경호;고중혁
    • 한국전기전자재료학회논문지
    • /
    • 제23권8호
    • /
    • pp.601-604
    • /
    • 2010
  • In this study, the piezoelectric energy harvester was investigated employing the pillar structure with the diameter size of 50~500 um. Usually, the aspect ratio between the height and diameter was related with the piezoelectric performance. High aspect ratio was showed the low electric noise and high piezoelectric properties than low aspect ratio. Therefore, we have selected the Su-8 photo-resist and modified lithography process to manufacture the pillar structure with height above the 250 ${\mu}m$. In this presentation, we will report the process and properties of micro pillar structure based on the PMN-PZT (Pb$(Mg_{1/3}Nb_{2/3})O_3$-PbZrTiO$_3$) materials.

Pb(Ni1/3Nb2/3)O3-PZT 세라믹스 고용체에서 과잉 NiO첨가에 따른 압전특성 변화 (The Effect of NiO Addition to the PNN-PZT Piezoelectric Ceramics on Piezoelectric Properties)

  • 최용길;손영진;권준철;조경원;윤만순;김일호;김영민;어순철
    • 한국재료학회지
    • /
    • 제15권6호
    • /
    • pp.413-418
    • /
    • 2005
  • Perovskite $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr,Ti)O_3[PNN-PZT]$ ceramics were synthesized by conventional ceramic processing technique. In order to modify piezoelectric properties for sensor application in this system, NiO addition was considered to provide $Ni^{+2}$ as an acceptor, which was known to occupy with B site in the structure. The effect of NiO addition up to $8\;mol\%$ on the following piezoelectric properties as well as sintering properties was investigated. When NiO added more than $1\;mol\%$, average grain size was decreased and second phase was found to form. Moreover, the second phase caused decrease in relative dielectric constant $(\varepsilon_{33}T/\varepsilon0)$, electro-mechanical coupling factor $(k_p)$, and piezoelectric charge constant $(d_{33})$, while increasing mechanical quality factor $(Q_m)$. When $1\;mol\%$ NiO was added, density, dielectric properties and piezoelectric properties were abruptly increased.

28W(T5) 형광등 구동용 압전트랜스포머의 전기적 특성 (Electrical Characteristics of Piezoelectric Transformer for Driving A 28W Fluorescent Lamp)

  • 류주현;황상모;윤광희;김종선;박창엽
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.847-851
    • /
    • 2000
  • In this study, contour-vibration-mode Pb($Ni_{1/2}$,$W_{1/2}$)$O_3$-Pb(Zr,Ti)$O_3$ piezoelectric transformers for driving a 28W(T5) fluorescent lamp were fabricated to the modified filter structure with ring and dot electrodes which has been developed for application in 455kHz AM radios. The piezoelectric transformers were fabricated to the size of $31.5$\times$31.5$\times$2.5$mm^3$ with the variations of ring/dot electrode area ratio. Driving of piezoelectric transformer was carried out with input region for the ring electrode and output region for the dot electrode. The electrical properties and characteristic temperature rises caused by the vibration were measured at various load resistances. A 28 W fluorescent lamp, T5, was successfully driven by the fabricated transformer. The transformer with ring/dot electrode area ratio of 1.83 exhibited the best properties in terms of output power, efficiency and characteristic temperature rise, 30.95 W, 97.57% and8.3$^{\circ}C$ respectively.

  • PDF

$\b{W}$형 3-Loop 발전소에 대한 일체형 가연성 흡수봉 경제성 평가

  • 박상원;장도익;정선교
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1996년도 춘계학술발표회논문집(1)
    • /
    • pp.213-218
    • /
    • 1996
  • 가압 경수로의 노심설계에 있어서 제한된 우라늄 자원의 효율적인 이용을 위한 다양한 방안으로 장주기 운전, 고 방출연소도 및 저누출 장전모형 등을 강구하고 있는 추세이다. 이러한 노심들은 원자로 운전주기 전반에 걸친 공간적 출력 분포 제어와 잉여반응도 제어를 위해 가연성 흡수봉을 사용하고 있으며 이와 관련 하여 가연성 흡수봉에 대한 전략등이 다 각도로 검토되고 있으며 다양한 노심에 대한 최적의 가연성 흡수봉 혹은 그 전략에 대해 많은 연구가 진행되고 있다. 본 연구에서는 웨스팅하우스형 3-Loop 발전소에 대해, 장주기 (18 개월-480 EFPD), 저누출 장전 모형 전략을 채용하여, Er$_2$O$_3$, Gd$_2$O$_3$, ZrB$_2$의 일체형 가연성 흡수봉에 대한 노심특성 및 경제성을 평형노심개념을 적용, KNFC가 노심설계에 사용하고 있는 APA(ALPHA/PHOENIX-P/ANC) 8.0.0 코드 체계를 이용하여 평가하였다. 노심특성에 대해서는 감속재 온도계수, 첨두출력인자, 잔존흡수봉효과 및 노심 연소거동에 대한 평가가 수행되었고, 동일한 주기길이(480 EFPD) 에 대한 우라늄 적재량에 대해 원광비, 변환비, 농축비, 가공비 그리고 이자율 등을 고려하여 핵주기 경제성 평가 코드인 POCO 코드를 이용하여 경제성을 평가하였다.

  • PDF

빌드업 필름의 선폭 6㎛급 패턴 가공을 위한 직접식 UV 레이저 프로젝션 애블레이션 (Direct UV laser projection ablation to engrave 6㎛-wide patterns in a buildup film)

  • 손현기;박종식;정수정;신동식;최지연
    • 한국레이저가공학회지
    • /
    • 제17권3호
    • /
    • pp.19-23
    • /
    • 2014
  • To directly engrave circuit-line patterns as wide as $6{\mu}m$ in a buildup film to be used as an IC substrate, we applied a projection ablation technique in which an 8 inch dielectric ($ZrO_2/SiO_2$) mask, a DPSS 355nm laser instead of an excimer laser, a ${\pi}$-shaper and a galvo scanner are used. With the ${\pi}$-shaper and a square aperture, the Gaussian beam from the laser is shaped into a square flap-top beam. The galvo scanner before the $f-{\theta}$ lens moves the flat-top beam ($115{\mu}m{\times}105{\mu}m$) across the 8 inch dielectric mask whose patterned area is $120mm{\times}120mm$. Based on the results of the previous research by the authors, the projection ratio was set at 3:1. Experiments showed that the average width and depth of the engraved patterns are $5.41{\mu}m$ and $7.30{\mu}m$, respectively.

  • PDF

적층 압전초음파모터용 소자의 전기적 특성 (The Electrical properties of piezoelectric device for Multilayer Piezoelectric Ultrasonic Motor)

  • 이갑수;이상호;류주현
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
    • /
    • pp.325-326
    • /
    • 2006
  • In this study, in order to develop piezoelectric device for multilayer piezoelectric ultrasonic motor, low temperature sintering $Pb(Mn_{1/3}Nb_{2/3})_{0.02}(Ni_{1/3}Nb_{2/3})_{0.12}(Zr_{0.48}Ti_{0.52})_{0.86}O_3$ system ceramics were fabricated according to the variations of forming pressure of casting sheet. At the 300[$kgf/cm^2$] forming pressure, the maximum density of 7.8[$g/cm^3$] was obtained. At the 350[$kgf/cm^2$] forming pressure, the maximum values of effective electromechanical coupling factor $k_{cff}\;=\;0.24$ and mechanical quality factor Qm=628 were obtained.

  • PDF

졸-겔 코팅에 의한 저온형 고체산화물 연료저지용 전해질막의 합성 및 특성 (Synthesis of Electrolyte Films for Low-Temperature Solid Oxide Fuel Cells by Sol-Gel Coating and Their Characteristics)

  • 현상훈;김승구;장운석
    • 한국세라믹학회지
    • /
    • 제36권4호
    • /
    • pp.391-402
    • /
    • 1999
  • Characteristics of composite electrolytes which were prepared by coating a thin film of YSZ (yttria sta-bilized zirconia : (ZrO2)0.92 (Y2O3)0.08) on YDC (yttria doped ceria : Ce0.8Y0.2O1.9) with mixed conductivity have been investigated in order to develop the low-temperature solid oxide fuel cell. The thickness (t) of spin-coated YSZ thin films after the heat-treatment at 600$^{\circ}C$ was increased proportionally to the sol con-centrations (C) while the decrease in its thickness with the spin rate ($\omega$) could be expressed in the e-quation of ln t=9.49-0.53 ln $\omega$(0.99mol//s sol conc.) When the sol concentration and the spin rate being less than 0.99 mol/l and higher than 1000 rpm respectively reliable YSZ/YDC composite electrolytes could be obtained by multi-coating although several micro-cracks were observed in singly coated YSZ film surfaces. The dense YSZ film with a 1$\mu\textrm{m}$ thickness was prepared by coating of 0.99 mol/l YSZ sol five-times at 2000 rpm followed by heat-treatment at 1400$^{\circ}C$ for 2h, The adhesion between YSZ film and YDC substrate was found to be very good. The open circuit voltages of H2/O2 single cell with YSZ/YDC composite electrolytes were 0.79∼0.82 V at 800$^{\circ}C$ and 0.75∼0.77V at 900$^{\circ}C$ The open circuit voltage was inversely proportioned to the thickness ratio of YSZ thin film (1$\mu\textrm{m}$) to YDC substrate(0.28-2.22 mm)

  • PDF