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http://dx.doi.org/10.3740/MRSK.2005.15.6.413

The Effect of NiO Addition to the PNN-PZT Piezoelectric Ceramics on Piezoelectric Properties  

Choi Y. G. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Son Y. J. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Kweon J. C. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Cho K. W. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Yoon M. S. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Kim I. H. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Kim Y. M. (Corea Electronics Corporation(CEC))
Ur S. C. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
Publication Information
Korean Journal of Materials Research / v.15, no.6, 2005 , pp. 413-418 More about this Journal
Abstract
Perovskite $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr,Ti)O_3[PNN-PZT]$ ceramics were synthesized by conventional ceramic processing technique. In order to modify piezoelectric properties for sensor application in this system, NiO addition was considered to provide $Ni^{+2}$ as an acceptor, which was known to occupy with B site in the structure. The effect of NiO addition up to $8\;mol\%$ on the following piezoelectric properties as well as sintering properties was investigated. When NiO added more than $1\;mol\%$, average grain size was decreased and second phase was found to form. Moreover, the second phase caused decrease in relative dielectric constant $(\varepsilon_{33}T/\varepsilon0)$, electro-mechanical coupling factor $(k_p)$, and piezoelectric charge constant $(d_{33})$, while increasing mechanical quality factor $(Q_m)$. When $1\;mol\%$ NiO was added, density, dielectric properties and piezoelectric properties were abruptly increased.
Keywords
PNN-PZT; piezoelectric; NiO doping;
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