• Bulletin of the Korean Chemical Society
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• v.29 no.6
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• pp.1149-1156
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• 2008

The conformational study on neutral and zwitterionic L-alanines (N-Ala and Z-Ala, respectively) and the transition state (TS) for their interconversion is carried out using ab initio HF and density functional B3LYP methods with the self-consistent reaction field method in the gas phase and in solution. At both the HF and B3LYP levels of theory, the local minimum N1 for N-Ala is found to be most preferred in the gas phase and a weak asymmetric bifurcated hydrogen bond between the amino hydrogens and the carbonyl oxygen appears to play a role in stabilizing this conformation. The local minima N2a and N2b are found to be the second preferred conformations, which seem to be stabilized by a hydrogen bond between the amino nitrogen and the carboxylic hydrogen. The relative stability of the local minimum N2b is remarkably increased in solution than that in the gas phase. The local minimum N2b becomes more stable than the local minimum N2a in most of the solution. On the whole the relative free energies of Z-Ala and TS become more lowered, as the solvent polarity increases. N-Ala prevails over Z-Ala in aprotic solutions but Z-Ala is dominantly populated in ethanol and water. In aprotic solutions, the population of Z-Ala increases somewhat with the increase of solvent polarity. The barrier to Z-Ala-to-N-Ala interconversion increases on the whole with the increase of solvent polarity, which is caused by the increase of stability for Z-Ala.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.206.2-206
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• 2003

• Journal of Microbiology and Biotechnology
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• v.20 no.1
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• pp.94-100
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• 2010

Zymomonas mobilis was immobilized in a modified graphite felt cathode with neutral red (NR-cathode) and Saccharomyces cerevisiae was cultivated on a platinum plate anode. An electrochemical redox reaction was induced by 3 volts of electric potential charged to the cathode and anode. The Z. mobilis produced 1.3-1.5 M of ethanol in the cathode compartment, whereas the S. cerevisiae produced 1.7-1.9 M in the anode compartment after 96 h. The ethanol produced by the Z. mobilis immobilized in the NR-cathode and S. cerevisiae cultivated on the platinum plate was 1.5-1.6 times higher than that produced under conventional conditions. The electrochemical oxidation potential inhibited Z. mobilis, but activated S. cerevisiae. The SDS-PAGE pattern of the total soluble proteins extracted from the Z. mobilis cultivated under the electrochemical oxidation conditions was gradually simplified in proportion to the potential intensity. Z. mobilis and S. cerevisiae were cultivated in the cathode and anode compartments, respectively, of an electrochemical redox combination system. The Z. mobilis culture cultivated in the cathode compartment for 24 h was continuously transferred to the S. cerevisiae culture in the anode compartment at a rate of 300 ml/day. Approx. 1.0-1.2 M of ethanol was produced by the Z. mobilis in the cathode compartment within 24 h, and an additional 0.8-0.9 M produced by the S. cerevisiae in the anode compartment within another 24 h. Thus, a total of 2.0-2.1 M of ethanol was produced by the electrochemical redox combination of Z. mobilis and S. cerevisiae within 48 h.

• Journal of Information Display
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• v.1 no.1
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• pp.42-47
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• 2000

The relationship between driving voltage and the amount of wall charge in the address period of surface discharge type AC Plasma Display Panel has been investigated. The amount of wall charge on each electrode is obtained simultaneously from the current profiles after applying only one addressing discharge pulse. The wall charge $Q_y$ on the scan electrode Y is almost the sum of $Q_x$ on the address electrode X and $Q_z$ on the sustain electrode Z. The $Q_y$ increased with the driving voltage regardless of the kind of electrode, whereas the addressing $T_d$ decreased. The $Q_x$ and $Q_y$ are increased considerably by blocking voltage $V_z$, whereas $Q_x$ is decreased. The $V_z$ dependence of $Q_x$ $Q_y$ and ${\varrho}_z$ in addressing discharge was $-13{\times}10^{-2}$ (pc/$V_z$), and $60{\times}10^{-2}$ ($pc/V_z$) and $70{\times}10^{-2}(pc/V_z)$, respectively.

• The Journal of Advanced Prosthodontics
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• v.3 no.3
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• pp.126-131
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• 2011

PURPOSE. The aim of this in vitro study was to examine the curing efficiency of various resin-based materials polymerized through ceramic restorations with 3 different thicknesses. Curing efficiency was evaluated by determining the surface microhardness (VHN) of the resin specimens. MATERIALS AND METHODS. Four kinds of resin materials were used. Z350 (3M ESPE $Filtek^{TM}$ Z350: A2 Shade), Z250 (3M ESPE $Filtek^{TM}$ Z250: A2 Shade) and $Variolink^{(R)}$ II (VL: Ivoclar vivadent, base: transparent) either with or without a self-curing catalyst (VLC: Ivoclar vivadent, catalyst: low viscosity/transparent) were filled into the silicone mold (10 mm diameter, 1 mm thick). They were cured through ceramic discs (IPS e.max Press MO-0 ingot ivoclar vivadent, 10 mm diameter, 0.5, 1 and 2 mm thicknesses) by LED light-curing units for 20 and 40 seconds. Vicker's microhardness numbers (VHNs) were measured on the bottom surfaces by a microhardness tester. Data were analyzed using a 3-way analysis of variance (ANOVA) at a significance level of 0.05. RESULTS. The thickness of ceramic disc increased, the VHNs of all four resin types were decreased (P<.05). The mean VHN values of the resins light cured for 40 seconds were significantly higher than that of LED for 20 seconds in all four resin materials (P<.05). VLC showed significantly higher VHN values than VL regardless of other conditions (P<.05). Z350 and Z250 showed higher values than VL or VLC (P<.01). CONCLUSION. Thinner ceramic disc with increased curing time resulted higher VHN values of all resin materials. The use of a catalyst produced a greater hardness with all polymerization methods. Restorative resin materials (Z350, Z250) showed higher VHN values than resin cement materials (VL, VLC).

• Advances in materials Research
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• v.5 no.2
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• pp.93-105
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• 2016

KNN-based ceramics modified with small amounts of $Bi_4Zr_3O_{12}$ (BiZ) has been synthesized using high-throughput experimentation (HTE). The results from X-ray diffraction show that for samples with base composition $(K_{0.5}Na_{0.5})NbO_3$ (KNN), the phase present changes from orthorhombic to pseudo-cubic with more than 0.2 mol% BiZ addition; for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.9}Ta_{0.1})O_3$ (KNNLT), the phase present changes from a mixture of orthorhombic and tetragonal symmetry to pseudo-cubic with more than 0.4 mol % while for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.86}Ta_{0.1}Sb_{0.04})O_3$ (KNNLST), the phase present is tetragonal with <0.3 mol% BiZ addition and transforms to pseudo-cubic with more dopant addition. The microstructures of the samples show that addition of BiZ decreases the average grain size and increases the volume of pores at the grain boundaries. The values of dielectric constant for KNN and KNNLT compositions increase slightly with BiZ addition while that for KNNLST decreases gradually with BiZ addition. The dielectric loss values are between 0.02 and 0.04 for KNNLT and KNNLST compositions while they are ~ 0.05 for KNN samples. The resistivity values increases with BiZ addition and values in the range of $10^{10}{\Omega}cm$ and $10^{12}{\Omega}cm$ are obtained. The piezoelectric charge coefficient ($d{^*}_{33}$) is highest for KNNLST samples and decreases gradually from ~400 pm/V to ~100 pm/V with BiZ addition.

• Proceedings of the Korean Society of Sericultural Science Conference
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• 2003.10a
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• pp.58-65
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• 2003

This study was carried out to investigate active constituents of Bombysis corpus on the neurite outgrowth from PCl2 cells led to isolate three phospholipids (4 6) and three aromatic amines (13) were obtained from the methanol extract of Bombycis corpus. Based on spectral data, their structures have been elucidated as nicotiamide (1), cytidine (2), adenine (3), 1-O-(9Z-octadecenoyl)-2-O-(8Z, 11Z-octadecadienoyl)-sn-glycero-3-phosphorylcholine(4), 1, 2-di-O-hexadecanoyl-sn-glycero-3-phosphorylcholine(5) and 1, 2-di-O-9Z-octadecenoyl-sn-glycero-3-phosphorylcholine(6). (omitted)

• Kyungpook Mathematical Journal
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• v.46 no.4
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• pp.573-580
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• 2006

In this paper, we obtain sufficient conditions for the oscillation of every solution of the difference equation $$x_{n+1}-x_n+\sum_{i=1}^{m}p_ix_{n-k_i}+qx_{n-z}=0,\;n=0,1,2,{\cdots},$$ where $p_i{\in}\mathbb{R}$, $k_i{\in}\mathbb{Z}$ for $i=1,2,{\cdots},m$ and $z{\in}\{-1,0\}$. Furthermore, we obtain sufficient conditions for the oscillation of all solutions of the equation $${\Delta}^rx_n+\sum_{i=1}^{m}p_ix_{n-k_i}=0,\;n=0,1,2,{\cdots},$$ where $p_i{\in}\mathbb{R}$, $k_i{\in}\mathbb{Z}$ for $i=1,2,{\cdots},m$. The results are given terms of the $p_i$ and the $k_i$ for each $i=1,2,{\cdots},m$.

• Communications of the Korean Mathematical Society
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• v.36 no.4
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• pp.715-727
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• 2021

In this paper, we give some results an upper bound of Hankel determinant of H₂(1) for the classes of 𝓝 (𝜶). We get a sharp upper bound for H₂(1) = c₃ - c²₂ for 𝓝 (𝜶) by adding z₁, z₂, …, z_n zeros of f(z) which are different than zero. Moreover, in a class of analytic functions on the unit disc, assuming the existence of angular limit on the boundary point, the estimations below of the modulus of angular derivative have been obtained. Finally, the sharpness of the inequalities obtained in the presented theorems are proved.

• Asian Journal of Turfgrass Science
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• v.15 no.2
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• pp.39-50
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• 2001

This research was designed to develop the rapid propagation technology of zoysiagrass using carpet production and to provide turf-growing farmers with efficient cultivation methods thor carpet production. Turfgrass cultivar tested in cadet production by seeding was Z. japonica cv. Zenith. Since the surface coverage rate reached to 85% in 2 months after seeding at the rate 6g/$m^2$ in the early part of July, carpet production using ‘Zenith’seeds would be possible to produce within within the same year. Thrfgrasses tested in carpet production by vegetative propagation were Z. japonica, medium type Z. matrella, fine type Z. matrella, and medium type Z. japonica. Planting rates of vegetative parts (sprigs) were 1.2L/$m^2$, 2.4L/$m^2$, 2.5L/$m^2$, and 5L/$m^2$. Two different sizes of sprig were used; 1~2 nodes and 3~4 nodes. Surface coverage rate was 90% in one year after planting at the rate of 2.5L sprigs of medium type Z. japonica. Therefore, the use of sprigs with 3~4 nodes at the planting rate of 2.5L would be suitable for the carpet prodcution. Three months old zoysiagrass carpet (Zenith) was overseeded with Kentucky bluegrass, perennial ryegrass, and tall fescue at two different overseeding rate. Surface coverage rate was the highest (80%) at the plot overseeded with perennial ryegrass that showed the earliest germination. Suitable overseeding species for the rapid sod formation at the early stage of establishment were tall fescue and perennial ryegrass and desirable overseeding time was from early to middle of September.