• Title/Summary/Keyword: $K_s$

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Study on the Solubilization of Phenoxide Anion by Mixed Surfactant Systems of CTAB and TTAB (CTAB/TTAB 혼합계면활성제에 의한 Phenoxide 음이온의 가용화에 대한 연구)

  • Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.44 no.3
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    • pp.177-183
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    • 2000
  • The interaction of phenoxide anion with .the mixed micelles of CTAB(Cetyl-trimethylammonium bromide) and TTAB(Tetradecyltrimethylammonium bromide) was studied by UV/Vis spectrophotometric method. The solubilization constants($K_s$) of phenoxide anion into the mixed micellar phase and the critical micellar concentrations(CMC) of those mixed surfactant systems have been measured and analyzed with the change of overall mole fraction of CTAB($\alpha_{CTAB}$) The effects of additives(n-pentanol and NaBr) on the solubilization of phenoxide anion by those mixed surfactant systems have been also measured. There was a great decrease on the values of solubilization constant and CMC with these additives. For the thermodynamic study, the dependence of $K_s$ values on temperature has been measured and various thermodynamic parameters(${\Delta}G^0_s$, ${\Delta}H^0_s$ and ${\Delta}S^0_s$) have been also calculated. The results show that all the values of ${\Delta}G^0_s$ and ${\Delta}H^0_s$ are negative within the measured temperature region but the values of ${\Delta}S^0_s$ are positive.

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Solubilization of Monochlorophenol Isomers by the Aqueous Solution of Tetradecyltrimethylammonium bromide (Tetradecyltrimethylammonium bromide 수용액에서 Monochlorophenol 이성질체들의 가용화에 대한 연구)

  • Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.337-342
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    • 2010
  • The interaction of monochlorophenol isomers with the micellar system of TTAB (tetradecyltrimethylammonium bromide) was studied by the UV/Vis spectrophotometric method. The solubilization constants ($K_s$) of monochlorophenol isomers into this micellar system have been measured with the change of temperature. Various thermodynamic parameters (${\Delta}G^{\circ}_s$, ${\Delta}H^{\circ}_s$, and ${\Delta}S^{\circ}_s$) have been calculated and analyzed from the dependence of $K_s$ values on the temperature. The results show that the values of ${\Delta}G^{\circ}_s$ and ${\Delta}H^{\circ}_s$ are all negative but the values of ${\Delta}S^{\circ}_s$ are all positive for the solubilizations of all isomers within the measured temperature range. The effects of additives (n-butanol and NaCl) on the solubilization of monochlorophenol isomers by the same surfactant system have been also measured. There was a great change on the values of $K_s$ and CMC simultaneously with these additives. From these changes we can postulate the solubilization sites of each isomer in the micellar system of TTAB.

Vitrification of Bovine Immature Oocytes using Microdrop Method

  • Park, H.S.;Kim, D.H.;Kim, S.W.;Yang, B.C.;Im, G.S.;Hwang, I.S.;Seo, J.S.;Yang, B.S.;Moon, S.J.;Chang, W.K.
    • Proceedings of the KSAR Conference
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    • 2004.06a
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    • pp.258-258
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    • 2004
  • Successful cryopreservation of mammalian oocytes would provide a source of materials for in vitro embryo production. This study was conducted to determine vitrification conditions for bovine immature oocytes using micro-drop method and, to examine maturation, fertilization and development of vitrified bovine immature oocytes. (omitted)

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Description of Lycoris chinensis Traub var. sinuolata K. Tae et S. Ko ex K. Tae et S. Ko (Amaryllidaceae) (진노랑상사화 Lycoris chinensis Traub var. sinuolata K. Tae et S. Ko ex K. Tae et S. Ko (Amaryllidaceae)에 대한 기재)

  • Tae, Kyoung-Hwa;Ko, Sung-Chul
    • Korean Journal of Plant Taxonomy
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    • v.33 no.4
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    • pp.387-392
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    • 2003
  • For Lycoris chinensis Traub var. sinuolata K. Tae et S. Ko ex K. Tae et S. Ko, Korean endemic plant, latin description is add to the previous study, and a key including L. chinensis Traub and L. aurea Herb. which are closely related to the above variety, is newly provided.

A study on SFCL application for the interconnection operation of 154kV power systems under 345kV S/S in Korean power system

  • Lee Seung Ryul;Kim Jong Yul;Yoon Jae Young
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.2
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    • pp.47-51
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    • 2005
  • This paper is for studying the feasibility of SFCL application for the interconnection operation of 154kV power systems under 345kV S/S in Korean power system. All Korean 154kV power systems are constructed as loop systems in downtown. However, the present 154kV systems are operated with separated systems around 345kV S/S because of fault current and overload problems. In this study, we investigate the structure and operation of 154kV power system in Seoul and study the feasibility of interconnection operation of 154kV systems under 345kV systmes by applying SFCLs to 154kV bus-tie.

Some Characterizations of Catenary Rotation Surfaces

  • Kim, Dong-Soo;Kim, Young Ho;Yoon, Dae Won
    • Kyungpook Mathematical Journal
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    • v.57 no.4
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    • pp.667-676
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    • 2017
  • We study the positive $C^1$ function z = f(x, y) defined on the plane ${\mathbb{R}}^2$. For a rectangular domain $[a,b]{\times}[c,d]{\subset}{\mathbb{R}}^2$, we consider the volume V and the surface area S of the graph of z = f(x, y) over the domain. We also denote by (${\bar{x}}_V,\;{\bar{y}}_V,\;{\bar{z}}_V$) and (${\bar{x}}_S,\;{\bar{y}}_S,\;{\bar{z}}_S$) the geometric centroid of the volume under the graph of z = f(x, y) and the centroid of the graph itself defined on the rectangular domain, respectively. In this paper, first we show that among nonconstant $C^2$ functions with isolated singularities, S = kV, $k{\in}{\mathbb{R}}$ characterizes the family of catenary rotation surfaces f(x, y) = k cosh(r/k), $r={\mid}(x,y){\mid}$. Next, we show that one of $({\bar{x}}_S,\;{\bar{y}}_S)=({\bar{x}}_V,\;{\bar{y}}_V)$, $({\bar{x}}_S,\;{\bar{z}}_S)=({\bar{x}}_V,\;2{\bar{z}}_V)$ and $({\bar{y}}_S,\;{\bar{z}}_S)=({\bar{y}}_V,\;2{\bar{z}}_V)$ characterizes the family of catenary rotation surfaces among nonconstant $C^2$ functions with isolated singularities.

Enhanced Photosensitivity in Monolayer MoS2 with PbS Quantum Dots

  • Cho, Sangeun;Jo, Yongcheol;Woo, Hyeonseok;Kim, Jongmin;Kwak, Jungwon;Kim, Hyungsang;Im, Hyunsik
    • Applied Science and Convergence Technology
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    • v.26 no.3
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    • pp.47-49
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    • 2017
  • Photocurrent enhancement has been investigated in monolayer (1L) $MoS_2$ with PbS quantum dots (QDs). A metal-semiconductor-metal (Au-1L $MoS_2$-Au) junction device is fabricated using a standard photolithography method. Considerably improved photo-electrical properties are obtained by coating PbS QDs on the Au-1L $MoS_2$-Au device. Time dependent photoconductivity and current-voltage characteristics are investigated. For the QDs-coated $MoS_2$ device, it is observed that the photocurrent is considerably enhanced and the decay life time becomes longer. We propose that carriers in QDs are excited and transferred to the $MoS_2$ channel under light illumination, improving the photocurrent of the 1L $MoS_2$ channel. Our experimental findings suggest that two-dimensional layered semiconductor materials combined with QDs could be used as building blocks for highly-sensitive optoelectronic detectors including radiation sensors.