• Title/Summary/Keyword: $CO_2$ source

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Effects of $CO_2$ addition to Oxygen-Enriched Combustion (산소부화연소에서 $CO_2$ 첨가에 대한 영향)

  • Kim, Ho-Keun;Kim, Han-Seok;Ahn, Kook-Young;Kim, Yong-Mo
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1389-1394
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    • 2003
  • $CO_2$ is a well-known green house gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. But the adiabatic flame temperature is too high. So existing facilities must be changed, or the adiabatic flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were studied experimentally for the various oxygen-enriched mtios(OER) by addition of $CO_2$ under coustant $O_2$ flowrate. Results showed that the reaction zone was quenched, broadened, as addition of $CO_2$ was increased. Temperature has a large effect on the NOx emission. The emission of NOx in flue gas decreased due to the decreased temperature of reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0, but the composition of CO decreased by quenching effect at OER=50 and 100%.

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Construction of Laser-heated Pedestal Growth System for Single Crystal Fibers (Fiber형 단결정 성장을 위한 LHPG 장치의 제작)

  • 임기수
    • Korean Journal of Optics and Photonics
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    • v.4 no.1
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    • pp.114-119
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    • 1993
  • We constructed a laser-heated pedestal growth station using a 25 W $CO_2$ laser to grow various single crystal fibers. The LHPG system consists of the optical system which includes a reflaxicon, an elliptic mirror and a parabolic mirror with their centers drilled, and the translation system to move a source and a seed independently. To test the system, we pulled a few ruby fibers with diameter of 600 ${\mu}m$ and length of 2 cm, and studied characteristics of their photoluminescence.

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Nitrogen and Fluorine Co-doped Activated Carbon for Supercapacitors

  • Kim, Juyeon;Chun, Jinyoung;Kim, Sang-Gil;Ahn, Hyojun;Roh, Kwang Chul
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.338-343
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    • 2017
  • Activated carbon has lower electrical conductivity and reliability than other carbonaceous materials because of the oxygen functional groups that form during the activation process. This problem can be overcome by doping the material with heteroatoms to reduce the number of oxygen functional groups. In the present study, N, F co-doped activated carbon (AC-NF) was successfully prepared by a microwave-assisted hydrothermal method, utilizing commercial activated carbon (AC-R) as the precursor and ammonium tetrafluoroborate as the single source for the co-doping of N and F. AC-NF showed improved electrical conductivity ($3.8\;S\;cm^{-1}$) with N and F contents of 0.6 and 0.1 at%, respectively. The introduction of N and F improved the performance of the pertinent supercapacitor: AC-NF exhibited an improved rate capability at current densities of $0.5-50mA\;cm^{-2}$. The rate capability was higher compared to that of raw activated carbon because N and F codoping increased the electrical conductivity of AC-NF. The developed method for the co-doping of N and F using a single source is cost-effective and yields AC-NF with excellent electrochemical properties; thus, it has promising applications in the commercialization of energy storage devices.

Geochemistry and Origin of $CO_2$-rich Groundwater from Sedimentary Rocks of Kyungsang System (경상계 퇴적암에서 산출되는 탄산지하수의 지화학적 특성과 생성기원)

  • 정찬호;이진국
    • The Journal of Engineering Geology
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    • v.10 no.1
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    • pp.51-62
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    • 2000
  • The $CO_2$-richrich water pumps or springs out at two sites (Sinchon and Kohran) consisting of Cretaceous sedimentary rocks in Kyungpook area. The water has been long known as its soda pop-liketaste and therapeutic effect against calcium deficit, stomach and skin troubles, etc. The water arecharacterized by a high $CO_2$ concentration $(P_{CO2}=0.29~l.01 atm)$ and electrical conductance (1,093~2,810$\mu$S/cm). The $CO_2$-rich water belongs to Ca(Na)-$HCO_3$ type in chemical classification. The contents of Ca, Mg, Na, HCO$_3$ and Fe of $CO_2$-rich water show much higher values than those of general groundwater Environmental isotopic data $(^2H/^1H, ^{18}O/^{16}O and ^3H/^1H)$ indicate that the water is ofmeteoric origin recharged after 1950s. The $CO_2$ in the springs seems to be originated from deep-seatedsource related to acidic porphyry and granite nearby sedimentary rocks. Carbonate minerals and albiteare likely to be the major source minerals of the dissoved inorganic constituents in the $CO_2$-rich water.The equilibrium state between major minerals and $CO_2$-rich water was calculated by a thermodynamicprogram.

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Estimation and Feature of Greenhouse Gas Emission in Building Sector by National Energy Statistic (국가 에너지통계에 따른 건물부문 온실가스 배출량 추계 및 특성)

  • Jeong, Young-Sun;Kim, Tae-Hyoung
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.7
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    • pp.187-195
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    • 2019
  • In December 2015, The Paris Agreement was adopted to undertake ambitious efforts to combat climate change. Korean government announced its goal of reducing the country's greenhouse gas emissions by up to 37% below business as usual projections by 2030 in 2015. The purpose of this study was to set up the calculation methodology of GHG emission($CO_{2e}$) in building sector and to estimate the annual GHG emission in building sector based on national energy consumption statistic. The GHG emission from buildings is about 135.8 million ton $CO_{2e}$ as of 2015, taking up about 19.6% of Korea's entire emission and is about 144.7 million ton $CO_{2e}$ in 2017. The GHG emission of building sector is increasing at annual rate of 2.0% from 2001 to 2017. The GHG emission from electricity consumption in buildings is 91.8 million ton $CO_{2e}$ in 2017, is the highest $CO_2$ emission by energy source. The results show that the intensity of GHG emission of residential building sector is $40.6kg-CO_{2e}/m^2{\cdot}yr$ and that of commercial building sector is $68.4kg-CO_{2e}/m^2{\cdot}yr$.

A $LN_2$-cooled, Broadband cw CO Laser (액체질소 냉각형광대역 cw CO 레이저)

  • Kim, Y.P.;Choi, J.W.;Won, J.W.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.667-671
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    • 1989
  • The CO laser is one of powerful light source for laser magnetic resonance spectroscopy in the mid-infrared region of the spectrum because of its wideband operational characteristics. In this work, a liquid nitrogen cooled cw CO laser is developed to allow broad-band operation from 5 to 8 ${\mu}m$. The design details will be presented.

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Electrical properties of Ultra-Shallow Junction formed by using Epitaxial $CoSi_{2}$ Thin Film as Diffusion Source ($CoSi_{2}$ 에피박막을 확산원으로 이용하여 형성한 매우 얇은 접합의 전기적 특성)

  • Koo, Bon-Cheol;Shim, Hyun-Sang;Jung, Yun-Sil;Bae, Kyoo-Sik
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.470-473
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    • 1998
  • $As^+$ was ion-implanted onto $CoSi_{2}$ thin films formed by rapidly thermal-annealed Co/Ti bilayers. Then the specimens were drive-in annealed at 500~100$0^{\circ}C$ to form ultra-shallow $n^+$p junction diodes and to measure their 1- V characteristics. When drive-in annealed at 50$0^{\circ}C$ for 280 sec., 50 nm thick ultra-shallow junctions were formed and di¬odes showed the best 1- V characteristics with low leakage current. In particular. the leakage current was 2 orders lower than that of diodes formed by using Co monolayer. It was attributed to uniform $CoSi_{2}$/Si interfaces.

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Microstructure and Properties of Nano-Sized Ni-Co Particulate Dispersed $Al_2O_3$ Matrix Nanocomposites

  • Oh, Sung-Tag;Mutsuo Sando;Koichi Niihara
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.334-339
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    • 1998
  • In purpose of introducing the inverse magnetostrictive properties into the structural ceramics, $Al_2O_3$ based nanocomposites dispersed with nano-sized Ni-Co particles were studied. The composites were fabricated by the hydrogen reduction and hot-pressing of $Al_2O_3$ and NiO-CoO mixed powders. The mixtures were prepared by using Ni- and Co-nitrate $(Ni(NO_3)_2\;{\cdot}\;6H_2O\;and\;Co(NO_3)_2\;{\cdot}\6H_2O)$ as source materials for the Ni-Co particles. Microstructural observations revealed that nano-sized Ni-Co particles were dispersed homogeneously at $Al_2O_3$ grain boundaries. High strength above 1 GPa was obtained for the $Al_2O_3/10$ wt% Ni-Co nanocomposite fabricated by a controlled powder preparation process. The inverse magnetostrictive response to applied stress was obtained due to the presence of dispersed Ni-Co particles, which indicates a possibility to incorporate new functions into the structural ceramics without loosing the mechanical properties.

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Synthesis of CoSe2/RGO Composites and Its Application as a Counter Electrode for Dye-Sensitized Solar Cells

  • Ko, Yohan;Choi, Wooyeol;Kim, Youbin;Lee, Chanyong;Jun, Yongseok;Kim, Junhee
    • Journal of Electrochemical Science and Technology
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    • v.10 no.3
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    • pp.313-320
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    • 2019
  • In this study, cobalt diselenide ($CoSe_2$) and the composites ($CoSe_2@RGO$) of $CoSe_2$ and reduced graphene oxide (RGO) were synthesized by a facile hydrothermal reaction using cobalt ions and selenide source with or without graphene oxide (GO). The formation of $CoSe_2@RGO$ composites was identified by analysis with X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and scanning electron microscopy (SEM). Electrochemical analyses demonstrated that the $CoSe_2@RGO$ composites have excellent catalytic activity for the reduction of $I_3{^-}$, possibly indicating a synergetic effect of $CoSe_2$ and RGO. As a consequence, the $CoSe_2@RGO$ composites were applied as a counter electrode in DSSC for the reduction of redox couple electrolyte, and exhibiting the comparable power conversion efficiency (7.01%) to the rare metal platinum (Pt) based photovoltaic device (6.77%).

Purification and Characterization of Bioactivity Compound Acemannan from Aloe vera (알로에 베라로부터 생리 활성 물질인 아세만난 분리 정제와 특성)

  • Ryu, Il-Whan;Sim, Chang-Sup;Lee, So-Young
    • Korean Journal of Pharmacognosy
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    • v.28 no.2
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    • pp.65-71
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    • 1997
  • This study was carried out to purify and to characterize various bioactive material acemannan from Aloe vera. Purified acemannan was mannose (67%) and acetyl group (23%), and the rest of glucose was galactose that consists of long chain polydispered beta-(1, 4) linked mannan polymers. The sugar and acetyl group in the molecule were linked by molar ratio of 3 : 1. This polysaccharide from Aloe vera may provide functional flood and potential drug source with antiviral and immunomodulating properties.

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