• Title/Summary/Keyword: $CO_2$ and $H_2O$ effects

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Effects of $SiO_2$ and Seed on Ba-ferrite Synthesized by Molten Salt (용융염법으로 합성한 Ba-ferrite의 $SiO_2$ 및 Seed 첨가 효과)

  • 김영근;이승관;김현식;오영우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.326-329
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    • 1996
  • In order to synthesize Ba-ferrite fine particles by molten salt method and inhibit the abnormal grain growth of sintered specimen, KCI anti NaCl were added to basic composition to 50% by weight, and added 1 male% of $SiO_2$ to control the shape of Ba-ferrite particles. $H_{c}$ and $M_{r}$ were decreased when F $e^{3+}$ was substituted with $Co_{2+}$ and $Ti_{4+}$ from x=0 to x=1.0 in $BaFe_{12-2x}$ $Ti_{x}$ $Co_{x}$ $O_{19}$ , and 1 mole% $SiO_2$ increased the size but shortened c-axis of hexagonal ferrite. Seeds added in Ba-ferrite particle effected inhibition of abnormal grain growth during sintering.ing.g.

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SiGe Surface Changes During Dry Cleaning with NF3 / H2O Plasma (NF3 / H2O 원거리 플라즈마 건식 세정에 의한 SiGe 표면 특성 변화)

  • Park, Seran;Oh, Hoon-Jung;Kim, Kyu-Dong;Ko, Dae-Hong
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.2
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    • pp.45-50
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    • 2020
  • We investigated the Si1-xGex surface properties when dry cleaning the films using NF3 / H2O remote plasma. After the dry cleaning process, it was found that about 80-250 nm wide bumps were formed on the SiGe surface regardless of Ge concentration in the rage of x = 0.1 ~ 0.3. In addition, effects of the dry cleaning processing parameters such as pressure, substrate temperature, and H2O flow rates were examined. It was found that the surface bump is significantly dependent on the flow rate of H2O. Based on these observations, we would like to provide additional guidelines for implementing the dry cleaning process to SiGe materials.

The Calculation of Radiative Heat Transfer from Turbulent Diffusion Flames Using the Finite Volume Method (유한 체적법을 이용한 난류 확산 화염에서의 복사 열전달 계산)

  • Kim S. H.;Huh K. Y.
    • 한국전산유체공학회:학술대회논문집
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    • 1997.10a
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    • pp.106-112
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    • 1997
  • The effects of radiative heat transfer are investigated in a turbulent combustion flow field with highly non-adiabatic flames. Turbulent combustion is modeled by the $k-{\varepsilon}-g$ model and a one step irreversible reaction scheme for the combustion chemistry. The radiative trasport equation is solved by the finite volume method considering the radiative transfer from $CO_2,\;H_{2}O$ and soot only. Gray gas is assumed to calculate the radiative properties of $CO_2\;and\;H_2O$. A two-equation soot formation model is applied to predict soot volume faction distribution. All equations are solved in a coupled manner and the numerical results are compared with available experimental data.

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The Doping and Plasma Effects on Gas Sensing Properties of α-Fe2O3 Thin Film

  • Choi, J.Y.;Jang, G.E.
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.5
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    • pp.189-193
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    • 2004
  • Pure and Sn or Pt doped $\alpha-Fe_2O_3$ thin films were prepared on $Al_2O_3$ substrates by RF-magnetron sputtering method and the sensitivities were compared. It was found that pure $\alpha-Fe_2O_3$ thin films did not exhibit much selectivity in CO and $i-C_4H_{10}$ gases while it showed the high sensitivity in proportion to the gas concentration of $C_2H_{5}OH$ gas. Pt-doped $\alpha-Fe_2O_3$ showed to be alike sensing properties as pure $\alpha-Fe_2O_3$ thin film in $C_2H_{5}OH$ gas. However, Sn-doped $\alpha-Fe_2O_3$ thin films exhibited the excellent sensitivity and selectivity in Hz gas. After microstructure modification by plasma etching on pure $\alpha-Fe_2O_3$ thin films, the gas sensing characteristics were dramatically changed.

Thermal Shock Behavior of $Al_2O_3$-$ZrO_2$ Ceramics Prepared by a Precipitation Method (침전법으로 제조한 $Al_2O_3$-$ZrO_2$계 세라믹스의 열충격 거동)

  • 홍기곤;이홍림
    • Journal of the Korean Ceramic Society
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    • v.28 no.1
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    • pp.11-18
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    • 1991
  • A precipitation method, one of the most effective liquid phase reaction methods, was adopted in order to prepare high-tech Al2O3/ZrO2 composite ceramics, and the effects of stress-induced phase transformation of ZrO2 on thermal shock behavior of Al2O3-ZrO2 ceramics were investigated. Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O were used as starting materials and NH4OH as a precipitation agent. Metal hydroxides were obtained by single precipitation(process A) and co-precipitation(process B) method at the condition of pH=7, and the composition of Al2O3-ZrO2 composites was fixed as Al2O3-15v/o ZrO2(+3m/o Y2O3). Critical temperature difference showing rapid strength degradation by thermal shock showed higher value in Al2O3/ZrO2 composites(process A : 20$0^{\circ}C$, process B : 215$^{\circ}C$) than in Al2O3(175$^{\circ}C$). The improvement of thermal shock property for Al2O3/ZrO2 composites was mainly due to the increase of strength at room temperature by adding ZrO2. The strength degradation was more severe for the sample with higher strength at room temperature. Crack initiation energies by thermal shock showed higher values in Al2O3/ZrO2 composites than in Al2O3 ceramics due to increase of fracture toughness by ZrO2.

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An Effects of $CO_2$ Addition on Flame Structure in a Non-premixed Counterflow Flame (비예혼합 대향류 화염에서 $CO_2$ 첨가가 화염 구조에 미치는 영향 연구)

  • Lee, Kee-Man
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.166-173
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    • 2007
  • A numerical study was conducted to have the effect of $CO_2$ addition to fuel on the chemical reaction mechanism with the change of the initial concentration of $CO_2$ and the axial velocity gradient. From this study, it was found that there were two serious effects of $CO_2$ addition on a non-premixed flame ; a diluent effect by the reactive species reduction and chemical effect of the breakdown of $CO_2$ by the third-body collision and thermal dissociation. Especially, the chemical effect was serious at the lower velocity gradient of the axial flow. It was certain that the mole fraction profile of $CO_2$ was deflected and CO was increased with the initial concentration of $CO_2$. It was also ascertained that the breakdown of $CO_2$ would cause the increasing of CO mole fraction at the reaction region. It was also found that the addition of $CO_2$ did not alter the basic skeleton of $H_2-O_2$ reaction mechanism, but contributed to the formation and destruction of hydrocarbon products such as HCO. The conversion of CO was also suppressed and $CO_2$ played a role of a dilution in the reaction zone at the higher axial velocity gradient.

Coal Gasification Performance with Key Operating Variables (주요 운전 변수에 따른 석탄의 가스화 성능 예측)

  • Lee, Seung-Jong;Chung, Seok-Woo;Yun, Yong-Seung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.437-440
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    • 2007
  • Gasification converts coal and other feedstocks into a very clean and usable gas, called syngas, that can be used to produce a wide variety products such as electricity, chemicals, transports fuels, hydrogen production, etc. This paper was studied the gasification performance effects with the variation of the gasification operating parameters such as the feeding amounts of oxygen, steam and coal. When $O_2/coal$ ratio was below 0.8, $H_2$ mole % was increased as increasing $O_2/coal$ ratio. CO mole % was increased when $O_2/coal$ ratio was below 1.2 as increasing the $O_2/coal$ ratio. As increasing steam/coal ratio, $H_2$ mole %was increased and CO mole % was decreased. The $O_2/coal$ and steam/coal ratio was $0.8{\sim}0.9$ and $0.0{\sim}0.4$, respectively, to keep the proper gasification condition that the gasifier temperature was $1300^{\circ}C{\sim}1450^{\circ}C$ and the cold gas efficiency was over 76%.

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A Study on the Lifted Flame Structure with Strain Rates in Premixed Impinging Jet Flames of Syngas (H2/CO) (합성가스(H2/CO) 예혼합 충돌 제트화염에서 신장률에 따른 부상된 화염 구조에 관한 연구)

  • SIM, KEUNSEON;JANG, BYOUNGLOK;LEE, KEEMAN
    • Journal of Hydrogen and New Energy
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    • v.26 no.4
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    • pp.347-356
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    • 2015
  • A study has been conducted numerically to investigate the lifted flat syngas flame structure of impinging jet flame configuration with the global strain rates in 10% hydrogen content. In this study, the effects of strain rate were major parameters on chemistry kinetics and flame structure at stagnation point. The numerical results were calculated by SPIN application of the CHEMKIN package. The strain rates were adjusted with Reynolds numbers of premixed syngas-air mixture. Different flame shapes were observed with different strain rates. As strain rate has increased, the flame temperature and axial velocity have been decreased due to the flame heat loss increment, and the OH radical reaction zones become narrower but each mole fractions are still constant. Also, the reversion of $H_2O$ product near stagnation point has been found out when strain rate has increased. This phenomenon is attributed to the rapid production of oxidizing radical reaction such as the R12 ($H+O_2(+M)=HO_2(+M)$), which makes the R18 ($HO_2+OH=O_2+H_2O$) reaction increment.

Characteristics of CuO doped WO3-SnO2 Thick Film Gas Sensors (CuO가 첨가된 WO3-SnO2 후막 가스센서 특성 연구)

  • Lee, Don-Kyu;Shin, Deuck-Jin;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.956-960
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    • 2010
  • CuO doped $WO_3-SnO_2$ thick film gas sensors were fabricated by screen printing method on alumina substrates and heat-treated at $350^{\circ}C$ in air. The effects of mixing ratio of $WO_3$ with $SnO_2$ on the structural and morphological properties of $WO_3-SnO_2$ were investigated X-ray diffraction and Scanning Electron Microscope. The structural properties of the $WO_3-SnO_2$:CuO thick film by XRD showed that the monoclinic of $WO_3$ and the tetragonal of $SnO_2$ phase were mixed. Nano CuO was coated on the $WO_3-SnO_2$ surface and then the surface of $WO_3$ was coated with $SnO_2$ particles with $1\sim1.5{\mu}m$ in diameters, as confirmed form the SEM image. The sensitivity of the $WO_3-SnO_2$:CuO sensor to 2000 ppm $CO_2$ gas and 50 ppm $H_2S$ gas for the various ratio of $WO_3$ and $SnO_2$ was investigated. The 4 wt% CuO doped $WO_3-SnO_2$(75:25) tkick films showed the highest sensitivity to $CO_2$ gas and $H_2S$ gas.

A Study of pH, Duty Cycle, Agitation on the Property of Co-deposited TiO2 and Thermal Stability in the Electrodeposited Ni-TiO2 Composite (pH, duty cycle, 교반, 첨가제가 Ni-TiO2 전기도금 복합체의 TiO2 공석특성과 열적안정성에 미치는 영향 연구)

  • Kim, Myong-Jin;Kim, Joung-Soo;Kim, Dong-Jin;Kim, Hong-Pyo;Hwang, Seong-Sik
    • Journal of the Korean institute of surface engineering
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    • v.45 no.3
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    • pp.97-105
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    • 2012
  • The effects of pH, types of applied current, agitation method and time, additive on the amount of co-deposited $TiO_2$ particles in the matrix were investigated. The deposition rates increased with increasing pH values, while the volume fraction of $TiO_2$ particles and the size of agglomerated $TiO_2$ particles in the composite decreased. The volume fraction of $TiO_2$ particles in the composite decreased when pulsed current of 50% duty cycle was used. And the size of agglomerated $TiO_2$ particles in the nickel matrix of pulsed current was smaller than that of DC current specimen. The volume fraction of $TiO_2$ particles in the matrix decreased with longer time by air agitation, but in case of using magnetic bar, volume fraction in the same range of time was relatively constant. The volume fraction of the electrodeposited Ni-$TiO_2$ composite in the solution containing 0.01 M Dimethylamine borane (DMAB) increased slightly with increasing agitation time regardless of agitation methods. Thermal stability of the electrodeposited Ni-$TiO_2$ composite increased with lower pH at the temperature range of $200{\sim}800^{\circ}C$, and the results showed that the amount of co-deposited $TiO_2$ relies more on the deposition rate than zetapotential of $TiO_2$ particles.