• Proceedings of the Materials Research Society of Korea Conference
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• 1995.11a
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• pp.6-6
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• 1995

• Applied Chemistry for Engineering
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• v.21 no.4
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• pp.391-395
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• 2010

This study presents the effect of CO in flue gas on the $H_2$ SCR by Pt/$TiO_2$ catalyst. Coexisting CO which has characteristics of competitive adsorption with $H_2$ as a reductant on the active sites showed the decrease of catalytic activity. Competitive adsorption with NO, CO and $H_2$ also caused the reduction of activity and $H_2$, CO slip simultaneously. With increasing the inlet CO concentration, such phenomenon became more pronounced. Adding $PdO_2$ and $CeO_2$ on the catalyst to avoid the inhibition by coexisting CO, $CeO_2$ added catalyst exhibited the durability against CO which fed 100 ppm under.

• Environmental and Resource Economics Review
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• v.23 no.4
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• pp.667-688
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• 2014

This research tested the EKC (Environment Kuznets Curve) Hypothesis using the $CO_2$ Emissions by region and GRDP. We built the panel data set on the 15 local government region from 1990 to 2010 for this analysis. GRDP, population and total factor productivity was considered as the factors influencing on the regional $CO_2$ Emissions. Analysis method in this research is panel GLS model as Lantz and Feng (2006). The results show that the EKC hypothesis did not hold in Korea but there is inverted U relationship between the $CO_2$ Emissions and total factor productivity. As the total factor productivity grows, the $CO_2$ increased but decreased after a certain level.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.239-239
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• 2010

Cobalt (Co) 박막은 낮은 저항과 우수한 열적 안정성에 의해 금속 배선공정에서 copper의 확산 및 산화를 방지하기 위해 사용된다. Co 박막을 증착하기 위해서는 유기화학 증착법이 많이 사용되고, 이를 위해 많은 Co 전구체들이 연구되어지고 있다. 본 연구에서는 $Co(hfac)_2$ 전구체의 플라즈마 및 반응가스에 따른 기상상태의 변화와 증착공정에서 발생되는 입자의 크기와의 상관관계를 연구하였다. 실험의 변수로 반응가스 ($H_2$, $H_2O$)와 플라즈마 파워 (0~50W)를 사용하였다. 또한 Co 전구체의 기상분해 및 반응을 분석을 위해 fourier transform infrared (FT-IR) spectroscopy를 사용하였다. 그리고 기상상태의 변화가 입자 형성에 끼치는 영향을 관찰하기 위해 저압에서 실시간으로 나노입자를 측정할 수 있는 장비인 particle beam mass spectrometer (PBMS)를 활용하였다.

• Clean Technology
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• v.19 no.4
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• pp.370-378
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• 2013

This review has shown the capability of MOFs and ZIFs materials to adsorb $CO_2$ under typical PSA temperatures and pressures. The usual operating conditions are adsorption temperatures of $15{\sim}40^{\circ}C$ and adsorption pressures of 4~6 bar based on numerous PSA processes which are widely employed in gases industry for adsorptive separation of $CO_2$. The extent of $CO_2$ adsorption on the microporous materials depends on the metal species and organic linkers existing in the frameworks. The pore size and the surface area, and the process variables are the key parameters to be associated with the efficiency of the adsorbents, particularly adsorption pressures if other variables are comparable each other. The MOFs and ZIFs materials require high pressures greater than 15 bar to yield significant $CO_2$ uptakes. They possess a $CO_2$ adsorption capacity which is very similar to or less than that of conventional benchmark adsorbents such as zeolites and activated carbons. Consequently, those materials have been much less cost-effective for adsorptive $CO_2$ separation to date because of very high production price and the absence of commercially-proven PSA processes using such new adsorbents.

• Korean Journal of Ecology and Environment
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• v.46 no.1
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• pp.75-85
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• 2013

This study investigated the effects of organic matter decomposition on the emission of greenhouse gas under the influence of environmental factors such as change of climate condition ($CO_2$ concentration and temperature), vegetation, and N concentration in the soil of Gyeongan stream in the laboratory. The experimental results showed that organic matter decomposition and $CH_4$, $CO_2$ flux were influenced by changes of complex environmental conditions. Organic matter decomposition rate was affected by changes of climate condition with N concentration and climate condition with vegetation. Through the results of $CH_4$, $CO_2$ flux, $CH_4$ flux was affected by change of climate condition with N concentration and climate condition with vegetation and affected by the presence of vegetation and N concentration. $CO_2$ flux was affected by change of climate condition with vegetation and vegetation with N concentration. According to results of the study, change of (1) climate conditions, (2) vegetation, and (3) N concentration, each have an effect on organic decomposition rate, that also influences emission of greenhouse gas. It is known that climate change is related to an increase in greenhouse gasses in the atmosphere However, additional study will be needed whether vegetation could remove positive effect of nitrogen addition in soil since this study shows opposite results of organic matter decomposition in response to the nitrogen addition.

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.44-51
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• 2006

Effects of multiple-cycle operation and $SO_2$ concentration on $CO_2$ capture characteristics of three limestones were investigated in a fluidized bed reactor. For each of these sorbents, the measured $CO_2$ capture capacity decreased as the number of cycles increased and as the $SO_2$ concentration increased. On the other hand, the $SO_2$ capture increased with the increased number of cycles and the $SO_2$ concentration. The total calcium utilization decreased as the number of cycles increased, but the effect of $SO_2$ concentrations on the total calcium utilization depended on the type of limestone. For Strassburg limestone, the total calcium utillization decreased with increasing $SO_2$ concentration. However, for Luscar and Danyang limestones, the total calcium utilization was almost independent of $SO_2$ concentration for the range investigated. The results showed that $SO_2$ in flue gas reduced the $CO_2$ capture capacity of limestone and that the sulfation pattern affected the $CO_2$ capture capacity.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.117-117
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• 2010

석탄 가스화에서 유도된 합성가스는 합성반응 공정을 통하여 합성석유, 메탄올(& DME), 합성천연가스(SNG) 등의 다양한 화학원료를 제조할 수 있어 이의 활용이 점차적으로 확대될 것이다. 이 중 SNG 공정의 경우, 석탄가스화기에서 생산된 합성가스는 집진, 탈황, 수성가스전환($H_2$/CO 비를 조절), $CO_2$ 제거 등의 공정을 거쳐 메탄화 반응기로 유도되는데, 메탄화 반응에서 $CO_2$가 반응에 참여하면 탄소포집 및 저장(CCS)의 부담을 크게 줄일 수 있어 이에 대한 관심이 커지고 있다. 특히, 상업용으로 활용되고 있는 단열반응기를 직렬로 연결할 경우, 메탄화반응의 발열로 인한 반응기내의 온도 상승으로 $CO_2$가 생성되는데 이후의 2차 또는 3차의 단열반응기에서 $CO_2$ 수소화반응이 진행되면 최종 생성물인 메탄의 수율이 증가하며, 뿐만아니라 생성물 중 포함된 수소의 농도를 낮출 수 있는 장점을 가지게 된다. 따라서, 본 연구에서는 Ni계 촉매를 사용하여 풍부한 $H_2$ 분위기에서 Fe를 첨가하여 이의 함량이 $CO_2$ 수소화반응의 탄소 전환율과 생성되는 메탄의 수율에 미치는 영향을 고찰하였다.

• Journal of the Korean Applied Science and Technology
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• v.17 no.2
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• pp.139-143
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• 2000

There appeared enhancements of the conversion of methane by adding a small amount of CO in the aromatization reaction of methane using the Mo-zeolite catalyst. In case of adding $CO_{2}$, $CO_{2}$ changed to CO first, and then the conversion reaction occurred. It was observed by using isotopes as reactants that CO is related to the aromatization reaction of methane.

• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.72-80
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• 1992

Group 6 $M(CO)_4$(2, 2'-bipyridine)[M=Cr, Mo, W] was synthesized by substituting CO ligand of $M(CO)_6$ with strong electron donating ligand, 2, 2'-blpyridine, in the presence of phase transfer catalyst. The effective of catalyst and solvent on the product yield were discussed according to concentration and kinds of catalyst, kinds of center cation and anion, type of alkyl and aryl groups attached to the center cation, and different chain length.