• Title/Summary/Keyword: wet chemistry

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Heat Transfer and Friction Characteristics of Louver Fin and Tube Heat Exchangers under Wet Conditions (루버핀-관 열교환기의 습조건에서의 열전달 및 마찰특성에 대한 실험 연구)

  • Kwon, Young Chul;Chang, Keun Sun
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.73-79
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    • 2008
  • An experimental study was conducted to investigate the effect of a tube row, a fin pitch and an inlet humidity on air-side heat and mass transfer performance of louvered fin-tube heat exchangers under wet conditions. Experimental conditions were varied by three fin pitches, two rows, two inlet relative humidities. Experimental results showed that the heat transfer performance decreased and the friction increased with the decrease of fin pitch, for 2 row heat exchanger. The effect of fin pitch on heat transfer performance was negligible with 3 row heat exchanger. The changes in relative humidity was not affected heat transfer and friction. However, the mass transfer performance was slightly decreased with the increase of relative humidity and with the decrease of fin pitch. The mass transfer performance of the louvered fin-tube heat exchanger decreased with the decrease of the fin pitch and was different according to the number of tube row.

A Study on the Removal of Complex Odor including Acetaldehyde and Ozone Over Manganese-based Catalysts (아세트알데히드와 오존 복합악취 저감을 위한 망간기반 촉매 성능 연구)

  • Seo, inhye;Lee, Minseok;Lee, Sooyoung;Cho, Sungsu;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.193-197
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    • 2017
  • In this study, we report on the catalyst process installed in conjunction with a wet plasma electrostatic precipitator to remove the oil mist and fine dust emitted from large-size grill restaurants. The multi-stage catalyst module reduced odor through catalytic reaction of acetaldehyde on catalysts even at an ambient temperature with ozone as an oxidant readily produced in a wet plasma electrostatic precipitator. Two types of manganese-based catalysts, $Mn_2O_3$ and $CuMnO_x$ were fabricated by extrusion molding for structured catalysts in practical applications, and the optimum conditions for high removal efficiencies of acetaldehyde and ozone were determined. When two optimized catalysts were applied in a two-stage catalyst module, the removal efficiency of acetaldehyde and ozone were ${\geq}85%$ and 100% respectively at the space velocity of $10,000h^{-1}$ and the reaction temperature of $100^{\circ}C$.

Glass Thinning by Fluoride Based Compounds Solution with Low Hydrofluoric acid Concentration (저불산 불소계 화합물 수용액을 이용한 글라스 박판화)

  • Kim, Ho-Tae;Gang, Dong-goo;Kim, Jin-Bae
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.557-560
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    • 2009
  • In this study, a new wet etching method and the solution for thinning the glass with the thickness below $100{\mu}m$ were investigated. For the preparation of etching solution with low hydrofluoric acid, it was effective to use $NH_4F$ or $NH_4HF_2$ as a main ingredient with the addition of sulfuric acid or nitric acid. Influence of the composition of mixed acid solution and the temperature on the etching rate was investigated. The addition of anionic surfactant provides the function to prevent the adhesion of sludge generated by the etching reaction. A new wet etching pilot device equipped with streaming generation parts was used to test etching of commercial non-alkali glass and soda lime glass. The non-alkali glass with the thickness of 640 ${\mu}m$ and soda lime glass with the thickness of $500{\mu}m$ were etched to $45{\mu}m$ and $100{\mu}m$, respectively, by using the pilot device. After the etching by pilot device, the roughness degree of the glass surface was maintained at $0.01{\sim}0.02{\mu}m$.

Comparison of Cell Lysis Techniques via Q-TOF LC/MS

  • Kaplan, Ozan;Oncul, Selin;Ercan, Ayse;Celebier, Mustafa
    • Mass Spectrometry Letters
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    • v.11 no.2
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    • pp.36-40
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    • 2020
  • Untargeted metabolomics is a useful tool for drug development focusing on novel chemotherapeutic and chemopreventative agents against cancer cells. In recent years, quadrupole time of flight liquid chromatography-mass spectrometry (Q-TOF LC/MS)-based untargeted metabolomic approaches have gained importance to evaluate the effect of these agents at the molecular level. The researchers working on cell culture studies still do not apply standardized methodologies on sample preparation for untargeted metabolomics approaches. In this study, the rough and wet lysis techniques performed on MCF-7 breast cancer cells were compared with each other via the Q-TOF LC/MS-based metabolomic approach. The C18 and hydrophilic interaction liquid chromatography (HILIC) columns were used for the separation of the metabolites in MCF-7 cell lysates. 505 peaks were detected through the HILIC column and 551 peaks were found through the C18 column for the wet lysis technique. This situation supported by the base peak chromatograms showed that the wet lysis technique allowed us to extract higher number of non-polar metabolites. Almost equal number of metabolites was found for the C18 and HILIC columns (697 peaks for the HILIC column and 695 peaks for the C18 column) when the rough lysis technique was used. However, the intensities of polar metabolites were higher for the rough lysis technique on base peak chromatograms for both the HILIC and C18 columns. Although cell lysis technique, which is the first step in the sample preparation for cell culture studies, does not cause dramatic differences in the number of the detected metabolite peaks, it affects the polar and non-polar metabolite ratio significantly. Therefore, it must be considered carefully especially for in vitro drug development studies.

Magnetic Properties of Modified DNAs

  • Do, Eui-Doo;Lee, Chang-Hoon;Kwon, Young-Wan;Choi, Dong-Hoon;Jin, Jung-Il;Oh, Dong-Keun;Nishide, Hiroyuki;Kurata, Takashi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.3-4
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    • 2006
  • Natural DNAs in dry state, i.e., A-DNAs, when intercalated with low levels of stable organic free radicals or complexed with low levels of Au(III), are attracted at room temperature to commercial magnets, whereas those containing high levels of intercalators or Au(III) are not. This surprising observation is explained by the EPR spectra and SQUID measurement of magnetization of the modified DNAs. It is conjectured that A-DNAs are morphologically heterogeneous containing ordered and disordered regions. The ordered regions appear to strongly mediate magnetic interactions between spins through their ${\pi}_z$-stacked structures. When the modified DNAs are wet or hydrated, they behave diamagnetically.

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Effects of Poria cocos Powder on Wet Noodle Qualities (복령분말이 생국수의 품질에 미치는 영향)

  • Kim, Young-Soo
    • Applied Biological Chemistry
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    • v.41 no.7
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    • pp.539-544
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    • 1998
  • A study was conducted to investigate the effects of Poria cocos powder on dough rheology and wet noodle quality. Poria cocos powder had considerably lower content of crude protein, crude fat and crude ash than those of wheat flour. Poria cocos powder had also much bigger particle size $(74.62\;{\mu}m)$ and larger surface area $(3884.13\;cm^2/g)$ than those of wheat flour. The peak, final viscosities and setback in amylograph increased with the increase of Poria cocos powder concentration. The water absorption and dough stability in farinograph increased with the increase of Poria cocos powder concentration. With the increase of Poria cocos powder, the L values decreased in wheat flour-Poria cocos powder blend and dough, but increased in wet noodles. The cooked weight and volume of cooked noodles decreased, but the turbidity of soup increased with the increase of Poria cocos powder concentration. The hardness, cohesiveness, chewiness and springiness of cooked noodles had the biggest values at 3% addition of Poria cocos powder, but the values decreased above that concentration. The sensory evaluation of cooked noodles showed that the wet noodles with high quality could be produced by $5{\sim}7%$ addition of Poria cocos powder.

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Improvement of Photo Current Density in Dye-sensitized Solar Cell by Glass Texturing

  • Nam, Sang-Hun;Suk, Won;Yang, Hee-Su;Hwang, Ki-Hwan;Jin, Hyun;Seop, Kyu;Hong, Byungyou;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.423-423
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    • 2012
  • Recently, many researchers made progress in various studies improving the efficiency of dye-sensitized solar cell. In this paper, we used glass textured by wet-chemical etching process for improvement of photocurrent density in dye-sensitized solar cells. This is owing to increase coefficient of light utilization. Consequently, DSSC using the textured glass exhibit a Jsc of 9.49 mA/$cm^2$, a Voc of 0.73 V and a fill factor (FF) of 0.67 with an overall conversion efficiency of 4.64. This result showed increasing of 20% current density and 16% conversion efficiency using the textured glass. These results suggested that glass texturing was very effective in controlling the light-scattering properties into the photovoltaic cell.

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Newer Insights on Ferrate(VI) Reactions with Various Water Pollutants: A Review

  • Lalthazuala, Levia;Lalhmunsiama, Lalhmunsiama;Vanlalhmingmawia, Chhakchhuak;Tiwari, Diwakar;Choi, Suk Soon;Lee, Seung-Mok
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.258-271
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    • 2022
  • Ferrate (VI) [Fe(VI)] has multi-functional features, which include potential oxidant, coagulant, and disinfectant. Because of these distinctive properties, numerous studies on the synthesis of ferrate (VI) and its possible applications in a wide research areas have been investigated. This review highlights the recent development made on different synthesis methods for ferrate including wet chemical, electrochemical, and thermal methods. The recent advancements achieved in ferrate (VI) oxidation and the synergistic effect of the oxidative properties of ferrate (VI) in the presence of various compounds or materials are also included. Moreover, this review discusses the applications of ferrate (VI) for degrading various types of water pollutants and its reaction mechanism. The optimized experimental conditions and interaction mechanisms of ferrate (VI) with micro-pollutants, dyes, and other organic compounds are also elaborated upon to provide greater insight for future studies. Lastly, the limitations and prospects of the ferrate use in the treatment of polluted water are described.

Effects of Spinning Conditions on Properties of Polyester Yarn Prepared using an Ultra-high-speed Melt Spinning Technique Equipped with a Steam Chamber

  • Ho, Yo-Seung;Kim, Hak-Yong;Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3252-3258
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    • 2010
  • In this study, the effects of the various parameters of spinning and drawing processes on the properties of polyester full drawn yarn (FDY) prepared by steam processing during high-speed spinning were investigated using several techniques. The wet shrinkage ratio of the FDY was able to be manipulated by controlling the temperature and draw ratio. The FDY made using the steam high speed spinning technique exhibited identical properties (such as tenacity, elongation, and wet shrinkage ratio) to that of regular FDY, made using the spin-draw process. FDY prepared using the steam process during high-speed spinning showed excellent dyeability. The dye pick-up of the polyester yarn spun at high-speed spinning was found to be improved when dyed under an atmospheric pressure of $100^{\circ}C$. This result was the same as regular FDY dyed under a high pressure of $130^{\circ}C$.

Visible-light Photocatalytic Activity of BiOCl/Bi3O4Cl Nanocomposites

  • Gao, Bifen;Chakraborty, Ashok Kumar;Yang, Ji-Min;Lee, Wan-In
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1941-1944
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    • 2010
  • The heterojunction structures of BiOCl/$Bi_3O_4Cl$, exhibiting considerable visible-light photocatalytic efficiency, were prepared by a simple wet-chemical process at ambient condition. The prepared nanocomposites were characterized by XRD, TEM, and UV-visible diffuse reflectance spectra. Under visible light (${\lambda}\geq$420 nm) irradiation, BiOCl/$Bi_3O_4Cl$ exhibited an enhanced photocatalytic activity in decomposing 2-propanol (IP) in gas phase and salicylic acid (SA) in aqueous solution, whereas the bare BiOCl and $Bi_3O_4Cl$ showed negligible activities. It is deduced that the remarkable visible-light photocatalytic activity of the BiOCl/$Bi_3O_4Cl$ originates from the hole $(h^+)$ transfer between VB of the $Bi_3O_4Cl$ and BiOCl semiconductors.