• Polymer(Korea)
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• v.36 no.3
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• pp.372-379
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• 2012

In this study, we treated silica nanoparticles with bis[3-(trimethoxysilyl)propyl]amine (BTMA) silane coupling agent to modify their surfaces. We investigated the effects of BTMA hydrolysis time, BTMA concentration and BTMA treatment time on the degree of silanization reaction of silica nanoparticles. We used Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA) and solid state cross-polarization magic angle spinning (CP/MAS) nuclear magnetic resonance spectroscopy (NMR) to obtain quantitative data. We found the decrease of isolated Si-OH peak intensity at 3747 $cm^{-1}$ and the increase of $-CH_2 $stretching and bending peaks with increasing hydrolysis time, concentration and treatment time of BTMA. EA analysis results also supported this trend. We found a strong effect of BTMA concentration on the degree of silanization of the silica particles, but weak effects of the hydrolysis time and the treatment time.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2544-2548
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• 2011

Two pyridinecarboxamide cobalt dicyanide building blocks and Mn(III) compounds have been employed to assemble cyanide-bridged heterometallic complexes, resulting in three trinuclear cyanide-bridged $Co^{III}-Mn^{II}$ complexes: $\{[Mn(MeOH)_4][Co(bpb)(CN)_2]_2\}{\cdot}2MeOH{\cdot}2H_2O$ (1), $\{[Mn(MeOH)_4][Co(bpmb)(CN)_2]_2\}{\cdot}2MeOH{\cdot}2H_2O$ (2) and $\{[Mn(DMF)_2(en)_2][Co(bpb)(CN)_2]_2\}{\cdot}2DMF{\cdot}H_2O$ (3) ($bpb^{2-}$ = 1,2-bis(pyridine-2-carboxamido)benzenate, $bpmb^{2-}$ = 1,2-bis(pyridine-2-carboxamido)-4-methyl-benzenate, en = ethylenediamine). Single crystal X-ray diffraction analysis shows their similar sandwich-like structures, in which the two cyanide-containing building blocks act as monodentate ligands through one of their two cyanide groups to coordinate the Mn(II) center. For complex 3, it was further linked into one-dimensional structure by ethylenediamine acting as bridges. Investigation of the magnetic properties of complex 3 reveals weak antiferromagnetic coupling between the neighboring Mn(II) centers through the bridging ethylenediamine molecule. A best-fit to the magnetic susceptibilities of complex 3 gave the magnetic coupling constant J = -0.073(2) $cm^{-1}$.

• Progress in Superconductivity
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• v.8 no.2
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• pp.143-151
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• 2007

Accurate measurements of the microwave surface resistance (Rs) of high temperature superconductor (HTS) films are important with regard to applications of HTS materials for wireless communications. As the surface resistance values of HTS films are usually extracted from the measured unloaded quality factor ($Q_0$) of resonators made of HTS films, it is essential to measure the resonator $Q_0$ with accuracy. The $TE_{011}\;mode\;Q_0$ of sapphire resonators with the endplates made of $YBa_2Cu_3O_{7-{\delta}}$(YBCO) film on $LaAlO_3$ is measured by using the S-parameter circle-fit method at a frequency of about 19.6 GHz and temperatures of 30 K to 90 K, which is compared with the measured values by using the Lorentzian-fit method. Good agreements are found between the two sets of $Q_0$ values measured by using the two different methods whether the resonator is used in a weak-coupling scheme or a strong-coupling scheme, showing reliability of both methods fur measuring the resonator $Q_0$ accurately. The $Q_0$ of sapphire resonators with a gap between the top plate and the rest of the resonator is also discussed.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.10
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• pp.31-39
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• 2004

This paper illustrates the noise characteristics under chip's core operations according to types of packages and modules for DDR DRAM For analyzing this, the impedance profiles and power noises are analyzed with DRAM chips having commercial TSOP package and commercial FBGA package on TSOP-based DIMM and FBGA-based DIMH In controversy with common concepts, we find that the noise-isolation characteristics of FBGA package are more weak and sensitive on transferred noises than those of the TSOP package. In addition, the simulated results show that the decoupling capacitor locations of modules are more important to control the self and transfer noise characteristics than the lead inductance of the packages. Therefore, satisfying the target spec of the noise suppression and isolation can be achieved through the design of power distribution systems only with considering not only the package types but also the whole module system.

• Journal of KSNVE
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• v.8 no.6
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• pp.1166-1171
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• 1998

The influences of the coupler consisting of stiffness and mass between neighboring two spans on mode localization are studied theoretically, and the results are confirmed by numerical examples. The mass of the coupler makes a structure sensitive to mode localization especially in higher modes while the stiffness does in all modes. A new type of delocalization phenomenon is observed for the first time in some modes for which mode localization does not occur or is very weak although structural disturbances are severe. A spring-mass system consisting of two substructures and a coupler connecting them is considered in the part of analytical study. As example structures for numerical analysis. simply supported continuous two-span beams with a coupler having a rotational stiffness and a mass moment of inertia on the mid support are considered.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.155-156
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• 2023

In the case of steel door frames commonly found in general buildings, there are various assembly methods such as rivets, bolts, and welding, but the welding method is generally used. However, this welding joint method has many problems, such as distortion due to heat and damage due to external shock. In particular, when used as a fire door, problems may occur in the event of a fire due to distortion caused by heat from welding and the weak welded joint area. In the case of rivet or welded joints, when moved after assembly, joint loosening due to external shock may occur. Problems may arise where the bonding strength becomes weak. In addition, with the recent increase in high-rise buildings and larger buildings, when assembly is completed and brought to the site, a place is needed to store it, and in addition, there is a problem in that it has to be transported several times in small quantities to the installation site, which is another problem of time and cost loss. This is coming to the fore. In order to fundamentally solve this problem, we have researched and developed a non-welding door frame that can be assembled on site. We have researched and developed three assembly methods: screw-type, insert-type, and protrusion-type. Non-welded door frames are small in size and easy to package, making them advantageous for domestic and overseas exports.

• Journal of the Korean Magnetics Society
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• v.18 no.5
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• pp.180-184
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• 2008

The relation of ferromagnet anisotropic magnetization and the antiferromagnet atomic spin configuration has been investigated for variously angles of unidirectional deposition magnetic field of FeMn layer in Corning glas/Ta(5 nm)/NiFe(7 nm)/FeMn(25 nm)/ Ta(5 nm) multilayer prepared by ion beam deposition. Three unidirectional deposition angles of FeMn layer are $0^{\circ},\;45^{\circ}$, and $90^{\circ}$, respectively. The exchange bias field ($H_{ex}$) obtained from the measuring easy axis MR loop was decreased to 40 Oe in deposition angle of $45^{\circ}$, and to 0 Oe in the angle of $90^{\circ}$. One other side hand, $H_{ex}$ obtained from the measuring hard axis MR loop was increased to 35 Oe in deposition angle of $45^{\circ}$, and to 79 Oe in the angle of $90^{\circ}$. Although the difference of uniderectional axis between ferromagnet NiFe and antiferromagnet FeMn was 90o, the strong antiferromagnetic dipole moment of FeMn caused to rotate the weak ferromagnetic dipole moment of NiFe in the interface. This result implies that one of origins for exchange coupling mechanism depends on the effect of magnetic field angle during deposition of antiferromgnet FeMn layer.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.410-415
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• 2001

An analytical and numerical examination of second-order fractional-step methods and boundary condition for the incompressible Navier-Stokes equations is presented. In this study, the compatibility condition for pressure Poisson equation and its boundary conditions, stability, and numerical accuracy of canonical fractional-step methods has been investigated. It has been found that satisfaction of compatibility condition depends on tentative velocity and pressure boundary condition, and that the compatible boundary conditions for type D method and approximately compatible boundary conditions for type P method are proper for divergence-free velocity for type D and approximately divergence-free for type P method. Instability of canonical fractional-step methods is induced by approximation of implicit viscous term with explicit terms, and the stability criteria have been founded with simple model problems and numerical experiments of cavity flow and Taylor vortex flow. The numerical accuracy of canonical fractional-step methods with its consistent boundary conditions shows second-order accuracy except $D_{MM}$ condition, which make approximately first-order accuracy due to weak coupling of boundary conditions.

• Korean Journal of Materials Research
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• v.18 no.11
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• pp.604-609
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• 2008

The sintering behavior of zircon with silica was investigated. Zircon with 5 vol% of sedimentation $SiO_2$ resulted in the apparent density of $4.45\;g/cm^3$, the diametral tensile strength of $12.125\;kgf/cm^2$, and the micro Vickers hardness of 1283 HV. The dissociation temperature and mechanical characteristics of the $ZrSiO_4$ were changed with different kinds of $SiO_2$. $SiO_2$ addition prevented dissociation of $ZrSiO_4$. Zircon with 5 vol% of sedimentation $SiO_2$ and with 5 vol% of fused $SiO_2$ resulted in increased diametral tensile strength and increased micro Vickers hardness by suppression of $ZrSiO_4$ dissociation and low temperature liquid $SiO_2$ formation. Zircon with fumed $SiO_2$ and quartz $SiO_2$ resulted in decreased diametral tensile strength and decreased micro Vickers hardness because of cristobalite and quartz phase formation and high temperature liquid $SiO_2$ formation. Zircon with 10 vol% of $SiO_2$ resulted in decreased diametral tensile strength and decreased micro Vickers hardness because of weak particle coupling due to excess formation of liquid $SiO_2$.

• Steel and Composite Structures
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• v.28 no.4
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• pp.471-482
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• 2018

The composite reinforced concrete and steel (RCS) structural systems have larger structural lateral stiffness, higher inherent structural damping, and faster construction speed than either traditional reinforcement concrete or steel structures. In this paper, four RCS subassemblies with or without the RC slab designed following a strong column-weak beam philosophy were constructed and tested under reversed-cyclic loading. Parameters including the width of slab and composite effect of the RC slab and beam were explored. The test results showed that all specimens performed in a ductile manner with plastic hinges formed in the beam ends near the column faces. The seismic responses of composite connections are influenced significantly by different width of slabs. Compared with that of the steel beam without the RC slab, it was found that the load carrying capacity of composite connections with the RC slab increased by 30% on average, and strength degradation, energy dissipation also had better performance, while the ductility of that were almost the same. Furthermore, the contribution of connection deformation to the overall specimen displacement was analyzed and compared. It decreased approximately 10% due to the coupling effect in the columns and beams with the RC slab. Based on the test result, some suggestions are presented for the design of composite RCS joints.