• Corrosion Science and Technology
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• 제7권4호
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• pp.224-232
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• 2008

During the hot rolling process, steels develop an oxide scale on their surface. This scale can affect the mechanical properties of the rolled steel and its surface aspect. The main problem comes from the mechanical integrity of the oxide scales which could delaminate or crack, leading eventually to later oxide incrustation within the steel. The objective of the present work is to qualify the mechanical integrity of the iron oxide scales during the hot rolling process. The laboratory experiments use a four point bending test to simulate the mechanical solicitation which takes place during the rolling sequence of the steel slabs. The oxide scales grow on a mild steel at $900^{\circ}C$ under wet or dry atmosphere and the oxidized steel is then mecahnically tested at $900^{\circ}C$ or $700^{\circ}C$. The high temperature four point bending tests are completed with microstructural observations and with the record of acoustic emission to follow in-situ the mechanical damages of the oxide scales. The results show the role of water vapor which promotes the scale adherence, and the role of the temperature as the oxide are more damaged at $700^{\circ}C$ than at $900^{\circ}C$.

• Corrosion Science and Technology
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• 제11권2호
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• pp.65-69
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• 2012

One dimensional(1D) $Na_2Ti_6O_{13}$ nanorods with 70 nm in diameter was synthesized by a molten salt method. Using the synthesized nanorods, about 750 nm thick $Na_2Ti_6O_{13}$ film was coated on Fluorine-doped tin oxide(FTO) glasss substrate by the Layer-by-layer self-assembly(LBL-SA) method in which a repetitive self-assembling of ions containing an opposite electric charge in an aqueous solution was utilized. Using the Kubelka-Munk function, the band gap energy of the 1D-$Na_2Ti_6O_{13}$ nanorods was nalyzed to be 3.5 eV. On the other hand, the band gap energy of the $Na_2Ti_6O_{13}$ film coated on FTO was found to be a reduced value of 2.9 eV, resulting from the nano-scale and high porosity of the film processed by LBL-SA method, which was favorable for the photo absorption capability. A significant improvement of photocurrent and onset voltage was observed with the $Na_2Ti_6O_{13}$ film incorporated into the conventional $Fe_2O_3$ photoelectrode: the photocurrent increased from 0.25 to 0.82 mA/$cm^2$, the onset voltage decreased from 0.95 to 0.78 V.

• 한국가스학회지
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• 제4권3호
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• pp.26-32
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• 2000

최근 국내에서는 효율적인 공간활용을 위해 해저터널을 이용하여 전력을 공급하는 것이 시도되고 있으며, 해저터널내에 에너지 공급 기간시설물(전력케이블, 가스배관, 송유관, 지역난방배관 등)들이 같이 포설될 수 있으면 공사비 절감의 효과는 엄청날 것이므로 관심도가 높아지고 있다. 따라서 본 논문에서는 세계최초로 몰타르(Mortar)로 충진되어 있는 해저터널에서 전력케이블과 가스배관이 병행할 경우, 유도에 의한 교류부식에 대하여 검토하였으며, 아직 국내에는 유도전압 제한치가 마련되어 있지 않으므로 인$\cdot$축의 안전적인 측면과 시스템의 보안적인 측면을 세심하게 검토하여 이에 대한 제한치를 정립하였고, 유도전압이 최소가 되도록 전력케이블의 상배치를 최적으로 설계하였다. 이 결과들은 실 사례에 적용되었다.

• Nuclear Engineering and Technology
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• 제50권2호
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• pp.223-228
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• 2018

AREVA NP (Courbevoie, Paris, France) is actively developing several enhanced accident-tolerant fuels cladding concepts ranging from near-term evolutionary (Cr-coated zirconium alloy cladding) to long-term revolutionary (SiC/SiC composite cladding) solutions, relying on its worldwide teams and partnerships, with programs and irradiations planned both in Europe and the United States. The most advanced and mature solution is a dense, adherent chromium coating on zirconium alloy cladding, which was initially developed along with the CEA and EDF in the French joint nuclear R&D program. The evaluation of the out-of-pile behavior of the Cr-coated cladding showed excellent results, suggesting enhanced reliability, enhanced operational flexibility, and improved economics in normal operating conditions. For example, because chromium is harder than zirconium, the Cr coating provides the cladding with a significantly improved wear resistance. Furthermore, Cr-coated samples exhibit extremely low corrosion kinetics in autoclave and prevents accelerated corrosion in harsh environments such as in water with 70 ppm Li leading to improved operational flexibility. Finally, AREVA NP has fabricated a physical vapor deposition prototype machine to coat full-length cladding tubes. This machine will be used for the manufacturing of full-length lead test rods in commercial reactors by 2019.

• Advances in concrete construction
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• 제16권1호
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• pp.69-78
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• 2023

This investigation delves into the adverse repercussions stemming from the impact of arsenic on steel pipes concealed within soil designated for rice cultivation. Simultaneously, the study aims to ascertain effective techniques for detecting arsenic in the soil and to provide strategies for mitigating the corrosion of steel pipes. The realm of nanotechnology presents promising avenues for addressing the intricate intersection of renewable energy, oil, and environmental pollution from a novel perspective. Nanostructured materials, characterized by distinct chemical and physical attributes, unveil novel pathways for pioneering materials that exert a substantial impact across diverse realms of food production, storage, packaging, and quality control. Within the scope of the food industry, the scope of nanotechnology encompasses processes, storage methodologies, packaging paradigms, and safeguards to ensure the safety of consumables. Of particular note, silver nanoparticles, in addition to their commendable antibacterial efficacy, boast anti-fungal and anti-inflammatory prowess, environmental compatibility, minimal irritability and allergenicity, resilience to microbial antagonism, thermal stability, and robustness. Confronting the pressing issue of arsenic contamination within both environmental settings and the food supply is of paramount importance to preserve public health and ecological equilibrium. In response, this study introduces detection kits predicated upon silver nanoparticles, providing an expeditious and economically feasible avenue for identifying arsenic concentrations ranging from 0.5 to 3 ppm within rice. Subsequent quantification employs Hydride Atomic Absorption Spectroscopy (HG-AAS), which features a detection threshold of 0.05 ㎍/l. A salient advantage inherent in the HG-AAS methodology lies in its capacity to segregate analytes from the sample matrix, thereby significantly reducing instances of spectral interference. Importantly, the presence of arsenic in the soil beneath rice cultivation establishes a causative link to steel pipe corrosion, with potential consequences extending to food contamination-an intricate facet embedded within the broader tapestry of renewable energy, oil, and environmental pollution.

• Interaction and multiscale mechanics
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• 제5권1호
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• pp.41-56
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• 2012

This study is focused on evaluation of the tensile properties of concrete exposed to acid rain environment. Acid rain environment was simulated by the mixture of sulfate and nitric acid in the laboratory. The dumbell-shaped concrete specimens were submerged in pure water and acid solution for accelerated conditioning. Weighing, tensile test, CT, SEM/EDS test and microanalysis were performed on the specimens. Tensile characteristics of the damaged concrete are obtained quantitatively. Evolution characteristics of the voids, micro cracks, chemical compounds, elemental distribution and contents in the concrete are examined. The deterioration mechanisms of concrete exposed to acid rain are well elucidated.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.39-42
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• 2002

Cloride attack of concrete is one of the important causes of corrosion of reinforcing steel in concrete with carbonation and frost damage. In this paper, the effect of fly-ash on the cloride attack were investigated by varying water binder ratio and fly-ash contents according to the chloride ion penetrationa test. (ASTM C 1202-94) The principal conclusions from this research were as follows: 1) The compressive strength of concrete at large ages, depends more on $C_2$S contents of base cement than fly-ash contents. 2) On the other hand, the chloride ion penetration of concrete at large ages, principally depends on fly-ash contents and the influence of type of base cement is insignificant.

• 한국해양공학회지
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• 제22권5호
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• pp.94-99
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• 2008

Three types of salt resistant concrete beams reinforced with glass fiber reinforced polymer-ribbed bars (GFRP-ribbed bars) were selected, and their applicable properties were investigated with the goal of improving the problem of capacity deterioration in marine structures due to sea water corrosion. In this study, the structural behaviors were similar to RC beams in relation to the development of the strength and stiffness up to the generation of the initial crack. After the growth of this initial crack, the structural properties decreased owing to a sudden loss of bond strength. Also these beams showed the trends of brittle failure. As a result, it was confirmed that a GFS beam replaced with Fly Ash (20%) and Silica Fume (5%) has the best application as a marine structural element.

• Journal of Advanced Marine Engineering and Technology
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• 제21권5호
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• pp.584-590
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• 1997

Harbour marine steel structures, which are served in severe marine environment, should be protected in appropriate method to reduce corrosion problems. Cathodic protection, one of the protection methods in terms of practical and economical point of view is being widely used to marine steel structures mentioned above. Recently it has been reported that the life of Al alloy anode with sacrificial anode for protection of harbour marine steel structures was shortened significantly than the original design life. In this study, the optimum cathodic protection design of harbour marine steel structures was investigated with parameter of sea water pollution degree.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 춘계학술대회논문집
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• pp.127-130
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• 2003

Electrolytic polishing is the anodic dissolution process in the transpassive state. It removes non-metallic inclusions and improves mechanical and corrosion resistance of stainless steel. Electrolytic polishing is normally used to remove a very thin layer of material from the surface of a metal object. An electrolyte of phosphoric, sulfuric and distilled water has been used in this study. In the low current density region, there can be found plateau region and material removal process and leveling process occur successively. In this study, an electrochemical polishing process using pulse current is adopted as a new electrochemical polishing process. In electrochemical machining processes, it has been found that pulse electrochemical processes provide an attractive alternative to the electrochemical processes using continuous current. Hence, this study will discuss the electrochemical polishing processes in low current density region and pulse electrochemical polishing.