• Journal of the Korean Wood Science and Technology
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• 제41권2호
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• pp.87-99
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• 2013

Waste paper stands for the major biodegradable organic fraction of most of municipal solid waste. The potential of waste paper for glucose production was investigated in this current work. The pretreatment was accomplished by first subjecting waste paper to disintegration time (30 s), followed by ink removal of disintegrated waste paper using an deinking agent. Concentrated acid hydrolysis of waste paper with sulfuric acid was optimized to maximize glucose conversion. The concentrated acid hydrolysis conditions for waste paper (disintegrated time: 30 s, deinking agent loading : 15 ml) were optimized by using central composite design and response surface methodology. The optimization process employed a central composite design, where the investigated variables were acid concentration (60~80%), loading sulfuric acid (1~5 ml) and reaction time (1~5 h). All the tested variables were identified to have significant effects (p < 0.05) on glucose conversion. The optimum concentrated acid hydrolysis conditions were acid concentration of 70.8%, loading sulfuric acid of 3.2 ml and a reaction time of 3.6 h. This research of concentrated acid hydrolysis was a promising method to improve glucose conversion for waste paper.

• 한국잠사곤충학회지
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• 제33권2호
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• pp.100-102
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• 1991

제사공정의 부잠사 처리폐수에 대하여 그 성상과 추출 유지성분을 분석한 결과 1. 부잠폐수의 COD 605mgO/$\ell$ 총 용존 고형물량 2,335mg/$\ell$ 총 부유 고형물량 2,234mg/$\ell$이었다. 2. 부잠폐수의 지질에는 triglyceride가 76.8%로 가장 많이 함유되었으며 유리 지방산 12.5%와 diglyceride 5.7% free sterol 5.0% 순이었다. 3. 부잠폐수지질의 지방산 조성은 oleic acid, linolenic acid와 linoleic acid의 함유율이 64.93%로 가장 많이 함유되어 있고 palmitic acid 29.39% stearic acid 4.93%의 순이었다.

• KSBB Journal
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• 제13권5호
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• pp.615-620
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• 1998

The readily fermentable carbon sources in swine were acetic acid, propionic acid and butyric acid at the average concentrations of 7.2 g/L, 2.2 g/L and 2.7 g/L, respectively. The swine waste also contained excess nitrogen and other mineral sources. In shake flask experiments, the optimal range of cell growth for Azotobacter vinelandii UWD were 1.0∼3.5 g/L of acetic acid, 0.7∼2.0 g/L of propionic acid and 0.5∼2.0 g/L of butyric acid. A mixture of these three acids simulating two times diluted swine waste supported the best cell growth but the amount of carbon sources was limited. In shake flask and fermentor experiments, an addition of 30 g/L of glucose increased the final cell dry weight 8 times while the final poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) concentration increased 86 times compared with using acid mixture only. A. vinelandii UWD preferred organic acids in the sequence of acetic acid, propionic acid, butyric acid, and valeric acid.

• Nuclear Engineering and Technology
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• 제32권1호
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• pp.10-16
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• 2000

Preliminary experiment was peformed to investigate the leaching characteristics of paraffin waste forms that had been recently generated in large quantities at domestic nuclear power plants. At first, waste simulants whose compositions were different in mixing ratio of paraffin to boric acid were prepared. Their compressive strengths were measured and ninety-day leaching test of specimen including cobalt was carried out according to ANSI/ANS-16.1 test procedure. Water immersion test was also conducted keeping pace with leaching test and the weight change and the compressive strength of specimen were observed after ninety days. The compressive strength of waste form exhibited 666 psi (4.53 MPa) in the case where mixing ratio of boric acid to paraffin was 78/22, which was adopted in concentrate waste drying system of domestic nuclear power plants. The leaching test resulted in about 50% of the cumulative fraction leached for boric acid and cobalt, respectively. The specific gravity of waste form was 0.87 ［g/g］whose value was less than that of water because the weight loss of about 39% occurred after the water immersion test of ninety days. It was also observed that the waste form which had undergone ninety-day water immersion test exhibited the compressive strength of 203 psi (1.38 MPa).

• 전기학회논문지P
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• 제56권2호
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• pp.65-73
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• 2007

In this study, the pulse charger and voltage regulator are proposed that can reuse the waste lead acid battery. The first we develop the voltage regulator that can reuse the waste lead battery. And the pulse current is applied to the terminal of the waste lead acid battery. The voltage regulator is available principle of the pulse current which can reduce the sulfate to incipient material such as Pb and PbO2. Therefore the internal resistance of the lead acid battery is decreased, the performance of the lead acid battery is improved and the durability is prolonged. The second we develop the pulse charger using the voltage regulator. The pulse charger uses the switch mode of the forward convert method. The pulse charger maintain the constant voltage in state removing the lead acid battery and when it connected the pulse charger, it is converted the charge mode of the constant current immediately. It continues the rapid charge until the full state of the lead acid battery. After that the pulse charger is converted to the charge mode of constant voltage automatically, and then it continues the normal charge. The experiment results show that the effectiveness of the voltage regulator and pulse charger such as the good performance and the prolonged durability in lead acid battery of the small and large capacity.

• 자원리싸이클링
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• 제29권3호
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• pp.61-74
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• 2020

본 연구에서는 폐형광등 처리 공정의 경제성 확보를 위하여 수행되었으며, 폐형광등 유리의 글래스비드용 원료로서의 사용 가능성, 폐형광체 분말로부터 희토류의 침출, 희토류 침출액으로부터 희토류의 용매추출 가능성 등을 검토하였다. 폐형광체는 산화이트륨 28.9%, 산화세륨이 3.46%, 산화유로퓸 1.95%, 산화터븀 1.76%, 산화란탄 1.43% 순으로 함유되어 있어 회수 및 정제 시 경제성이 충분할 것으로 판단되었다. 폐형광등 유리를 사용하여 글래스비드를 시험 생산 한 결과 그 생산수율과 품질이 우수하여 폐형광등 유리를 글래스비드용 원료로 사용할 수 있을 것으로 판단되었다. 소다배소한 폐형광체를 수침출하면 알루미늄과 규소성분 및 잔류 탄산나트륨 등이 용해하며, 이 수용액에 탄산가스를 불어 넣어 pH를 7 정도로 떨어뜨리면 NaAl₂(CO₃)(OH)₂와 SiO₂ 등이 침전하였다. 자이렌을 희석제로 사용하는 cyanex272-hydrochloric acid, cyanex272-sulfuric acid, D2EHPA-hydrochloric acid, D2EHPA-sulfuric acid, lonquest290-hydrochloric acid, lonquest290-sulfuric acid, p507-hydrochloric acid 조합의 용매추출에서 Y, Eu, Ce, La, Tb의 추출률이 100%에 가깝다. 그러나 동일 조건에서의 원소별 추출률의 차이, 즉 선택성은 16% 이하이다.

• Elastomers and Composites
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• 제38권1호
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• pp.19-26
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• 2003

혼합폐플라스틱과 섬유소로서 폐신문지를 혼합하여 복합체를 구성하고 그 기계적인 물성을 조사하였다. 수지-수지 및 수지-섬유소 사이의 계면접착력을 증대시키고자 섬유소와 친화성을 가진 아비틱산을 소량 첨가하였다. 섬유소의 투입량이 많아질수록 인장강도는 플라스틱자체보다 저하되었으며 아비틱산은 강도에 좋은 영향을 주지 못하였다. 파단신장률 및 충격강도는 섬유소만의 투입량에 따라서는 감소하였으나, 섬유소가 적은 양이고 아비틱산이 적게 포함되어 있을 경우에 놀라운 상승을 나타내었다. 물성의 향상은 아비틱산의 화학적인 양면성에 기인한다고 여겨진다.

• 한국환경보건학회지
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• 제31권4호
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• pp.294-300
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• 2005

Food waste can be a valuable carbon source in biological nutrient removal (BNR) systems because of high C/N and C/P ratios. However, food waste should be pretreated to promote its hydrolysis rate because hydrolysis reaction would be a rate-limiting step. This study investigates the influence of the enzymatic pretreatment on acid fermentation of food waste. Solubilization of particulate matter in food waste by using commercial enzymes was examined. The acidification efficiency and the volatile fatty acids (VFAs) production potential of enzymatically pretreated food waste were also examined. The highest volatile suspended solids (VSS) reduction was obtained with an enzyme mixture ratio of 1:2:1 of carbohydrase:protease:lipase. An optimum enzyme dosage for solubilization of food waste was $0.1\%$(V/V) with the enzyme mixture ratio of 1:2:1. In the acid fermentation of enzymatically pretreated food waste, $0.1\%$(V/V) enzyme mixture dosage for pretreatment result in the maximum VFAs production and the best VFAs fraction in soluble COD(SCOD). The VFAs production at this addition level was 3.3 times higher than that of no-enzyme added fermenter. The dominant VFAs present was n-butyrate followed by acetate.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.432-436
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• 2001

In this study, calcium sulfate(gypsum) powder was obtained using waste sulfuric acid and stainless refinery sludge by- produced from chemical reagent and the iron industry, by the neutralization of waste sulfuric acid. As variables for the experiment the mole ratio of the H$_2$SO$_4$ : Ca(OH)$_2$, the pH, the reaction temperature and time, the amount of catalyst were used. The crystal shape and microstructure of obtained powder were observed by XRD and SEM, and the thermal property was investigated by DTA. As the NaCl is added 0~20wt% as a catalyst to the H$_2$SO$_4$ : Ca(OH)$_2$, system it can be found that the crystal shape goes through the processes as follows : gypsum dihydratlongrightarrowgypsum hemihydrate＋gypsum dihydratelongrightarrowgypsum hemihydrate. And gypsum hemihydrate is $\beta$-type as the result of DTA. As waste sulfuric acid and stainless refinery sludge were used, the pH of reacted solution (which was 0.8) was rapidly raised up to 8~9 by the addition of stainless sludge and gypsum dihydrate was produced as a by-product. Therefore, it was found that stainless refinery sludge is sufficiently applicable for the neutralization of waste sulfuric acid.

• 한국지하수토양환경학회지:지하수토양환경
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• 제17권6호
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• pp.92-101
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• 2012

Korea shows the soil pH is 5.8 ~ 6.2 by many factors including the geological structure and climate condition. There is known as the cause for soil acidification by weathering of the mineral, excessive use of the chemical fertilizer, and extensively diffused acid rain. The purpose of research is environmentally-friendly material neutralization technology development utilizing the waste resources against by acid soil. The experiment analyze the physico-chemical property of the acid soil and waste resource materials (waste lime, oyster shell, bottom ash). The Batch-Test was performed under 3 stage. As a result, the acid soil showed up acid soil about 3.19. And waste lime, oyster, bottom ash showed the alkalinity with 9.62, 10.08, 9.17. In case of 1 batch-test experimental result, waste lime and oyster shell, the alkalinity was shown over 7.5 and the good efficiency was showed, on the other hands, the bottom ash showed the pH 4 the neutralization efficiency which is low. waste resource materials to be applied to 2 steps was chosen as the waste lime except the bottom ash and oyster. In 2 step batch-test experiment, it was exposed to be the most appropriate in case of doing the combination ratio of the waste lime and oyster shell with 9 : 1. It was exposed to be efficient most in the effeciency and aspect of economical efficiency combination ratio of the soil and materials was 9.6 : 0.6 with 3 step batch-test experimental result.