• Title/Summary/Keyword: volume distribution

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Monte Carlo Simulation of the Molecular Properties of Poly(vinyl chloride) and Poly(vinyl alcohol) Melts

  • Moon, Sung-Doo;Kang, Young-Soo;Lee, Dong-J.
    • Macromolecular Research
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    • v.15 no.6
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    • pp.491-497
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    • 2007
  • NPT Monte Carlo simulations were performed to calculate the molecular properties of syndiotactic poly(vinyl chloride) (PVC) and syndiotactic poly(vinyl alcohol) (PVA) melts using the configurational bias Monte Carlo move, concerted rotation, reptation, and volume fluctuation. The density, mean square backbone end-to-end distance, mean square radius of gyration, fractional free-volume distribution, distribution of torsional angles, small molecule solubility constant, and radial distribution function of PVC at 0.1 MPa and above the glass transition temperature were calculated/measured, and those of PVA were calculated. The calculated results were compared with the corresponding experimental data and discussed. The calculated densities of PVC and PVA were smaller than the experimental values, probably due to the very low molecular weight of the model polymer used in the simulation. The fractional free-volume distribution and radial distribution function for PVC and PVA were nearly independent of temperature.

Analysis of Electric Field Distribution and Characteristics of Volume Resistivity in HDPE/EVA Film for Recycling (재활용을 고려한 HDPE/EVA필름의 전계분포 및 체적저항특성 해석)

  • Lee, Hung-Kyu;Lim, Kee-Joe;Kim, Yong-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.9
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    • pp.801-807
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    • 2008
  • Recently, CV, CN-CV and CNCV-W cable are used for HVDC transmission and distribution cable. However, XLPE which is used as insulation layer of power cable has thermosetting properties. It is very difficult to recycling. In this paper, we prepared HDPE/EVA film, which the blending ratio are 80:20, 70:30, 60:40, 50;50 respectively for the purpose of recycling. Main factor such as electric field distribution and its resistivity in insulation system affected on insulation performance and reliability for HVDC applications. Therefore, electric field distribution formed by space charge and characteristics of volume resistivity was currently investigated. We suggest the possibility of utilization for HVDC insulation layer from the results.

Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
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    • v.4 no.2
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    • pp.157-166
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    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

Effects of the Method of Changing Compression Ratio on Engine Performance in an SI Engine (가솔린 엔진에서 압축비 변경 방법이 성능에 미치는 영향)

  • 이원근;엄인용
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.27-33
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    • 2001
  • In this study, it is observed that the distribution of combustion chamber volume affects the volumetric efficiency. The distribution ratio was adjusted by controlling combustion chamber volume of head and piston bowl one. Four cases were investigated, which are the combination of different distribution ratios and different compression ratios (9.8-10.0). A commercial SOHC 3-valve engine was modified by cutting the bottom face of the head and/or replacing the piston by the one that has different volume. The result shows that the less the head side volume, the more volumetric efficiency is achieved under the same compression ratio. It is also observed that increasing volumetric efficiency results in early knock occurrence due to increased "real" compression ratio. To consider reliability in estimating the volumetric efficiency, we examined the sensitivity of the AFR equation to possible errors in emission measurements. It is shown that the volumetric efficiency, which is calculated by measuring AFR and fuel consumption, can be controlled in 1% error. 1% error.

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A Study on the Improvement of Accuracy in Mapping the Distribution of the Emission Volume of Air Pollution Using GIS (GIS를 이용한 대기오염 배출량 분포도의 정확도 향상에 관한 연구)

  • 최진무
    • Spatial Information Research
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    • v.6 no.1
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    • pp.65-76
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    • 1998
  • Air contaminant density must be inferred exactly to manage air pollution. Each land use of air pollution source is duplicated in the existing air contaminant distribution because the resolution of the land use map is low. The purpose of this study is to understand how the land use map is used to determine effectively in the distribution calculation of the emission volume and the inference of air contaminant density, as it is made in a high resolution. The major findings are as follows : In this study, as to making a high resolution($28.5m{\times}28.5m$) map of land use with GIS, each air pollution source is not duplicated spatially and land use can be reflected effectively. In Seoul, each air contaminant density was inferred (using a TCM-2 model) with the existing distribution map of emission volume, whose resolution is $1km{\times}1km$, and the new distribution map of emission volume, whose resolution is $28.5km{\times}28.5km$. According to the result, the inference value of the new distribution map was more similar to the actual value of an automatic survey network.

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Free vibration responses of nonlinear FG-CNT distribution in a polymer matrix

  • Zerrouki, Rachid;Hamidi, Ahmed;Tlidji, Youcef;Karas, Abdelkader;Zidour, Mohamed;Tounsi, Abdelouahed
    • Smart Structures and Systems
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    • v.30 no.2
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    • pp.135-143
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    • 2022
  • The object of this paper is to investigate the free vibration behavior under the effect of carbon nanotube distribution in functionally graded carbon nanotube-reinforced composite (FG-CNTRC) by using higher-order shear deformation theories. In this work, we present a novel distribution method for carbon nanotubes in the polymer matrix by using a new exponential power law distribution of carbon nanotube volume fraction. It is assumed that the SWCNTs are aligned along the beam axial direction and the distribution of the SWCNTs may vary through the thickness of the beam with different patterns of reinforcement. The rule of mixtures is used in order to obtain material properties of the CNTRC beams. Hamilton's principle is used in deriving the equations of motion. The validity of the free Vibration results is examined by comparing them with those of the known data in the literature. The results that obtained indicate that the carbon nanotube volume fraction distribution play a very important role on the free vibrations characteristics of the CNTRC beam.

Walsh Analysis of the State of Mixture in Heterogeneous Media and its Application (비균질체의 혼합상태에 대한 Walsh해석과 응용)

  • 박진무
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.1
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    • pp.164-169
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    • 1986
  • Walsh analysis is applied to the numerical specification of the volume distribution which is the key parameter in the formulation of the constitutive equations of heterogeneous media, indicating the geometrical state of the mixture. An example of two-dimensional volume distribution, its approximation, and the Walsh correlation coefficients are presented and the change of the information distribution in the operations is investigated. The phenomena of information concentration upon the large-scale Walsh coefficients are applied to the volumetric response of porous slids, clarifying the validity of the spherical-model calculation.

Analysis on Electric Field Distribution of Dielectric Considering Surface or Volume Resistivity By Charge Simulation Method (전하 중첩법을 이용한 표면 저항 또는 체적 저항을 고려한 유전체의 전계 분포해석)

  • Min, S.W.;Kim, Y.J.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1987-1989
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    • 2000
  • In this paper, electric field distribution of dielectric sphere considering surface or volume resistivity is analysed by the use of rotational symmetric charge simulation method. We applied three methods such as ${\alpha},{\beta}$ modified $\beta$ method to check electric field calculation error. We find f method and modified $\beta$ method are suitable to simulate volume and surface resistivity respectively.

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Mechanical strength analysis for functionally graded composite plates (경사기능 복합재료 판의 기계적 강도해석)

  • Na, Kyung-Su;Kim, Ji-Hwan
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.66-69
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    • 2005
  • Mechanical strength of functionally graded composite plates that composed of ceramic, functionally graded material and metal layers is investigated using 3-D finite element method. In FGM layer, material properties are assumed to be varied continuously in the thickness direction according to a simple power law distribution in terms of the volume fraction of a ceramic and metal. The 3-D finite element model is adopted by using an IS-node solid element to analyze more accurately the variation of material properties in the thickness direction. Numerical results are compared with those of the previous works. In addition, the displacements, the tensile stresses and the compressive stresses are analyzed for the variation of FGM thickness ratio and volume fraction distribution.Mechanical strength of functionally graded composite plates that composed of ceramic, functionally graded material and metal layers is investigated using 3-D finite element method. In FGM layer, material properties are assumed to be varied continuously in the thickness direction according to a simple power law distribution in terms of the volume fraction of a ceramic and metal. The 3-D finite element model is adopted by using an IS-node solid element to analyze more accurately the variation of material properties in the thickness direction. Numerical results are compared with those of the previous works. In addition, the displacements, the tensile stresses and the compressive stresses are analyzed for the variation of FGM thickness ratio and volume fraction distribution.

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Mathematical Description of the Volume of Distribution in the Isolated Organ

  • Kim, Chong-Kook;Kim, Yang-Bae
    • Journal of Pharmaceutical Investigation
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    • v.10 no.1
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    • pp.1-3
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    • 1980
  • The model of an isolated organ system has been developed to simulate the kinetic behavior of drug levels in an acting organ or site. The model is developed from basic considerations of drug distribution with hemodynamical and pharmacokinetical meanings. Model: It is considered a situation in which non-metabolic drug substance is injected into the arterial inflow of an isolated organ at constant rate. The volume of distribution and the concentration of drug in the venous outflow can be mathematically expressed as a function of time.

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