• 대한치과기공학회지
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• 제31권1호
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• pp.7-15
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• 2009

Purpose: This study was to propose the clear understanding for stress distribution of supporting bone by use of staggered buccal offset tripodal placement of fixtures of posterior 3 crown implant partial dentures. We realized posterior 3 crown implant fixed partial dentures through finite element modeling and analysed stress effect of implant arrangement location to supporting bone under external load using finite element method. Method: To understand stress distribution of 3 crown implant fixed partial dentures which have 2 different arrangement by finite element analysis. In each model, for loading condition, we applied $45^{\circ}$ oblique load to occlusal surface of crown and applied 100 N for 3 crown individually(total 300 N) for imitating possible oral loading condition. at this time, we calculated Von Mises stress distribution in supporting bone through finite element method. Result: When apply $45^{\circ}$ oblique load to in-line arrangement model, maximum stress result for 100 N for each 3 crown 47.566MPa. In tripodal placement, result for 1mm buccal offset tripodal placement implant model was maximum distributed load 51.418MPa, so result was higher than in-line arrangement model. Conclusion: In stress distribution result by placement of implant fixture, the most effective structure was in-line arrangement. The tripodal placement does not effective for stress distribution, gap cause more damage to supporting bone.

• Bulletin of the Korean Chemical Society
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• 제30권8호
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• pp.1743-1748
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• 2009

Novel 2-aminothiazolinium based tripodal receptors were designed and synthesized. The binding property of these receptors toward various anions was investigated by the isothermal titration calorimetry (ITC) method. Receptor 4 recognized the acetate anion with 1:1 stoichiometry, whereas it bound the other oxoanions such as sulfate and phosphate in complex modes. By modifying the phenyl groups at the 4-position of the thiazoline rings of the tripodal receptor 4 to induce a mutual aromatic stacking interaction among the three ligands, receptor 10 showed totally different binding behavior, which gave rise to the 1:1 binding mode for the sulfate anion. This result was confirmed by ESI MS spectrometry.

• Bulletin of the Korean Chemical Society
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• 제23권10호
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• pp.1420-1424
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• 2002

• Bulletin of the Korean Chemical Society
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• 제31권3호
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• pp.724-726
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• 2010

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.833-836
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• 2005

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2003년도 ICCAS
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• pp.2045-2050
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• 2003

This paper describes the development of service robotic systems with the Tripodal schematic control architecture. We show practical advantages of the proposed architecture by giving examples of our experience. First, we explain how to add new task using Tripodal architecture approach. The Tripodal architecture provides some crucial organizing principles and core components that are used to build the basis for the system. Thus, the newly developed behaviors, motion algorithm, knowledge, and planning schemes are arranged so as to guarantee the efficiency of the performance of components. Second, we describe the reusability and scaleability of our architecture by introducing the implementation process of the guide robot Jinny. Most of modules developed for former robots like PSR-1 and PSR-2 systems are used directly to the Jinny system without significant modification. Experimental results clearly showed that the developed strategy is useful, even if the hardware configurations as well as software algorithms are more complex and more accumulating.

• Bulletin of the Korean Chemical Society
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• 제27권5호
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• pp.747-750
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• 2006

Research on tripodal complexes has grown in recent decades and has been subject of numerous reports.1-11 The reasons for this interest include their relevance to model functions of metalloenzymes1-3 and their potential applications in catalysis.13-17 The ligand system used most in this category has been tren, the tripodal tetraamine N(CH2CH2NH2)3, and its derivatives.4 The bz3tren is a versatile tetradentate ligand, known to form stable complexes not only with transition metals5-11 including Cu2+, Zn2+ and Co2+ but also anion species.12 However, only few results on the d10 metal complexes with bz3tren have been reported by us10 and others.6,7 As a part of on going efforts, we therefore focus our attention to extend other d10 system that includes heavy metal ions.

• 폴리머
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• 제38권3호
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• pp.386-390
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• 2014

덴드리머의 중심에 삼발이 핵을 갖는 덴드리머의 합성을 위한 효율적인 연결 방법이 개발되었다. 합성전략은 알데히드 덴드론과 아자이드기를 갖는 삼발이 핵 사이의 반응을 톨루엔 용매와 triphenylphosphine 존재하에서 진행하는 새로운 클릭화학(Staudinger/aza-Wittig 반응)을 이용하였다. 덴드리머의 삼발이 핵으로 작용할 수 있는 단위체인 1,3,5-tris-(3-azido-propoxy)-benzene을 합성하였고, 이 화합물의 아자이드기는 덴드리머의 형성에 이용되었다. 1,3,5-Tris-(3-azido-propoxy)-benzene을 이용하여 알데히드 덴드론과 Staudinger/aza-Wittig 반응을 통해 덴드리머를 합성하였으며, 모든 덴드리머는 높은 수득률로 얻어졌다.

• Bulletin of the Korean Chemical Society
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• 제27권5호
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• pp.739-743
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• 2006

Synthesis of cholic acid-based tripodal receptor (1) and its high chloride ion affinity in comparison with that of chenodeoxycholic acid (2) and lithocholic acid-based receptor (3) was achieved. Anion binding affinities of the receptors were evaluated $by\;^1H$ NMR and ITC titrations. Tripodal receptor 1 showed a selective affinity for $CI ^-$ over $Br ^-$, $I^-$, $H_2 PO _4\;^-$, and $CH _3 CO_2\;^-$. The selectivity of 1 for $CI ^-$ is about 3 times that of $Br ^-$, and 17 times that for $H_2 PO_4\;^-$.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3343-3345
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• 2014