Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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2-Aminothiazolinium Based Tripodal Receptors:Synthesis and Recognition of Oxoanions

  • Nguyen, Quynh Pham Bao (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University) ;
  • Le, Thanh Nguyen (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University) ;
  • Kim, Taek-Hyeon (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University)
  • Published : 2009.08.20
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Abstract

Novel 2-aminothiazolinium based tripodal receptors were designed and synthesized. The binding property of these receptors toward various anions was investigated by the isothermal titration calorimetry (ITC) method. Receptor 4 recognized the acetate anion with 1:1 stoichiometry, whereas it bound the other oxoanions such as sulfate and phosphate in complex modes. By modifying the phenyl groups at the 4-position of the thiazoline rings of the tripodal receptor 4 to induce a mutual aromatic stacking interaction among the three ligands, receptor 10 showed totally different binding behavior, which gave rise to the 1:1 binding mode for the sulfate anion. This result was confirmed by ESI MS spectrometry.

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