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http://dx.doi.org/10.5012/bkcs.2009.30.8.1743

2-Aminothiazolinium Based Tripodal Receptors:Synthesis and Recognition of Oxoanions  

Nguyen, Quynh Pham Bao (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University)
Le, Thanh Nguyen (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University)
Kim, Taek-Hyeon (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.8, 2009 , pp. 1743-1748 More about this Journal
Abstract
Novel 2-aminothiazolinium based tripodal receptors were designed and synthesized. The binding property of these receptors toward various anions was investigated by the isothermal titration calorimetry (ITC) method. Receptor 4 recognized the acetate anion with 1:1 stoichiometry, whereas it bound the other oxoanions such as sulfate and phosphate in complex modes. By modifying the phenyl groups at the 4-position of the thiazoline rings of the tripodal receptor 4 to induce a mutual aromatic stacking interaction among the three ligands, receptor 10 showed totally different binding behavior, which gave rise to the 1:1 binding mode for the sulfate anion. This result was confirmed by ESI MS spectrometry.
Keywords
2-Aminothiazolinium tripodal receptors, Recognition of oxoanions
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