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http://dx.doi.org/10.5012/bkcs.2006.27.5.747

d10 Metal Complexes of a Tripodal Amine Ligand  

Choi, Kyu-Seong (Department of Chemistry, Kyungnam University,)
Kang, Dong-hyun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
Lee, Ji-Eun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
Seo, Joo-beom (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.5, 2006 , pp. 747-750 More about this Journal
Abstract
Research on tripodal complexes has grown in recent decades and has been subject of numerous reports.1-11 The reasons for this interest include their relevance to model functions of metalloenzymes1-3 and their potential applications in catalysis.13-17 The ligand system used most in this category has been tren, the tripodal tetraamine N(CH2CH2NH2)3, and its derivatives.4 The bz3tren is a versatile tetradentate ligand, known to form stable complexes not only with transition metals5-11 including Cu2+, Zn2+ and Co2+ but also anion species.12 However, only few results on the d10 metal complexes with bz3tren have been reported by us10 and others.6,7 As a part of on going efforts, we therefore focus our attention to extend other d10 system that includes heavy metal ions.
Keywords
Tripodal amine ligand; $d^ {10}$ Metal ions; Complex; Crystal structure; NMR;
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