Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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d10 Metal Complexes of a Tripodal Amine Ligand

  • Choi, Kyu-Seong (Department of Chemistry, Kyungnam University,) ;
  • Kang, Dong-hyun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, Ji-Eun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Seo, Joo-beom (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
  • Published : 2006.05.20
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Abstract

Research on tripodal complexes has grown in recent decades and has been subject of numerous reports.1-11 The reasons for this interest include their relevance to model functions of metalloenzymes1-3 and their potential applications in catalysis.13-17 The ligand system used most in this category has been tren, the tripodal tetraamine N(CH2CH2NH2)3, and its derivatives.4 The bz3tren is a versatile tetradentate ligand, known to form stable complexes not only with transition metals5-11 including Cu2+, Zn2+ and Co2+ but also anion species.12 However, only few results on the d10 metal complexes with bz3tren have been reported by us10 and others.6,7 As a part of on going efforts, we therefore focus our attention to extend other d10 system that includes heavy metal ions.

Keywords

References

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