• 제목/요약/키워드: titanium (Ti)

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양극산화 불꽃 방전에 의한 Ti 산화피막의 표면특성 (Characterization of Surface at Ti Oxide Films Converted by Anodic Spark Discharge)

  • 송재주;한병성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.545-546
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    • 2006
  • This study was performed to investigate the surface properties of electrochemically oxidized pure titanium by anodic spark discharging method. Commercially pure titanium plates of $10{\times}20{\times}1[mm]$ in dimensions were polished sequentially emery paper. Anodizing was performed at current density of $76.2\;[mA/cm^2]$, application voltage of 290, 350, 400 [V] using a regulated DC power supply, which allowed automatic transition constant current when a preset maximum voltage has been reached. The Ti surface oxided films was characterized by scanning electron microscope(SEM). The precipitation of HA(Hydroxyapatite) crystals on anodized surface was greatly accelerated by hydrothermal treatment. The concentrations of DL-$\alpha$-Glycerolphosphate Magnesiurn(DL-$\alpha$-GP-Mg) salt and Ca acetate in an electrolyte was highly affected the precipitation of HA crystals converted by Ti Anodized oxide films by Shape of Impulse Voltage.

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Mechanical and wear properties of HPT-biomedical titanium: A review

  • Mohammed, Mohsin Talib
    • Biomaterials and Biomechanics in Bioengineering
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    • 제2권3호
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    • pp.185-196
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    • 2015
  • Titanium (Ti) based alloys are widely used in biomedical implants due to their low density, excellent corrosion resistance and good biocompatibilities. In recent years, growing interest in sever plastic deformation (SPD) has stimulated research and development on the techniques to attain refining of the grain size to the submicrometer or even nanometer level. The mechanical and wear properties determining the application of Ti in medicine may be improved via SPD. High pressure torsion (HPT) technique is one of the approaches available for improving the mechanical and wear properties of biomedical Ti materials. Accordingly, this article is designed to examine most recent state of the art scientific works related to the developments in mechanical properties and wear resistance of biomedical Ti materials processed by HPT. A comprehensive review in this area is systematically presented.

Titanium Dioxide Nanomaterials and its Derivatives in the Remediation of Water: Past, Present and Future

  • Tiwari, Alka;Shukla, Alok;Tiwari, Diwakar;Choi, Suk Soon;Shin, Hyun-Gon;Lee, Seung-Mok
    • 공업화학
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    • 제30권3호
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    • pp.261-279
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    • 2019
  • The aim of this review article is to summarize the role of titanium oxide ($TiO_2$) nanomaterials in the remediation of the aquatic environment contaminated with various emerging pollutants. The advanced oxidation process led by the semiconductor $TiO_2$ is an impetus in the remediation technology. Therefore, a vast number of literature works are available in this area. Further, the role of modified $TiO_2$ or thin film materials were discussed in the review. Also, the Localized Surface Plasmon Resonance (LSPR) effect of using noble metaldoped $TiO_2$ played an interesting role in the remediation process.

티타늄금속과 골조직의 계면에 관한 연구 -골과 임플란트 계면에서의 Ti-ion의 거동에 대하여(1)- (ON THE INTERFACE BETWEEN TITANIUM METAL AND BONE TISSUE -Ti-ion leakage from bone and implant interface(1)-)

  • 조성암;조광헌;서조영
    • 대한치과보철학회지
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    • 제33권2호
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    • pp.354-357
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    • 1995
  • The secondary ion of titanium from commercially pur titanium implant which installed at Rabbit tibia. Was analyzed by Secondary lon Mass Spectroscopy. And we detected about 3476 ppm ion from $10-50{\mu}m$ distance from interface.

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Electrochemical Impedance Characteristics of Anodic Oxide Layer Formed on Titanium Binary Alloy Surface

  • Lee, Kang;Choe, Han-Choel;Ko, Yeong-Mu
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2008년도 추계학술대회 초록집
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    • pp.30-30
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    • 2008
  • In this study, electrochemical impedance characteristics of anodic oxide layer formed on titanium binary alloy surface have been investigated. Titanium oxide layers were grown on Ti-$_XTa$ and Ti-$_XNb$(X=10, 20, 30 and 40 wt%) alloy substrates using phosphoric acid electrolytes.

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치과주조용 Ti-X%Zr(X=10,20,40)합금의 연삭성 (Grindability of Cast Ti-X%Zr(X=10,20,40) Alloys for Dental Applications)

  • 정종현;노형록
    • 대한치과기공학회지
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    • 제33권4호
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    • pp.263-270
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    • 2011
  • Purpose: The grindability of binary Ti-X%Zr(X=10,20,40) alloys in order to develop a Ti alloy with better machinability than unalloyed titanium has been evaluated. Methods: Experimental Ti-Zr alloys were made in an argon-arc melting furnace. Slabs of experimental alloys were ground using a SiC abrasive wheel on an electric handpiece at circumferential speeds(12000,18000,25000 or 30000rpm) by applying a force(200gr). Grinding rate was evaluated by measuring the amount of metal volume removed after grinding for 1 minute and the volume ratio of metal removed compared to the wheel material lost, which was calculated from the diameter loss (grinding ratio). Experimental datas were compared to those for cp Ti(commercially pure titanium) and Ti-6%Al-4%V alloy were used controls. Results: It was observed that the grindability of Ti-Zr alloys increased with an increase in the Zr concentration. More, they are higher than cp Ti, particularly the Ti-20%Zr alloy exhibited the highest grindability at all circumferential speeds. There was significant difference in the grinding rate and grinding ratio between Ti-20%Zr alloy and cp Ti at any speed(p<0.05). Conclusion: By alloying with Zr, the Ti exhibited better grindability at all circumferential speeds. the Ti-20%Zr alloy has a great potential for use as a dental machining alloy.

$Si_3N_4-TiC$ Ceramic 공구에 화학증착된 TiC, TiN 및 Ti(C, N)에 관한 연구 (A Study on the Chemically Vapor Deposited TiC, TiN, and TiC(C, N) on $Si_3N_4$-TiC Ceramic Tools.)

  • 김동원;김시범;이준근;천성순
    • Tribology and Lubricants
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    • 제4권2호
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    • pp.36-43
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    • 1988
  • Titanium carbide(TiC) and titanium nitride(TiN) flims were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$ and $TiCl_4-H_2-N_2$ gas mixtures, respectively. The nonmetal to metal ratio of deposit increases with increasing $m_{C/Ti}$(mole ratio of CH$_4$ to TiCl$_4$ in the input) for TiC coatings and $m_{N/Ti}$(mole ratio of N$_2$ to TiCl$_4$ in the input) for TiN coatings. The nearly stoiahiometric films could be obtained under the deposition condition of $m_{C/Ti}$ between 1.15 and 1.61 for TiC, and that of $m_{N/Ti}$ between 25 and 28 for TiN. Also maximum microhardness of the coatings can be obtained in these ranges. The interfacial region of TiC coatings on $Si_3N_4$-TiC ceramics is wider than that of TiN coatings according to Auger depth profile analysis, which indicates good interfacial bonding for TiC. Experimental results show that TiC coatings have an randomly equiaxed structure and Columnar structure with(220) preferred orientation can be obtained for TiN coatings. And, multilayer coatings have a dense and equiaxed structure.

A STUDY ON MECHANICAL PROPERTIES OF TiN, ZrN AND WC COATED FILM ON THE TITANIUM ALLOY SURFACE

  • Oh, Dong-Joon;Kim, Hee-Jung;Chung, Chae-Heon
    • 대한치과보철학회지
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    • 제44권6호
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    • pp.740-750
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    • 2006
  • Statement of problems. In an attempt to reduce screw loosening, dry lubricant coatings such as pure gold or tefron have been applied to the abutment screw. However, under repeated tightening and loosening procedures, low wear resistance and adhesion strength of coating material produced free particles on the surface of abutment screw and increased frictional resistance resulting in screw tightening problems. Purpose. The aim of this study was to compare friction coefficient, adhesion strength, vickers hardness and evaluate coating surface of titanium alloy specimens coated with TiN(titanium nitride), ZrN(zirconium nitride) and WC(tungsten carbide). Material and method. Titanium alloy(Ti-6Al-4V) discs of 12mm in diameter and 1mm in thickness divided into 4 groups. TiN, ZrN and WC was coated for the specimens of 3 groups respectively, and those of 1 group were not coated. Each group was made up of 4 specimens. In this study, sputtering method was used among the PVD(Physical Vapor Deposition) techniques available for TiN, ZrN and WC coatings. Friction coefficient, adhesion strength, vickers hardness and coating surface of 4 groups were measured. Results. 1. For all three coating conditions, friction coefficient was significantly decreased. Especially, ZrN coated surface showed the lowest value. $TiN(0.39{\pm}0.02)$, $ZrN(0.24{\pm}0.01)$, $WC(0.31{\pm}0.03)$. 2. TiN coating showed the highest adhesion strength, however ZrN coating had the lowest value. $TiN(25.3N{\pm}1.6)$, $ZrN(14.8N{\pm}0.6)$, $ WC(18.4N{\pm}0.7)$. 3. Vickers hardness of all three coatings was remarkably increased as compared with that of none coated specimen. TiN coating had the highest Vickers hardness, however WC coating showed the lowest value. $TiN(1865.2{\pm}33.8)$, $ZrN(1814.4{\pm}18.6)$, $WC(1008.5{\pm}35.9)$. 4. The ZrN or WC coated specimen showed a homogeneous and smooth surface, however the rough surface with defects was observed for TiN coating. Conclusions. When TiN, ZrN and WC coating applied to the abutment screw, frictional resistance would be reduced, as a result, the greater preload and prevention of the screw loosening could be expected.