• 한국세라믹학회지
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• 제36권11호
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• pp.1178-1182
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• 1999

• 한국지하수토양환경학회지:지하수토양환경
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• 제12권3호
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• pp.29-35
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• 2007

본 연구에서는 산소플라즈마로 티타늄을 산화하고 급속열처리하여 티타니아 광촉매 박막을 제조하고 휴믹산 제거실험을 수행하였다. 플라즈마 화학기상증착장치에서의 산소플라즈마는 티타늄 표면을 산화시킴으로써 광촉매 피막을 생성하게 된다. 증착조건에서 RF power는 최대 500 W 이하에서 100 W, 150 W, 300 W, 처리시간은 5분, 10분에서 조절되었다. 박막의 특성은 XPS와 XRD로 측정하였다. 실험으로서 우리는 박막이 높은 성능을 나타내는 최적을 조건을 찾았다. 또한 제조된 박막의 경우 기존 Thermal spray Titania film에 비해 2배정도 우수하였고 분말만큼 광촉매 성능을 갖는다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.36.2-36.2
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• 2011

Titanium and its alloys have been widely used for orthopedic implants because of their good biocompatibility. We have previously shown that the crystalline titania layers formed on the surface of titanium metal via anodic oxidation can induce apatite formation in simulated body fluid, whereas amorphous titania layers do not possess apatite-forming ability. In this study, hot water and heat treatments were applied to transform the titania layers from an amorphous structure into a crystalline structure after titanium metal had been anodized in acetic acid solution. The apatite-forming ability of titania layers subjected to the above treatments in simulated body fluid was investigated. The XRD and SEM results indicated hot water and/or heat treatment could greatly transform the crystal structure of titania layers from an amorphous structure into anatase, or a mixture of anatase and rutile.The abundance of Ti-OH groups formed by hot water treatment could contribute to apatite formation on the surface of titanium metals, and subsequent heat treatment would enhance the bond strength between the apatite layers and the titanium substrates. Thus, bioactive titanium metals could be prepared via anodic oxidation and subsequent hot water and heat treatment that would be suitable for applications under load-bearing conditions.

• Bulletin of the Korean Chemical Society
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• 제34권4호
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• pp.1065-1069
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• 2013

A highly sensitive electrochemical detection method for bisphenol A (BPA) has been developed by using multi-walled carbon nanotube (CNT)-doped titania-Nafion composite modified glassy carbon (GC) electrode. The CNT-titania-Nafion/GC electrode exhibited excellent electrocatalytic activity towards BPA. Therefore, the CNT-titania-Nafion/GC electrode showed improved voltammetric responses for BPA compared to that obtained with bare GC electrode. In addition, cetyltrimethylammonium bromide (CTAB), a cationic surfactant, was added into the BPA sample solution in order to accumulate BPA through hydrophobic interaction between CTAB and BPA. The CNT-titania-Nafion/GC electrode gave a linear response ($r^2$ = 0.999) for BPA from $1.0{\times}10^{-8}$ M to $5.0{\times}10^{-6}$ M with a detection limit of $9.0{\times}10^{-10}$ M (S/N = 3). The modified electrode showed good selectivity against interfering species and also exhibited good reproducibility. The present electrochemical sensor based on the CNT-titania-Nafion/GC electrode was applied to the determination of BPA in food package samples.

• Bulletin of the Korean Chemical Society
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• 제34권8호
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• pp.2271-2275
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• 2013

We report on the photoelectrochemical properties of partially reduced mesoporous titania thin films. The fabrication is achieved by synthesizing mesoporous titania thin films through the self-assembly of a titania precursor and a block copolymer, followed by aging and calcination, and heat-treatment under a $H_2$ (1 torr) environment. Depending on the temperature used for the reaction with $H_2$, the degree of the reduction (generation of oxygen vacancies) of the titania is controlled. The oxygen vacancies induce visible light absorption, and decrease of resistance while the mesoporosity is practically unaltered. The photoelectrochemical activity data on these films, by measuring their photocurrent-potential behavior in 1 M NaOH electrolyte under AM 1.5G 100 mW $cm^{-2}$ illumination, show that the three effects of the oxygen vacancies contribute to the enhancement of the photoelectrochemical properties of the mesoporous titania thin films. The results show that these oxygen deficient $TiO_2$ mesoporous thin films hold great promise for a solar hydrogen generation. Suggestions for the materials design for improved photoelectrochemical properties are made.

• 한국진공학회지
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• 제6권S1호
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• pp.23-26
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• 1997

Nanophase titania film was obtained by plasma spraying. The structure of titania film was investigated with transmission electron microscopy (TEM). It was found taht the film was composed of grains with mean particle size of 15nm. The crystal structure of nanophase titania film was found to be anatase phase by electron diffraction.

• 한국세라믹학회지
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• 제25권6호
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• pp.677-684
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• 1988

Titania powders were obtained from the various hydrolysis condition the variation of Alkoxide, water/Alcohol, REaction, Temp., reaction time and solvent system were investigated. In this result, spherical monodisperesed titania gel powders(≒0.7${\mu}{\textrm}{m}$) were obtained using EtOH(as solvent), and this method had rapid reaction time compare with iso-PrOH(as solvent).

• 한국재료학회지
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• 제4권4호
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• pp.477-482
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• 1994

열처리에 따른 함수 티타니아의 구조변화를 X-선 회절, 투과전자현미경, 적외선 흡수 및 라만 분광분석 등을 통하여 조사하였다. 과산화수소와 사염화티타의 혼합용액으로부터 $30^{\circ}C$, pH 9에서 함수 티타니아를 제조하였다. 침전물은 완전하게는 결정화되지 않은 anatase형의 티타니아였다. $700^{\circ}C$까지 열처리온도가 증가함에 따라 anatase의 결정성은 증가하였으며, 입성자은 높은 온도에서 일어났다. $700^{\circ}C$에서 anatase로부터 rutile형이 생성되었다.

• Advances in nano research
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• 제4권3호
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• pp.157-165
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• 2016

The photocatalytic (PC) activity of anatase titania nanoparticles can be improved through codoping with transition metals and nitrogen. In addition, the PC activity can also be improved by creating monodisperse, mesoporous nanoparticles of titania. The question naturally arose as to whether combining these two characteristics would result in further improvement in the PC activity or not. Herein, we describe the synthesis and photocatalytic characteristics of codoped, monodisperse anatase titania. The transition metals tested in the polydisperse and the monodisperse forms were Mn, Co, Ni, and Cu. In each case, it was found that the monodisperse version had a higher PC activity compared to the corresponding polydisperse version.

• 환경위생공학
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• 제20권4호통권58호
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• pp.45-50
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• 2005

Titania gel formations were prepared by sol-gel method using titanium(IV) chloride $(TiCl_4)$, and its characteristics were analyzed by varying the $epoxide/TiCl_4$ ratio and the amount of water In the end, titania $(TiO_2)$ aerogel were prepared using supercritical drying process. VOCs such as benzene, toluene, and m-xylene (BTX) were oxidized using prepared titania aerogel and commercially available $TiO_2$, and its performance was compared. The surface area, pore volume, and average pore diameter of 1,2-epoxybutane are significantly smaller than the propylene oxide. And the titania aerogels with 6 moi of epoxides have high surface areas, pore volumes, and average pore diameters. As a result of photo-oxidation, conversion of benzene was reached about $70\%$, and other reactants were reached about $60\%$ similarly. The conversion of BTX was increased as inlet concentration decreased. The reactivity of titania calcined at $600^{\circ}C$ was greater than $400^{\circ}C$ and $800^{\circ}C$. Water is required as a reactants for the oxidation of VOCs, and the continuous consumption of hydroxyl radicals required replenishments to maintain catalyst activity. The activity ratio increased with increasing reaction time when enough amount of water was present in the reactor.