• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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• pp.1-20
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• 1998

Processing of thin films by chemical vapor deposition (CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit for the substrate temperature that diamond can deposit is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD process variables.

• Advances in aircraft and spacecraft science
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• 제8권1호
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• pp.1-15
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• 2021

Mars exploration demands aerodynamic computations for a proper design of missions of spacecraft carrying instruments and astronauts to Mars. Both Computational Fluid Dynamics (CFD) and Direct Simulation Monte Carlo (DSMC) method play a key role for this purpose. To the author's knowledge, the altitude separating the fields of applicability of CFD and DSMC in Mars atmosphere entry is not yet clearly defined. The limitations in using DSMC at low altitudes are due to technical limitations of the computer. The limitations in using CFD at high altitudes are due to thermodynamic non-equilibrium. Here, this problem is studied in Mars atmosphere entry, considering the Mars Pathfinder capsule in the altitude interval 40-80 km, by means of a DSMC code. Non-equilibrium is quantified by the relative differences between translational temperature and: rotational (θt-r), vibrational (θt-v), overall (θt-ov) temperatures, anisotropy is quantified by the relative difference between the translational temperature component along x and those along y (θx-y) and along z (θx-z). The results showed that θt-r, θt-v, θx-y, θx-z are almost equivalent. The altitude of 45 km should be the limit altitude for a proper use of a CFD code and the altitude of 40 km should be the limit altitude for a reasonable use of a DSMC code.

• 천문학회지
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• 제49권1호
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• pp.1-8
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• 2016

The aim of this study is to describe the physical processes taking place in the solar photosphere. Based on 3D hydrodynamic simulations including a detailed radiation transfer scheme, we investigate thermodynamic structures and radiation fields in solar surface convection. As a starting model, the initial stratification in the outer envelope calculated using the solar calibrations in the context of the standard stellar theory. When the numerical fluid becomes thermally relaxed, the thermodynamic structure of the steady-state turbulent flow was explicitly collected. Particularly, a non-grey radiative transfer incorporating the opacity distribution function was considered in our calculations. In addition, we evaluate the classical approximations that are usually adopted in the onedimensional stellar structure models. We numerically reconfirm that radiation fields are well represented by the asymptotic characteristics of the Eddington approximation (the diffusion limit and the streaming limit). However, this classical approximation underestimates radiation energy in the shallow layers near the surface, which implies that a reliable treatment of the non-grey line opacities is crucial for the accurate description of the photospheric convection phenomenon.

• 대한화학회지
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• 제40권6호
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• pp.409-414
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• 1996

선형 비평형 열역학의 최소 엔트로피 생성원리를 사용하여 정상 평면충격파 형상에 대한 Navier-Stokes 유체방정식의 적용한계를 연구하였다. 해석적 결과를 얻기 위하여 평형상태에 가까운 하류 위치에서 방정식을 선형화 하였다. 하류 극한의 경계조건을 충족하는 Navier-Stokes 방정식의 해를 충격파 진행속도의 마하수 M=1 근처에서 급수전개하였을 때, 일차항까지는 열역학의 요구조건과 부합하였다.

• 한국결정성장학회지
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• 제9권1호
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• pp.80-83
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• 1999

화학증착에 의한 박막 제조에서는 화학반응을 수반되어 엄밀한 속도론적 분석이 어렵다. 이러한 경우는 열역 학적인 분석이 화학증착공정을 이해하는데 더 유용하고 원하는 박막을 제조하기 위한 최적공정조건을 결정함에 있어서 도 도움이 된다. 이러한 이유로 화학증착 상태도가 사용되어 왔다. 본 연구에서는 C-H 계와 Si-Cl-H 계의 열역학적 분 석을 통하여 열역학이 어떻게 화학증착 공정에 응용될 수 있는가를 보여주려고 하였다. 각 공정변수가 증착 구동력에 미 치는 효과를 결정함으로서, C-H 계에서 다이아몬드가 증착될 수 있는 열역학적인 한계를 계산하였다. Si-Cl-H 계에서는 동 과포화도 곡선을 계산함으로써 화학증착 공정변수의 효과에 대한 부가적인 정보를 얻을 수 있었다.

• 대한기계학회논문집
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• 제16권1호
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• pp.77-86
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• 1992

본 연구에서는 사이클은 터빈 출구로 부터 배출되는 폐열을 최대한 회수하여 얻은 증기를 연소기내에 분사시킴으로써 부가적인 압축기 및 비출력의 상향을 기할수 있다.아울러 폐열이용 암모니아 흡수기 냉동기를 구동하여 압축기 입구 온도를 낮 춤에 의해 열효율 및 비출력의 증대는 물론 대기온도 변화에 따른 기관 성능의 변동을 감소시킬 수 있다.

• International Journal of Naval Architecture and Ocean Engineering
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• 제5권4호
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• pp.529-545
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• 2013

Strong restrictions on emissions from marine power plants (particularly $SO_x$, $NO_x$) will probably be adopted in the near future. In this paper, a combined solid oxide fuel cell (SOFC) and gas turbine fuelled by natural gas is proposed as an attractive option to limit the environmental impact of the marine sector. It includes a study of a heat-recovery system for 18 MW SOFC fuelled by natural gas, to provide the electric power demand onboard commercial vessels. Feasible heat-recovery systems are investigated, taking into account different operating conditions of the combined system. Two types of SOFC are considered, tubular and planar SOFCs, operated with either natural gas or hydrogen fuels. This paper includes a detailed thermodynamic analysis for the combined system. Mass and energy balances are performed, not only for the whole plant but also for each individual component, in order to evaluate the thermal efficiency of the combined cycle. In addition, the effect of using natural gas as a fuel on the fuel cell voltage and performance is investigated. It is found that a high overall efficiency approaching 70% may be achieved with an optimum configuration using SOFC system under pressure. The hybrid system would also reduce emissions, fuel consumption, and improve the total system efficiency.

• International Journal of Automotive Technology
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• 제2권4호
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• pp.147-155
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• 2001

Analysis of the thermodynamic cycle of IC engine from the point of view of economy and emissions was carried out. From this analysis potential capability of engine development was derived. This potential capability is lean-burn engine, fuelled with homogeneous mixture with $\lambda \geq$ 1.4. Several different modes of fuelling were proposed and tested on one-cylinder test engine from the point of view of extending lean operating limit of the engine, emissions and fuel economy. Among them were: fuelling with evaporated preheated gasoline, with gas (LPG evaporated) and with liquid butane. From these modes, fuelling with liquid butane injected to inlet port was selected and finally tested. This novel system of fuelling offered better than standard engine performances and emissions at lean operating limit. These results were validated on full-scale two-cylinder engine.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 1999년도 제1회 학술대회논문집(KIASC 1st conference 99)
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• pp.198-201
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• 1999

An optimal cooling method for HTS(high Tc superconductor) current leads has been analytically sought to minimize the required refrigerator power. The binary current lead is a series combination of a normal metal conductor at the warmer part and an HTS at the colder part. The lead is cooled by direct contacts with a two-stage cryocooler at the joint and at the cold end. It is clearly proven that there exists unique optimal values for the joint temperature and the current density to minimize the refrigerator power per unit current. the actual power input to the cryocooler in the optimal conditions is compared with its thermodynamic limit, and some significant issues in practical design are presented with a useful graphical method.

• 한국재료학회지
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• 제15권1호
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• pp.47-53
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• 2005

The E.M.F. of the galvanic cell with fused salt was measured to determine the activities of zinc at 720-860 K over the entire composition range of liquid Zn-In and Zn-Sn alloys. The cell used was as follows: $$(-)W{\mid}Zn(pure){\mid}Zn^{2+}(KCl-LiCl){\mid}Zn(in\;Zn-In\;or\;Zn-Sn\;alloy){\mid}W(+)$$ The activities of zinc in the alloys showed positive deviation from Raoult's law over the entire composition range. The activity of cadmium and some thermodynamic functions such as Gibbs free energy, enthalpy and entropy were derived from the results by the thermodynamic relationship. The comparison of the results and the literature data was made. The liquid Zn-In and Zn-Sn alloys are found to be close tn the regular solution. The concentration fluctuations in long wavelength limit, $S_{cc}(o)$, in the liquid alloy were calculated from the experimental results.