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Effect of H2O2 modification of H3PW12O40@carbon for m-xylene oxidation to isophthalic acid

  • Fang, Zhou-wen;Wen, Di;Wang, Zhi-hao;Long, Xiang-li
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2172-2184
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    • 2018
  • The production of isophthalic acid (IPA) from the oxidation of m-xylene (MX) by air is catalyzed by $H_3PW_{12}O_{40}$ (HPW) loaded on carbon and cobalt. We used $H_2O_2$ solution to oxidize the carbon to improve the catalytic activity of HPW@C catalyst. Experiments reveal that the best carbon sample is obtained by calcining the carbon at $700^{\circ}C$ for 4 h after being impregnated in the 3.75% $H_2O_2$ solution at $40^{\circ}C$ for 7 h. The surface characterization displays that the $H_2O_2$ modification leads to an increase in the acidic groups and a reduction in the basic groups on the carbon surface. The catalytic capability of the HPW@C catalyst depends on its surface chemical characteristics and physical property. The acidic groups play a more important part than the physical property. The MX conversion after 180 min reaction acquired by the HPW@C catalysts prepared from the activated carbon modified in the best condition is 3.81% over that obtained by the HPW@C catalysts prepared from the original carbon. The IPA produced by the former is 46.2% over that produced by the latter.

SUBNORMALITY OF THE WEIGHTED CESÀRO OPERATOR Ch∈l2(h)

  • Hechifa, Abderrazak;Mansour, Abdelouahab
    • Korean Journal of Mathematics
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    • v.25 no.1
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    • pp.117-126
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    • 2017
  • The subnormality of some classes of operators is a very interesting property. In this paper, we prove that the weighted $Ces{\grave{a}}ro$ operator $C_h{\in}{\ell}^2(h)$ is subnormal and we described completely the set of the extended eigenvalues for the weighted $Ces{\grave{a}}ro$ operator, some other important results are also given.

Dyeing of Wool and Nylon Fabrics with Chinese Scholar Tree Extract (괴화 추출물에 의한 모와 나일론직물의 염색성)

  • 배정숙;허만우
    • Journal of the Korean Home Economics Association
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    • v.41 no.2
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    • pp.107-121
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    • 2003
  • This study was discussed the dyeing of wool and nylon fabrics with Chinese Scholar Tree extract. The extracts of Chinese Scholar Tree was prepared in the condition of heating at $95{\pm}5C$, for 1 hour and cooling to 40C. And then the extracts of color matter treate with vacuum concentration at $60{\pm}2^{\circ}C$, 30mmHg and dried with spray dryer. The dyeing of wool and nylon fabric in this experiment was also employed the mordant dyeing method such as pre-mordant, post-mordant and simultaneous mordant method. The mordanting agents used in this study were as followings ; aluminium potassium sulfate, copper(II) acetate monohydrate, chromium potassium sulfate$.$$7H_2O$, Tin(II) chloride dihydrate, iron(II)sulfate $7H_2O$. For an evaluation of the dyeing property of the mordanting agents, the pre-mordant method, the repeat dyeing and the fastness of the light, dry cleaning, washing and rubbing measured respectively. From the results of the dye absorption, the optimum dyeing condition of the wool and nylon fabrics with Chinese Scholar Tree extract is at 80C dyeing temperature for 60 minutes. The optimum concentration of mordanting agent is Al, Cr, Sn 1%, Fe, Cu 2% solution. In general, the fastness property of the dyed wool and nylon fabrics had a comparatively high grade.

A NOTE ON FUZZY HV-SUBMODULES

  • Davvaz, B.
    • Journal of applied mathematics & informatics
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    • v.11 no.1_2
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    • pp.265-271
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    • 2003
  • The purpose of this paper is to present certain results arising from product between fuzzy $H_{v}$-submodules. In particular, we consider the fundamental relation $\varepsilon$* defined on an $H_{v}$-module and give a property of the fundamental relations and fundamental modules with respect to the fuzzy product of $H_{v}$-modules.

A study on the performance of the polymer valve in Total Artificial Heart (인공심장용 폴리머 밸브의 역류 특성 분석)

  • Lee, J.J.;Choi, J.H.;Lee, J.H.;Yi, S.W.;Om, K.S.;Ahn, J.M.;Min, B.G.
    • Proceedings of the KOSOMBE Conference
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    • v.1998 no.11
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    • pp.241-242
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    • 1998
  • For the aritificial heart valve, two types of valves-polymer and mechanical valve- are generally used. The polymer valve is used as a new low-cost artificial valve. Among the several properties of the artificial valve, the low-regurgitation property is important because it can provide better cardiac output characteristic. So in this study we analyzed and compared the regurgitation property of the mechanical valve which is generally used nowdays and the polymer valve which was made in our group. As results, the polymer valve showed the better regurgitation property compared to the mechanical valve approximately by 3 times, and increased the cardiac output by 10%.

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Mechanical Property and Microstructure of the Annealed Fe-Si Alloy Manufactured by Laser-Powder Bed Fusion (L-PBF 공정 처리된 Fe-Si 합금의 열처리 조건에 따른 미세조직 및 기계적 특성)

  • J. Y. Park;M. S. Gwak;S. G. Jeong;H. S. Kim;J. G. Kim
    • Transactions of Materials Processing
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    • v.32 no.2
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    • pp.67-73
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    • 2023
  • To overcome a climate change, manufacturing complex-shaped electric mobility parts becomes one of the important issues for enhancing a performance of motor with reducing their weight. Therefore, development of laser-based additive manufacturing shed on light due to their flexible manufacturing capacity that can be suitable to solve the poor formability of Fe-Si alloys for electric mobility parts. Although there are several studies existed to optimize the performance of additively manufactured Fe-Si alloys, the post-annealing effect was not well investigated yet though this is important to control the texture and mechanical properties of additively manufactured parts. In the present work, annealing effect on the mechanical property and microstructure of additively manufactured Fe-4.5Si alloy was investigated. Because of the ordered phase initiation after annealing, the hardness of additively manufactured Fe-4.5Si alloy increased up to 1173 K while a hardness drop occurs at the 1273 K condition due to the micro-crack initiation. The response surface methodology result represents the 1173 K-5 h sample is an optimal condition to maximize the mechanical property of additively manufactured alloy without micro-cracks.

A study on the surface change of MgO by discharge in AC PDP (방전시간에 따른 MgO 표면층의 변화에 관한 연구)

  • Ji, S.W.;Yeo, J.Y.;Kim, D.H.;Park, C.H.;Cho, J.S.
    • Proceedings of the KIEE Conference
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    • 1998.07e
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    • pp.1764-1766
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    • 1998
  • One of the most important problems in the development of AC PDP is to make long life and more stable panels. It is well known that the life time of a panel strongly depends on the sputtering-resistant property of the protecting layer such as MgO. However, the sputtering rate is so low that it is very difficult to measure the sputtering-resistant property of MgO. This paper describes a high speed measurement technique to test the sputtering-resistant property of MgO thin film by the R.F. magnetron sputtering. In this case the MgO sample has been used as a target of sputtering process. Moreover, the MgO surface changed by ion-bombarding sputtering are also discussed with SEM photoes.

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PEBBLING ON THE MIDDLE GRAPH OF A COMPLETE BINARY TREE

  • LOURDUSAMY, A.;NELLAINAYAKI, S. SARATHA;STEFFI, J. JENIFER
    • Journal of applied mathematics & informatics
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    • v.37 no.3_4
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    • pp.163-176
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    • 2019
  • Given a distribution of pebbles on the vertices of a connected graph G, a pebbling move is defined as the removal of two pebbles from some vertex and the placement of one of those pebbles at an adjacent vertex. The t-pebbling number, $f_t(G)$, of a connected graph G, is the smallest positive integer such that from every placement of $f_t(G)$ pebbles, t pebbles can be moved to any specified vertex by a sequence of pebbling moves. A graph G has the 2t-pebbling property if for any distribution with more than $2f_t(G)$ - q pebbles, where q is the number of vertices with at least one pebble, it is possible, using the sequence of pebbling moves, to put 2t pebbles on any vertex. In this paper, we determine the t-pebbling number for the middle graph of a complete binary tree $M(B_h)$ and we show that the middle graph of a complete binary tree $M(B_h)$ satisfies the 2t-pebbling property.

The Conceptual Design of High-Tc superconducting Magnet for a Superconducting Property Measurement System (초전도 특성평가장치용 고온 초전도 마그네트의 개념 설계)

  • Choi, S.J.;Lee, S.Y.;Bae, J.H.;Sohn, M.H.;Kim, W.S.;Park, C.;Lee, J.K.;Lee, S.J.;Choi, K.
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.1
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    • pp.20-24
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    • 2009
  • The superconducting property measurement system is used to acquire electrical and thermal properties on short HTS tape samples and the system is composed of specimen holder for mounting HTS tape and a magnet for applying magnetic fields externally. The magnet consists of two split racetrack windings and is designed to produce maximum 3T of center field. The temperature of specimen holder can be varied in range from 10K to 77K. The field homogeneity is required less than 300 gauss stray field contour within 20cm axially and 3cm radially from origin. We have worked on the conceptual designs of the conduction-cooled magnet for the superconducting characteristic measurement system. The measurement system will be fabricated in near future based on the design parameters presented in this paper.

BI-LIPSCHITZ PROPERTY AND DISTORTION THEOREMS FOR PLANAR HARMONIC MAPPINGS WITH M-LINEARLY CONNECTED HOLOMORPHIC PART

  • Huang, Jie;Zhu, Jian-Feng
    • Bulletin of the Korean Mathematical Society
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    • v.55 no.5
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    • pp.1419-1431
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    • 2018
  • Let $f=h+{\bar{g}}$ be a harmonic mapping of the unit disk ${\mathbb{D}}$ with the holomorphic part h satisfying that h is injective and $h({\mathbb{D}})$ is an M-linearly connected domain. In this paper, we obtain the sufficient and necessary conditions for f to be bi-Lipschitz, which is in particular, quasiconformal. Moreover, some distortion theorems are also obtained.