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Ferroelectric Properly of Bi3.75La0.25Ti3O12 Ceramic Sintered in the Ambient (분위기 소결공정에 의한 Bi3.75La0.25Ti3O12세라믹의 강유전특성)

  • 김응권;박춘배;박기엽;송준태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.9
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    • pp.783-787
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    • 2002
  • In recent year, B $i_{4-}$x L $a_{x}$ $Ti_3$ $O_{12(BLT)}$ is one of promising substitute materials for the ferroelectric random access memory(FRAM) applications. But the systematic composition is still insufficient, so this experiment was carried out in ceramic ambient sintering process which has the very excellent ferroelectric property. Samples were prepared by a bulk and the purpose which was estimated with a suitability of thin films applications. The density of B $i_{3.75}$ L $a_{0.25}$ $Ti_3$ $O_{12}$ was high and the XRD pattern showed that the intensity of main peak (117) was increased at the argon ambient sintering. Controlling the quantity of oxygen, crystallization showed a thin, long plate like type, and we obtained the excellent dielectric and polarization properties at the argon atmosphere sintering. Also this sintering process was effective at the bulk sample. Argon ambient sintered sample produced higher permittivity of 154, the remanent polarization(2Pr) of 6.8 uC/$\textrm{cm}^2$ compared with that sintered in air and oxygen ambient. And this sintering process showed a possibility which could be applied to thin films process..

Vibration Analysis of Frame Structural Systems by the Receptance Method (Receptance 방법에 의한 골조구조계의 진동해석)

  • S.Y. Han;K.C. Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.174-186
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    • 1991
  • There exist many frame structural systems which may be regarded as a combined structural system composed of beam/bar elements and attachments reducible to damped spring-mass systems. In this paper, analytical methods based on the receptance for the vibration analysis of such a system are presented. For the free vibration analysis and response calculations to point excitations, receptances of a uniform Timoshenko beam and a bar are derived in closed and spectral forms, and the method to obtain the system receptance by synthesizing the receptances of the elements and other subsystems is presented. The system damping property is also obtainable by sysnthesizing the components' damping properties. For calculations of the system responses to support motion, the Support Displacement Transfer Ratio(SDTR) of a uniform Timoshenko beam and a bar conceptually similar to the receptance is defined, and the method of synthesizing them with other subsystems' receptances is also presented. Such a method is very convenient especially in dynamic reanalysis subject to changes of some design variables.

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Development of two-component polyurethane metering system for in-mold coating (인몰드 코팅을 위한 2액형 폴리우레탄 공급장치 개발)

  • Seo, Bong-Hyun;Lee, Ho-Sang
    • Design & Manufacturing
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    • v.10 no.2
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    • pp.18-23
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    • 2016
  • Injection molded thermoplastic parts may need to be coated to facilitate paint adhesion, or to satisfy other surface property requirements, such as appearance, durability, and weather resistance. In this paper, a two-component polyurethane metering system was developed for the simultaneous injection and surface coating of a plastic substrate. The system was composed of storage tanks, feed pumps, axial piston pumps, mixing head. The tank was designed to be double-jacket structured and fabricated for polyol and isocyanate, respectively. A temperature chamber was used to maintain the material temperature to be $80^{\circ}C$ during flowing from storage tank to mixing head. Inside the chamber, feed pump, low pressure filter, high pressure pump, high pressure filter, pressure sensor, flow meter were installed. A mixing head of L-type was used for homogeneous mixing of polyol and isocyanate. Inside the mixing head, a cartridge heater and a temperature sensor were installed to control the temperature of the materials. The flow rate of axial-piston pump was controlled by using closed-loop feedback control algorithm. The input flow-rates were compared with the measured values. The output error was 6.7% for open-loop control, whereas the error was below 2.2% for closed-loop control. In addition, the pressure generated through mixing-head nozzle increased with increasing flow rate. It was found that the pressure drop between metering pump and mixing-head nozzle was almost 10 bar.

Study on the Hybrid Passivation layer of OLEDs using the Organic/Inorganic Thin Film (유/무기 복합 박막을 이용한 유기발광 소자의 보호층에 관한 연구)

  • Bae, Sung-Jin;Lee, Joo-Won;Lee, Young-Hoon;Kang, Nam-Soo;Kim, Dong-Young;Hwang, Sung-Woo;Kim, Jai-Kyung;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.78-80
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    • 2006
  • The hybrid thin-film (HTF) passivation layer composed of the Ultra Violet (UV) curable acrylate layer and MS-31 (MgO:$SiO_2$=3:1wt%) layer was adopted in organic light emitting device (OLEO) to protect organic light emitting materials from penetrations of oxygen and water vapors. The results showed that the HTF layer possessed a very low WVTR value of lower than $0.007gm/m^{2+}day$ at $37.8^{\circ}C$ and 100% RH. This value was within the limited range of the sensitivity of WVTR measurements. And the lifetime of the HTF passivated device became almost three times longer than that of the bare device. The HTF on the OLEO was found to be very effective in protect what from the penetrations of oxygen and moisture.

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Effects of Doneness on the Microbial, Nutritional, and Quality Properties of Pork Steak of Different Thicknesses

  • Jang, Aera;Kim, Hye-Jin;Kim, Dongwook;Kim, JinSoo;Lee, Sung-Ki
    • Food Science of Animal Resources
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    • v.39 no.5
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    • pp.756-767
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    • 2019
  • This study aimed to evaluate the effect of doneness on the microbial, nutritional, and quality characteristics of 1.5 cm- and 2.0 cm-thick pork neck steaks. Pork neck meat was obtained within 24 h after slaughtering, cut into 1.5 cm- and 2.0 cm-thick slices (n=5), packed in LLD-PE wrap, and stored at $4{\pm}2^{\circ}C$ for 7-10 days until aerobic plate counts (APC) reach 5.51-6.50 Log CFU/g. Then, the pork meat was cooked on a frying pan till it was medium-rare, medium, or well-done. The microbial inhibition rates of the 1.5 cm- and 2.0 cm-thick steak in medium-rare state were 58.26% and 51.70%, respectively, whereas it was 100% for medium-done pork steak of either thickness. The total calories of the 1.5 cm- and 2.0 cm-thick well-done pork steaks were 643.61 kcal/100 g and 675.00 kcal/100 g, respectively, which was higher than that in medium-rare and medium-done steaks. The retention ratios for Fe and K in the well-done steak were significantly lower than those in the medium and medium-rare steak of either thickness (p<0.05). The shear force of the medium-rare and medium steak did not differ, whereas that of the well-done steak was significantly higher than that of the medium-rare steak of either thickness (p<0.05). We observed that the well-done pork steak had tough texture, low mineral content, and high calories. Therefore, consumption of medium and medium-rare pork is more beneficial than that of well-done pork.

The protective effect of methanol extract of Corni Fructus on brain injury caused by unilateral common carotid artery occlusion in mice (산수유(山茱萸) 메탄올 추출물이 편측 경동맥 폐색으로 유도된 생쥐의 허혈성 뇌손상에 미치는 영향)

  • Choi, Na Ri;Jo, Sung Hyeon;Lee, Se-Eun;Lee, Min Ji;Cho, Suin
    • The Korea Journal of Herbology
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    • v.35 no.1
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    • pp.1-8
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    • 2020
  • Objectives : This study was conducted to evaluate the effects of Corni Fructus, the dried fruits of Cornus officinalis Sieb., on unilateral common carotid artery occlusion (UCCAO) in mouse model. Methods : The Corni Fructus used in the experiment was extracted with anhydrous methanol, then filtered and freeze-dried. C57BL/6 mice used in the experiments were conducted left UCCAO surgery to set up UCCAO rodent model for mice. The mice were divided into five groups for evaluate the effect of methanol extract of Corni Fructus (COM) on UCCAO induced ischemic brain injury. The expression levels of nitric oxide in cerebrum and serum, body weight change were measured. To determine the effect of UCCAO and COM administration on brain neurons, morphological changes of the cerebrum through a microscope was conducted. And western blot was performed to confirm the underlying mechanism of neuroprotective effect of COM administration. Results : COM administered UCCAO groups (CO50, CO150, and CO500) had no significant effects on nitric oxide production in ipsilateral hemisphere proteins and sera. The CO500, 500 mg/kg COM administration, attenuated UCCAO-induced p38 inflammatory signaling pathway and inflammatory mediators such as iNOS and COX-2. The CO500 group showed resilient morphological changes of hippocampus neuronal cells about brain damage caused by decreased flow of blood. These group also showed decreased inflammation and cellular stress response in neuronal cells. Conclusions : From these results, COM has a neuroprotective property via moderating inflammatory factors and cellular stress inducing factors in brain cells.

Water and Oil Repellency of Wool Fabric Treated with Nano-type Finishing Agent (Wool 직물의 나노 발수 발유가공)

  • Choi, Bo-Ryun;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.26-34
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    • 2008
  • Wool fabric having high moisture content were treated with fluorocarbon-based water and oil repellent finishing agents by pad-dry-cure system. Three types of finishing agents which were regular-type or nano-type were adapted to compare the surface chemical composition, water and oil repellent property, crease recovery angle, and durability to repeated laundering. From the surface chemical compositions resulted by ESCA and C1s curve-fitting, it was shown that the regular-type finishing agent were easily taken off from the finished wool fabrics after repeated laundering. On the other hand, the fluoroalkyl groups of nano-type finishing agents turned round from fabric surface to fiber internal after repeated laundering. The water repellency of the wool fabrics treated with regular-type agent had a little changes according to the treatment condition changes and sharply decreased with repeated laundering. However, these values when treated with nano-type agents increased with the concentration and cure temperature and were maintained after 20 times laundering. The wool fabrics treated with nano-type agent had a great oil repellency irrespective of treatment conditions. Furthermore, the wrinkle recovery values of the wool fabrics treated with nano-type agents were higher than those of the fabrics treated with regular-type agent and were unchanged after 20 times laundering.

THE EFFECT OF PROESSURE ON THE ELECTRICAL CONDUCTIVITY OF SEA WATER ( II ) -The Activation Energy and the Activation Volume Change- (해수의 전기전도도에 미치는 압력의 영향 ( II ) -활성화에너지와 활성화부피변화-)

  • HWANG Kum-Sho;HWANG Jung-Ui
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.10 no.4
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    • pp.213-220
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    • 1977
  • In this study, physical and chemical properties of sea water were investigated qualitatively from the data measured by means of the conductive method as described in the previous paper. The activation energy, ${\Delta}E$, calculated from the suggested equation describing the electrical conductive property of sea water was about 3.0 to 4.0 Kcal/mole at a given pressure and concentration. The average values of the activation volume change, ${\Delta}V$, over the pressure 1 to 1,200 bars decreased from -1.30 to $-0.27\;cm^3/mole$ as the temperature increased from 10 to $25^{\circ}C$.

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A Study on the Dyeing Property of Polycarboxylic Acid Treated Cotton Fabrics with Chelidonium majus Extracts (애기똥풀 추출액에 대한 Polycarboxylic Acid 처리 면직물의 염색특성 연구)

  • Choi, Kyung-Eun;Kang, Sung-Il;Rhie, Jeon-Sook;Chung, Yong-Sik
    • Korean Journal of Human Ecology
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    • v.9 no.1
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    • pp.43-50
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    • 2006
  • The main colorant of Chelidonium majus extracts is a berberine which shows relatively good dyeability onto silk fabrics in the appropriate dyeing conditions without mordant, But cotton fabrics are difficult to dye with berberine because of the low substantivity the cationic to cellulosic fibers. we treated cotton fabrics using three types of polycarboxylic acid, DL-malic acid, citric acid, 1,2,3,4-butanetetracarboxylic acid(BTCA) to increase dyeability of Chelidonium majus extracts onto cotton fabrics. As a result the cotton fabrics treated with polycarboxylic acid could be dyed with Chelidonium majus extracts and also showed yellow vividly. The dye uptake were increased with increasing the number of carboxy groups. And so dye uptake resulted the largest in the BTCA solutions which have four carboxylic groups in the molecular unit. The optimal dyeing temperature a of Chelidonium majus extracts onto polycarboxylic acid treated cotton fabrics were $60^{\circ}C$. The dye equilibrium was reached 20 minutes after dyeing. Neutral pH of dye solutions showed in higher K/S value than acidic or alkaline conditions. But the colorfastness to washing and light according to polycarboxylic acid treat was not enhance.

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Properties of carbonated green construction materials by changes in processing conditions (공정조건 변화에 따른 탄산화 녹색건자재의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.3
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    • pp.152-160
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    • 2013
  • The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.