• 제목/요약/키워드: surface zeta-potential

검색결과 260건 처리시간 0.023초

Preparation and Surface Charge Characterization of Polystyrene Particles and Powders with Carboxyl and/or Poly(ethylene glycol) Groups

  • Kim, Bae-Joong;Kim, Seong-Hun;Park, Ki-Hong
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.94-94
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    • 2003
  • Cross-linked polystyrene (PS) particles with carboxyl and/or poly(ethylene glycol) units on surface were formed by an emulsifier-free emulsion polymerization using styrene, methacrylic acid (MA), and poly(ethylene glycol) dimethacrylate (PEG-diMMA) at pH 7, and followed by freeze-drying to give the corresponding powders. Monodisperse polymer particles could be obtained at a concentration of PEG-diMMA 1 mol% relative to styrene. Zeta potential of polymer surface was measured to be 91 mV at a polymer of PEG-diMMA 1 mol% and was dropped as the content of MA increased.

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Dyeability of photooxidized meta-aramid fabrics to cationic dyes

  • Dong, Yuanyuan;Jang, Jin-Ho
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2009년도 제41차 학술발표회
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    • pp.79-80
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    • 2009
  • Aramid fabrics were photooxidized by UV/$O_3$ irradiation. The UV irradiation caused the oxygen content of the aramid fabric surface to increase and reduced the surface zeta potential, coupled with improved water wettability. The modified aramid fabrics showed higher affinity to cationic dyes which may be resultd from the newly introduced electrostatic interaction between cationic dyes and anionic dyeing sites on the photooxidized surface layers. Although color fastness to both staining and rubbing were good to excellent, color fastness to shade change was moderate.

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실란 표면 개질된 나노복합막의 염료 분리 특성 (Surface Modification of Nanofiltration Membrane with Silane Coupling Agents for Separation of Dye)

  • 박희민;임지은;김성애;이용택
    • 멤브레인
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    • 제28권6호
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    • pp.414-423
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    • 2018
  • 본 연구에서는 염색 염료 산업의 폐수 처리 및 재활용 공정에 분리막을 적용하고자 실란 커플링제를 이용하여 상용화된 나노복합막을 표면 개질하였다. 실란 커플링제는 말단 관능기가 다른 octyltrimethoxysilane (OcTMS)와 (3-aminopropyl) trimethoxysilane (APTMS)을 사용하였으며, 표면 개질을 통해 염료 분리 및 내오염성을 향상시키고자 하였다. XPS, FE-SEM, EDX 분석을 통하여 막 표면의 화학 구조 변화 및 실란 적층을 확인하였고, AFM 분석을 통해 개질막의 표면 모폴로지를 확인하였다. Zeta potential을 통해 실란 개질 막이 상용막 대비 표면 전하가 중성으로 변하는 것을 확인하였다. 그 결과, OcTMS와 APTMS로 개질한 막의 내오염성은 NE70에 비해 약 2배 이상 향상되었다. 또한, 실란으로 표면 개질한 나노복합막은 음이온 염료(Orange II) 용액에서 약 90% 이상, 양이온 염료(Safranin-O) 용액에서 약 98% 이상의 염료 제거율을 나타내어 양이온 염료 용액 처리에 적합한 것을 확인하였다.

산화구리를 함유하는 전통 세라믹 유약의 항균특성에 관한 연구 (Antibacterial properties of traditional ceramic glazes containing copper oxide)

  • 김응수;최정훈;노형구;한규성;김진호;황광택
    • 한국결정성장학회지
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    • 제29권6호
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    • pp.372-378
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    • 2019
  • 산화구리를 함유하는 전통 세라믹 유약은 황색포도상구균과 대장균에 대해 항균활성을 나타낸다. 환원 분위기에 소결한 모든 시편들은 황색포도상구균과 대장균에 대해 항균활성을 나타내나 산화분위기에서 소결한 일부 시편들만 황색포도상구균과 대장균에 대해 항균활성을 나타내었다. 산화구리를 함유하는 전통 세라믹 유약의 항균기작을 설명하기 위해 유약의 결정상, 미세구조, 이온용출, 표면 제타전위 분석을 실시하였다. 환원 분위기에서 소결한 시편들은 유약층에 Cu 입자들이 형성되는 것을 확인할 수 있다. Cu 용출량은 전체적으로 0.05 ppm 이하이며 가장 많이 용출되는 이온은 Ca 이었다. 산화구리를 3 wt.% 이상 첨가한 모든 시편들은 높은 음극의 표면 제타전위를 나타내었다. 세라믹 유약의 항균활성은 일반적으로 용출되는 양이온들과 연관되어 보이나 산화분위기에서 소결한 시편들의 대장균에 대한 항균활성은 직접적인 연관성이 나타나지 않는다. 세라믹 유약 시편의 표면 제타전위가 이온용출과 더불어 대장균에 대한 항균활성에 보조적 기여를 하는 것으로 보인다.

Synergistic Effect of Reductase and Keratinase for Facile Synthesis of Protein-Coated Gold Nanoparticles

  • Gupta, Sonali;Singh, Surinder P.;Singh, Rajni
    • Journal of Microbiology and Biotechnology
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    • 제25권5호
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    • pp.612-619
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    • 2015
  • We have synthesized gold nanoparticles (GNPs) using chicken feathers (poultry waste) and Bacillus subtilis RSE163. Disulfide reductase and keratinase produced by Bacillus subtilis during the degradation of chicken feather has been used to reduce Au3+ from HAuCl4 precursor to produce gold nanoparticles. The synthesized biogenic GNPs were characterized by UV-visible spectroscopy, transmission electron microscopy (TEM), and zeta potential measurements. Fourier transform infrared (FTIR) spectroscopy indicated the presence of protein capping on synthesized GNPs, imparting multifunctionality to the GNP surface. Furthermore, the nontoxic nature of biogenic GNPs was insured by interaction with Escherichia coli (ATCC11103), where TEM images and enhancement of growth rate of E. coli in log phase signified their nontoxic nature. The results indicate that the synthesis of biocompatible GNPs using poultry waste may find potential applications in drug delivery and sensing.

새로운 수용성(水溶性) 방부방충제(防腐防蟲劑)의 재중(材中) 정착성(定着性)에 관한 계면전기화학적(界面電氣化學的) 특성(特性) (Surface Electrochemical Study on the Fixation Properties of New Water-borne Preservatives in Red Pine)

  • 김영숙
    • Journal of the Korean Wood Science and Technology
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    • 제24권4호
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    • pp.93-99
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    • 1996
  • In order to investigate the extent of fixation of new water-borne preservatives in blocks of pinus densiflora sapwoods the streaming potential through the column with preservative treated wood was measured at various conditions. The rates of leachability of ingredients in the treated wood were estimated by the measurement of electric conductivity of the solution with the leached components. The solution was also analyzed by Atomic absorption spectrophotometer (AA). As a results, the experimental data indicated that the fixation of CCB, CCFZ and ACQ in wood were relatively unstable. The fixation rates of CCB, CCFZ were improved by increasing heat and drying time. The amounts of the leached ingredients were apparently higher in CCB and CCFZ than in CCA, while the rate of leaching of ACQ was not changed at various drying temperature.

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해수의 농도 변화에 따른 bentonite 침전에 대한 유변학적 고찰 (Rheological Study on bentonite Clay Sedimentation with various concentrations of Sea water)

  • 최상원;서호준
    • 한국환경과학회지
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    • 제5권1호
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    • pp.35-41
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    • 1996
  • For studying of coagulation and sedimentation in estuarine clay, we obtained several flow curves with various concentrations of sea water by using Coutte type rotational rheometer. The initial shear stress on high concentration of sea water was observed big, but after this, its value is decreasing with increasing shear rate. The maximum pick of shear stress is decreasing with the decreasing of concentration of sea water The trend is same totally above for viscosity. The sedimentation times with the concentration of sea water vary in $\infty$ ~ 5 minutes. The zeta potential is changed dramatically between 114 and 118 concentration of sea water. That is consistent with the sedimentation graph. From these results, the phenomena of coagulation and sedimentation can be explained with viscoelastic terms on structual formation among particles by the changes of surface potential affected from contacting sea water to dispersed particles.

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티올키토산으로 피복된 EPA(Eicosapentaenoic acid) 함유 리포좀의 제조 및 아토피 감염 쥐에 대한 면역 특성 (Preparation of Thiol-chitosan Coated EPA-containing Liposome and Immune Response in Mouse Model of Atopic Dermatitis)

  • 정효연;김진;이용욱;이기영
    • KSBB Journal
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    • 제25권1호
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    • pp.97-102
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    • 2010
  • The enhancement of immunity for atopic dermatitis with application of eicosapentaenoic acid (EPA)-loaded liposome was evaluated on NC/Nga mice. The EPA-loaded liposome was coated with thiol-chitosan. The liposomes were characterized with transmission electron microscopy (TEM), surface zeta potential & particle size analyzer (Zeta-PSA) and differential scanning calorimetry (DSC). The loading efficiency of EPA in the liposome was about 4.7%. The particle size of the EPA-Ioaded liposome was about 230 nm. The values of Immunoglobulin E (IgE), interleukin-4 (IL-4), and tumor necrosis factor-$\alpha$ (TNF-$\alpha$) were reduced significantly with application of the EPA-loaded liposome. The interferon-$\gamma$ (IFN-$\gamma$) value was increased with the application effect. It is concluded that EPA loaded liposome have immunity advancing effects in mouse model of atopic dermatitis.

W CMP 공정에서의 연마패드표면 안정화 상태와 그 개선 (Stability and Improvement of Polishing Pad in W CMP)

  • 박재홍;키노시타 마사하루;요시다 코이치;신이치 마츠무라;정해도
    • 한국전기전자재료학회논문지
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    • 제20권12호
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    • pp.1027-1033
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    • 2007
  • In this research, the polishing pad for W CMP has been analyzed to understand stabilization of polishing performance. For stabilization of process, the polishing pad condition is one of important factors. The polishing pad plays a key role in polishing process, because it contact with reacted surface of wafer[1]. The physical property of pad surface is ruled by conditioning tool which makes roughness and profile of pad surface. Pad surface affects on polishing performance such as RR(Removal Rate) and uniformity in CMP. The stabilized pad surface has stable roughness. And its surface has high level of wettability which can increase the probability of abrasive adhesion on pad. The result of this research is that the reduction of break-in and dummy polishing process were achieved by artificial machining to make stable pad surface. In this research, urethane polishing pad which is named IC pad(Nitta-Haas Inc.) and has micro pore structure, is studied. Because, this type of pad is the most conventional type.

홍삼농축액 함유 유화액의 유화특성에 관한연구 (Emulsifying Properties of Concentrated Red Ginseng Extract: Influence of Concentration, pH, NaCl)

  • 류관모;장현호;이의석;이기택;홍순택
    • 한국응용과학기술학회지
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    • 제34권3호
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    • pp.504-514
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    • 2017
  • 본 연구에서는 홍삼농축액의 유화특성을 조사하였다. 먼저, 홍삼농축액의 표면활성능을 조사하였으며, 이어서 홍삼농축액 유화액을 제조하고 이의 이화학적 성질을 조사하였다. 홍삼농축액의 물/기름 계면에서 계면장력은 홍삼농축액 농도의 증가와 더불어 감소하였다. 홍삼농축액을 이용하여 유화액을 제조한 결과, 첨가 농도의 증가와 더불어 유화 지방구 크기는 감소하였으며, 홍삼농축액 농도가 3.5 wt% 이상일 경우 일정한 지방구 크기($d_{43}$$0.39{\mu}m$)의 안정한 유화액을 형성하였고, separation analyzer($LUMiFuge^{(R)}$)를 이용한 유화안정도 평가 결과에서도 이와 유사한 안정도 변화 경향을 확인할 수 있었다. 또한 홍삼농축액 유화액 중 지방구 크기는 pH 및 NaCl 농도변화에 의존하였는데, pH가 감소함에 따라 지방구 크기는 증가하고 음의 제타전위 값[-67.0 mV (pH 9.0) ${\rightarrow$ + 2.1 mV (pH 2.0)]은 낮아지는 경향을 보였으며, NaCl 농도(0.1 M ${\rightarrow$ 0.5 M)가 높을수록 지방구 크기는 증가하였다. 본 실험을 통해 홍삼농축액의 유화능을 확인할 수 있었다.