• Title/Summary/Keyword: surface washing

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Optimization of Bismuth-Based Inorganic Thin Films for Eco-Friend, Pb-Free Perovskite Solar Cells (친환경 Pb-Free 페로브스카이트 태양전지를 위한 비스무스 기반의 무기 박막 최적화 연구)

  • Seo, Ye Jin;Kang, Dong-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.117-121
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    • 2018
  • Perovskite solar cells have received increasing attention in recent years because of their outstanding power conversion efficiency (exceeding 22%). However, they typically contain toxic Pb, which is a limiting factor for industrialization. We focused on preparing Pb-free perovskite films of Ag-Bi-I trivalent compounds. Perovskite thin films with improved optical properties were obtained by applying an anti-solvent (toluene) washing technique during the spin coating of perovskites. In addition, the surface condition of the perovskite film was optimized using a multi-step thermal annealing treatment. Using the optimized process parameters, $AgBi_2I_7$ perovskite films with good absorption and improved planar surface topography (root mean square roughness decreased from 80 to 26 nm) were obtained. This study is expected to open up new possibilities for the development of high performance $AgBi_2I_7$ perovskite solar cells for applications in Pb-free energy conversion devices.

The Variation of Mechanical Properties with Directions of PET High Stretch Fabrics (PET 고신축사 직물의 방향에 따른 역학적 특성의 변화)

  • 김영민;박종범;김주애;조현혹
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.1
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    • pp.160-167
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    • 2002
  • Stretch fabrics are wide-spread for high performance clothing use with requirements of fitness and adaptability to human's movement. A newly developed 100% PET high stretch fabric has excellent properties with respect to stretch, softness, bulkiness, and apparent volume compared to PET filament fabrics. The 100% PET high stretch fabric shows advantages of a dimensional stability, dye and agent adaptability in dying and finishing process, a property of stretch recovery after washing and lower production cost than that of spandex fabric. KES-FB was used to measure mechanical properties to various directions of the fabric. This study centered on whether the 100% PET high stretch fabric is suitable to quality and shape retention of fabric by testing several properties including tensile, compression, shear, bending and surface characteristic to various measuring directions. Tensile linearity showed maximum value at $0^{\circ}$ in plain and $90^{\circ}$ in twill. Shear Stiffness of plain and twill showed maximum value equally at $45^{\circ}\;and\;135^{\circ}$. Bending rigidity showed maximum value at $0^{\circ}$ in plain and $45^{\circ}$ twill. Mean deviation of MIU showed maximum value at $0^{\circ}\;and\;90^{\circ}$ in plain and $135^{\circ}$ in twill.

Natural Dyeing of Chitosan Crossinked Cotton Fabrics(III) - Amur cork tree - (키토산 가교 처리된 면직물의 천연염색에 관한 연구(III) - 황벽을 중심으로 -)

  • Kwak, Mi-Jung;Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.10 no.4
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    • pp.544-551
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    • 2008
  • In this study, the colorants of Amur cork tree were extracted with boiling water. Chitosan crosslinked cotton fabrics have been dyed with aqueous extract of Amur cork tree and their dyeabilities on the fabrics were studied. Additionally the fastness to washing and light were also investigated. Cotton fabrics were treated with a crosslinking agent epichlorohydrin in the presence of chitosan to provide the cotton fabrics the dyeing properties of natural dye(Amur cork tree) by the chemical linking of chitosan to the cellulose structure. This process was applied by means of the conventional mercerizing process. The chitosan finishing and durable press finishing of the cotton fabrics occurred simultaneously in the mercerization bath. On the surface color change, the fabric of no-chitosan finished and no-mordanted has greenish yellow. The more crosslinked chitosan on cotton fabrics has the more turned down greenish on the surface color, as increasing the concentration of chitosan, greenish color turn down to the yellow close the 90o hue angle. In all sorts of fabrics, dyeability(K/S) is slightly affected by the number of manufacturing process and the concentration of chitosan. But only mercerized cotton fabric has higher dyeability (K/S) than mordant treated cotton fabrics. Wash fastness has little different results by each condition, but almost similar values. Light fastness was improved with chitosan treatment on cotton fabric.

Geometric and Mechanical Characteristics of the Boxthorn Berry (구기자의 품종별 기하하적 및 기계적 특성)

  • Kim, Woong;Lee, Seung-Kee;Cho, Sung-Ho;Woong, Han Jae
    • The Korean Journal of Community Living Science
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    • v.25 no.3
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    • pp.383-388
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    • 2014
  • This study was examined the physical characteristics (geometry, yield strength, thousand-seeds weight, true density, and moisture content) required for mechanization-related technologies such as (harvesting, washing, transport, and drying). Large differences in the size and shape of boxthorn berries(Jangmyeong, Bullo, Chungmyeong, and Hokwang) are used to analyze these physical properties. The average diameter, volume, surface area, and sphericity rate are calculated using long and short diameters of the boxthorn berry according to its variety. Hokwang has the largest measured surface area, and Bullo, the smallest. Average yield strength is 1.78 kPa and the mechanical pressure of soft boxthorn berries is not more than 1 kPa. Bullo has the highest true density. The optimum drying time for the measurement of moisture content is 4 hours at the drying temperature of $100^{\circ}C$.

Cutting Characteristics of Dry Turning Using Compressed Air (압축공기를 이용한 건식 선삭가공의 절삭특성)

  • Song Chun-Sam;Kim Joo-Hyun
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.1
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    • pp.8-14
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    • 2005
  • The purposes of using cutting fluid during cutting have been cooling, lubricating, chip washing, and anti-corroding. However, the present manufacturing industry restricts the use of cutting fluid because cutting fluid contains poisonous substances which are harmful to the human body. Therefore dry cutting becomes an unavoidable assignment and a lot of researches have studied cutting methods without using cutting fluid. Because dry turning is a continuous work, tools life is reduced by continuous heat generation and surface gets rough due to reduced lubrication, so it is important to consider these situations. In this paper, the way of selecting the optimal machining condition by the minimum number of experiments and the effectiveness of using compressed air in high hardness materials through Taguchi method have been found. Dry cutting using compressed air showed better cutting characteristics than normal dry cutting with respect to by cutting force, tool wear, and surface roughness. Also, the optimal machining condition f3r dry cutting using compressed air could be selected through Taguchi method.

A Study on the Grinding Characteristics according to Oil Mist Supply Method (오일 미스트 분사 방법에 따른 연삭특성)

  • 허남환;이석우;최헌종
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.254-257
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    • 2002
  • As the large Coolant amount used of a machine holds mass serious trouble recently, an environment pollution is increased, and a machine is conquering large specific gravity in an empty cost plane. It is the stage that must reexamine the parts washing that processing is later with this current way or a problem of a liquid waste treatment back. The environmental problems by using coolant demanded the new cooling methods. As one of them, the studies on the grinding with compressed cold air and oil mist have been done. The cooling method using compressed cold air was effective through going down the temperature of compressed air supplied below -$25^{\circ}C$ and increasing the amount of compressed cold air, but had not enough cooling effect due to the low performance of lubrication. Therefore, the cooling methods using oil mist newly were suggested. This method can satisfy both cooling effect and lubrication with only small amount of coolant, also have the benefit in the point of decreasing the environmental pollution. This paper focused on analyzing the grinding characteristics of the cooling method using oil mist. The grinding test according to compressed cold air and oil mist supply direction were done.

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Novel Coloration of Cotton Fabrics by UV-induced Phtografting of Reactive Black 5 and Acrylic acid

  • Dong, Yuanyuan;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.1
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    • pp.11-20
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    • 2011
  • UV-induced surface copolymerization has been widely applied as a simple, useful and versatile approach to improve the surface properties of textiles. C.I. Reactive Black 5 and acrylic acid (AA) were continuously grafted onto cotton by UV irradiation. The photografting may occur by the copolymerization of AA with the vinylsulfone reactive dye which photochemically converted from the bissulfatoethylsulfone reactive group. The graft yield and color yield were influenced by UV energy, the dye and photoinitiator concentrations, a mole ratio of AA to dye, and pH. The coloration of cotton fabrics having a K/S of 7.0 can be obtained under a UV irradiation energy of 15$J/cm^2$ by the photografting of an aqueous alkaline formulation of 6% dye concentration containing 3% photoinitiator concentration on the weight of monomers, and a 3:1 mole ratio addition of AA to the dye. Furthermore, the photochemically dyed cotton fabrics showed comparable washing (staining) and rubbing fastness to conventional reactive dyeing method except shade change in the wash fastness and light fastness.

Preparation and Characterization of Crosslinked Sodium Alginate Membranes for the Dehydration of Organic Solvents

  • Goo, Hyung Seo;Kim, In Ho;Rhim, Ji Won;Golemme, Giovanni;Muzzalupo, Rita;Drioli, Enrico;Nam, SangYong
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.55-60
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    • 2004
  • In recent years, an increasing interest in membrane technology has been observed in chemical and environmental industry. Membrane technology has advantages of low cost, energy saving and environmental clean technology comparing to conventional separation processes. Pervaporation is one of new advanced membrane technology applied for separation of azeotropic mixtures, aqueous organic mixtures, organic solvent and petrochemical mixtures. Sodium alginate composite membranes were prepared for the enhancement of long-term stability of pervaporation performance of water-ethanol mixture using pervaporation. Sodium alginate membranes were crosslinked with CaCl$_2$ and coated with polyelectrolyte chitosan to protect washing out of calcium ions from the polymer. The surface structures of PAN and hydrolysed PAN membrane were confirmed by ATR Fourier transform infrared (FT-IR). A field emission scanning electron microscopy (FE-SEM; Jeol 6340F) operated at 15 kV. Concentration profiles for Ca in the membrane surface and membrane cross-section were taken by an energy dispersive X-ray (EDX) analyser (Jeol) attached to the field emission scanning electron microscopy (Jeol 6340F). Pervaporation experiments were done with several operation run times to investigate long-term stability of the membranes.

Characterization of a Blend-Biosurfactant of Glycolipid and Lipopeptide Produced by Bacillus subtilis TU2 Isolated from Underground Oil-Extraction Wastewater

  • Cheng, Fangyu;Tang, Cheng;Yang, Huan;Yu, Huimin;Chen, Yu;Shen, Zhongyao
    • Journal of Microbiology and Biotechnology
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    • v.23 no.3
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    • pp.390-396
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    • 2013
  • Biosurfactants have versatile properties and potential industrial applications. A new producer, B. subtilis TU2, was isolated from the underground oil-extraction wastewater of Shengli Oilfield, China. Preliminary flask culture showed that the titer of biosurfactant obtained from the broth of TU2 was ~1.5 g/l at 48 h (718 mg/l after purification), with a reduced surface tension of 32.5 mN/m. The critical micelle concentration was measured as 50 mg/l and the surface tension maintained stability in solution with 50 g/l NaCl and 16 g/l $CaCl_2$ after 5 days of incubation at $70^{\circ}C$. FT-IR spectra exhibited the structure information of both glycolipid and lipopeptide. MALDI-TOF-MS analyses confirmed that the biosurfactant produced by B. subtilis TU2 was a blend of glycolipid and lipopeptide, including rhamnolipid, surfactin, and fengycin. The blended biosurfactant showed 86% of oil-washing efficiency and fine emulsification activity on crude oil, suggesting its potential application in enhanced oil recovery.

Application of SWMM for Management of the Non-point Source in Urban Area -Case Study on the Pohang City- (도시지역 비점오염원 관리를 위한 SWMM의 적용 -포항시를 대상으로-)

  • Lee, Jae-Yong;Jang, Seong-Ho;Park, Jin-Sik
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.247-254
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    • 2008
  • Non-point source pollution that originates from surface applied chemicals in either liquid or solid form is a part of urban activities and it appears in the surface runoff caused by rainfall. This study investigates the characteristics of non point source pollution in relation to storm events and the first washing effect in the Study area, which is comprised of different land use types. Then, a Best Management Practices (BMP) model, for urban areas, is applied with the Storm water Management Model (SWMM) Windows Interface which was developed by the EPA in the USA. During the storm event analysis of the hydrographic and pollutographic data showed that the peak of pollutants concentration was within the peak flow, 30 to 60 minute into the storm event in the Study area. The results of simulation using SWMM Windows Interface, Structure Techniques as applied in the study were highly efficient for removal of pollutants. Predicted removal efficiency was 26.0% for SS, 22.1 for BOD, 24.1% for COD, 20.6% for T-N, and 21.6% for T-P, respectively.