• Structural Engineering and Mechanics
• /
• 제19권5호
• /
• pp.567-580
• /
• 2005

Numerous tests on concrete structure members under local pressure demonstrated that the compressive strength of concrete at the loaded surface is increased by the confinement effect provided by the enveloping concrete. Even though most design codes propose specific criteria for preventing bearing failure, they do not take into consideration size effect which is an important phenomenon in the fracture mechanics of concrete/reinforced concrete. In this paper, six series of square prism concrete blocks with three different depths (size range = 1:4) and two different height/depth ratios of 2 and 3 are tested under concentrated load. Ultimate loads obtained from the test results are analysed by means of the modified size effect law (MSEL). Then, a prediction formula, which considers effect of both depth and height on size effect, is proposed. The developed formula is compared with experimental data existing in the literature. It is concluded that the observed size effect is in good agreement with the MSEL.

• Nano
• /
• 제13권10호
• /
• pp.1850114.1-1850114.7
• /
• 2018

Here we report an optimized hot-injection method and a phase transfer strategy for the synthesis of water-soluble $CuInS_2$ QDs with desired properties. The structure and morphology studies demonstrate that the resulting QDs are $CuInS_2$ tetragonal phase with well-defined facets. It is also found that the crystal size gradually increases with the increase of reaction temperature, while the surface of QDs with pre- and post-phase transfer is functionalized with hydrophobic and hydrophilic ligands, respectively. Spectroscopy measurements reveal the size-dependent optical properties of $CuInS_2$ QDs, demonstrating the quantum confinement effect in this system.

• 한국재료학회지
• /
• 제19권12호
• /
• pp.637-643
• /
• 2009

In this study, we analyzed the effect of silicon oxynitride matrix on the optical properties of Au nanoparticles dispersed on composite film and explored the effectiveness of the silicon in fine tuning the refractive index of the composite film for applications in optical waveguide devices. The atomic fraction of nitrogen in $SiO_xN_y$ films was controlled by varying the relative flow ratio of nitrogen gas in reactive sputtering and was evaluated optically using an effective medium theory with Bruggeman geometry consisting of a random mixture between $SiO_2$ and $Si_3N_4$. The Au nanoparticles were embedded in the $SiO_xN_y$ matrix by employing the alternating deposition technique and clearly showed an absorption peak due to the excitation of surface plasmon. With increasing nitrogen atomic fraction in the matrix, the surface plasmon resonance wavelength shifted to a longer wavelength (a red-shift) with an enhanced resonance absorption. These characteristics were interpreted using the Maxwell-Garnett effective medium theory. The formation of a guided mode in a slab waveguide consisting of 3 $\mu$m thick Au:$SiO_xN_y$ nanocomposite film was confirmed at the telecommunication wavelength of 1550 nm by prism coupler method and compared with the case of using $SiO_2$ matrix. The use of $SiO_xN_y$ matrix provides an effective way of controlling the mode confinement while maintaining or even enhancing the surface plasmon resonance properties.

• 대한금속재료학회지
• /
• 제56권12호
• /
• pp.900-909
• /
• 2018

A $ZnO/TiO_2$ photocatalyst decorated with PbS quantum dots (QDs) was synthesized to achieve high photocatalytic efficiency for the decomposition of dye in aqueous media. A $TiO_2$ porous layer, as a precursor photocatalyst, was fabricated using micro-arc oxidation, and exhibited irregular porous cells with anatase and rutile crystalline structures. Then, a ZnO-deposited $TiO_2$ catalyst was fabricated using a zinc acetate solution, and PbS QDs were uniformly deposited on the surface of the $ZnO/TiO_2$ photocatalyst using the successive ionic layer adsorption and reaction (SILAR) technique. For the PbS $QDs/ZnO/TiO_2$ photocatalyst, ZnO and PbS nanoparticles are uniformly precipitated on the $TiO_2$ surface. However, the diameters of the PbS particles were very fine, and their shape and distribution were relatively more homogeneous compared to the ZnO particles on the $TiO_2$ surface. The PbS QDs on the $TiO_2$ surface can induce changes in band gap energy due to the quantum confinement effect. The effective band gap of the PbS QDs was calculated to be 1.43 eV. To evaluate their photocatalytic properties, Aniline blue decomposition tests were performed. The presence of ZnO and PbS nanoparticles on the $TiO_2$ catalysts enhanced photoactivity by improving the absorption of visible light. The PbS $QDs/ZnO/TiO_2$ heterojunction photocatalyst showed a higher Aniline blue decomposition rate and photocatalytic activity, due to the quantum size effect of the PbS nanoparticles, and the more efficient transport of charge carriers.

• Smart Structures and Systems
• /
• 제14권5호
• /
• pp.811-830
• /
• 2014

A numerical study has been carried out to simulate an innovative monitoring procedure to detect and localize damage in reinforced concrete beams retrofitted with carbon fiber reinforced polymer (CFRP) unidirectional laminates. The main novelty of the present simulation is its ability to conduct the electromechanical admittance monitoring technique by considerably compressing the amount of data required for damage detection and localization. A FEM simulation of electromechanical admittance-based sensing technique was employed by applying lead zirconate titanate (PZT) transducers to acquire impedance spectrum signatures. Response surface methodology (RSM) is finally adopted as a tool for solving inverse problems to estimate the location and size of damaged areas from the relationship between damage and electromechanical admittance changes computed at PZT transducer surfaces. This statistical metamodel technique allows polynomial models to be produced without requiring complicated modeling or numerous data sets after the generation of damage, leading to considerably lower cost of creating diagnostic database. Finally, a numerical example is carried out regarding a steel-reinforced concrete (RC) beam model monotonically loaded up to its failure which is also retrofitted by a CFRP laminate to verify the validity of the present metamodeling monitoring technique. The load-carrying capacity of concrete is predicted in the present paper by utilizing an Ottosen-type failure surface in order to better take into account the passive confinement behavior of retrofitted concrete material under the application of FRP laminate.

• 한국표면공학회지
• /
• 제43권3호
• /
• pp.121-126
• /
• 2010

The PS(porous Si) were fabricated with different anodization time and current density. The structural and optical properties of PS were investigated by SEM(scanning electron microscopy), AFM(atomic force microscopy), and PL(photoluminescence). It is found that the pore size and surface roughness of PS are proportional to the current density. The PL spectra show that the PL peak position is red-shifted with increasing anodization time. This behavior corresponds to the change of pore size which is consistent with the quantum confinement model. The FWHM(full width at half maximum) of PL peak is decreased from 97 to 51 nm and the PL peak position is blue-shifted with increasing current density up to 10 mA/$cm^2$. The PL peak intensity of the PS fabricated under 1 mA/$cm^2$ is the highest among samples.

• Geomechanics and Engineering
• /
• 제24권4호
• /
• pp.323-335
• /
• 2021

This paper aims to estimate the range of the excavation damaged zone (EDZ) formation caused by the tunnel boring machine (TBM) advancement through dynamic three-dimensional large deformation finite element analysis. Large deformation analysis based on Coupled Eulerian-Lagrangian (CEL) analysis is used to accurately simulate the behavior during TBM excavation. The analysis model is verified based on numerous test results reported in the literature. The range of the formed EDZ will be suggested as a boundary under various conditions - different tunnel diameter, tunnel depth, and rock type. Moreover, evaluation of the integrity of the tunnel structure during excavation has been carried out. Based on the numerical results, the apparent boundary of the EDZ is shown to within the range of 0.7D (D: tunnel diameter) around the excavation surface. Through series of numerical computation, it is clear that for the rock of with higher rock mass rating (RMR) grade (close to 1st grade), the EDZ around the tunnel tends to increase. The size of the EDZ is found to be direct proportional to the tunnel diameter, whereas the depth of the tunnel is inversely proportional to the magnitude of the EDZ. However, the relationship between the formation of the EDZ and the stability of the tunnel was not found to be consistent. In case where the TBM excavation is carried out in hard rock or rock under high confinement (excavation under greater depth), large range of the EDZ may be formed, but less strain occurs along the excavation surface during excavation and is found to be more stable.

• 분석과학
• /
• 제20권5호
• /
• pp.413-418
• /
• 2007

방사선 방법에 의해 실리카 나노입자에 CdS 나노입자를 코팅하였다. TEM분석결과, $SiO_2$ 나노입자 표면에 CdS의 입자의 크기는 대략 20 nm임을 확인 하였다. 또한, XRD 분석결과 결정체 화합물임을 확인하였다. PL 분석결과 PVP-CdS 나노입자와 $SiO_2$@CdS 복합체의 경우, 방출특성이 상당히 다르다는 것이 확인되었다. PVP-CdS의 경우, 방출스펙트럼이 550 nm-600 nm 에서 나타나고, $SiO_2$@CdS의 방출스펙트럼의 경우 단파장 이동함을 확인하였다. 또한 새로운 피이크 (450 nm) 나타남을 확인하였는데, 이는 CdS 의 유발양자 제한 효과에 의한 것으로 사료된다.

• 한국재료학회지
• /
• 제18권12호
• /
• pp.640-644
• /
• 2008

ZnO/ZnS core/shell nanocrystals (${\sim}5-7\;nm$ in diameter) with a size close to the quantum confinement regime were successfully synthesized using polyol and thermolysis. X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) analyses reveal that they exist in a highly crystalline wurtzite structure. The ZnO/ZnS nanocrystals show significantly enhanced UV-light emission (${\sim}384\;nm$) due to effective surface passivation of the ZnO core, whereas the emission of green light (${\sim}550\;nm$) was almost negligible. They also showed slight photoluminescence (PL) red-shift, which is possibly due to further growth of the ZnO core and/or the extension of the electron wave function to the shell. The ZnO/ZnS core/shell nanocrystals demonstrate strong potential for use as low-cost UV-light emitting devices.

• Wind and Structures
• /
• 제12권1호
• /
• pp.49-61
• /
• 2009

A method is presented to estimate the form drag and the base pressure on a triangular cylinder in the presence of blockage effect. The Strouhal number, which is found to increase with the flow constriction experimentally by Ramamurthy & Ng (1973), may be decoupled from the blockage effect when re-defined by using the velocity at flow separation and a theoretical wake width. By incorporating this wake width into the momentum equation by Maskell (1963) for the confined flow, a relationship between the form drag and the base pressure is derived. Independently, the experimental data of surface pressure from Ramamurthy & Lee (1973) are found to be independent of the blockage effect when expressed in terms of a modified pressure coefficient involving the pressure at separation. Using the potential flow model by Parkinson & Jandali (1970) and its subsequent development in Yeung & Parkinson (2000) for the unconfined flow, a linear relation between the pressure at separation and the form drag is formulated. By solving the two equations simultaneously with a specified blockage ratio and an apex angle of the triangular cylinder, the predictions of the drag and the base pressure are in reasonable agreement with experimental data. A new theoretical relationship for the Strouhal number, pressure drag coefficient and base pressure proposed in this study allows the confinement effect to be appropriately taken into consideration. The present approach may be extended to three-dimensional bluff bodies.