• Title/Summary/Keyword: surface charge

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DYNAMIC SIMULATION MODEL OF A HYBRID POWERTRAIN AND CONTROLLER USING CO-SIMULATION-PART II: CONTROL STRATEGY

  • Cho, B.;Vaughan, N.D.
    • International Journal of Automotive Technology
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    • v.7 no.7
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    • pp.785-793
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    • 2006
  • The topic of this study is the control strategy of a mild hybrid electric vehicle (HEV) equipped with a continuously variable transmission (CVT). A brief powertrain and vehicle configuration is introduced followed by the control strategy of the HEV with emphasis on two key parts. One of them is an ideal operating surface (IOS) that operates the CVT powertrain optimally from the viewpoint of the tank-to-wheel efficiency. The other is a charge sustaining energy management to maintain the battery state of charge (SOC) within an appropriate level. The fuel economy simulation results of the HEV over standard driving cycles were compared with those of the baseline vehicle. Depending on the driving cycle, 1.3-20% fuel saving potential is predicted by the mild hybridisation using an integrated starter alternator (ISA). The detailed energy flow analysis shows that the majority of the improvement comes from the idle stop function and the benefits for electrical accessories. Additionally, the differences between the initial and the final SOC are in the range $-1.0{\sim}+3.8%$ in the examined cycle.

Effect of Annealing Temperature with Silver Nanoparticles Incorporation on the Electronic Structure of Poly (3, 4-ethylenedioxythiphene) : poly (styrenesulfonate) Film (은 나노입자가 함침된 Poly (3, 4-ethylenedioxythiphene) : poly (styrenesulfonate)필름의 전자 구조상태에 미치는 열처리효과 연구)

  • Wang, Seok-Joo;Lee, Cho-Young;Park, Hyung-Ho
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.503-506
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    • 2008
  • The effect of silver nanoparticles (NPs) incorporation on the electronic properties of poly (3, 4-ethylenedioxythiphene) : poly(styrenesulfonate) (PEDOT : PSS) films was investigated. The surface of silver NPs was stabilized with trisodium citrate to control the size of silver NPs and prevent their aggregation. We obtained ca. 5 nm sized silver NPs and dispersed NPs in PEDOT : PSS solution. Sheet resistance, surface morphology, bonding state, and work function values of the PEDOT : PSS films were modified by silver NPs incorporation as well as annealing temperature. Sodium in silver NPs solution could lead to a decrease of work function of PEDOT : PSS; however, large content of silver NPs have an effect on the increase in work function, resulting from charge localization on the silver NPs and a decrease in the number of charge-trapping-related defects by chemical bond formation.

An Experimental Study on the Oxidation Process of Silicon (실리콘 산화공정에 대한 실험적 고찰)

  • 최연익;김충기
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.16 no.1
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    • pp.26-32
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    • 1979
  • Dry oxidation and wet oxidation processes of silicon have been examined experimentally. The oxidation temperatures were 1.10$0^{\circ}C$, 1.15$0^{\circ}C$, and 1.200 $^{\circ}C$, and oxygen flow rate was changed from 0.2 liter/min to 2.8 liter/min. From the experimental measurements, oxidation temperaturel time and oxygen flow rate have been tabutated for oxide layers 0.1$\mu$ - 1.0$\mu$ in thickness. The quality of the grown oxide layer has been investigated In terms of the dielectric constant, breakdown voltage, fixed surface charge densify (Qss/q) and mobile charge density (Q /q). From these measurements, it is concluded that the quality of the oxide layer is sufficient to expect the normal operation of MOS transistors.

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Fabrication of Hemoglobin/Silver Nanoparticle Heterolayer for Electrochemical Signal-enhanced Bioelectronic Application

  • Lee, Taek;Yoon, Jinho;Choi, Jeong-Woo
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.556-560
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    • 2017
  • A hemoglobin/silver nanoparticle heterolayer was fabricated for bioelectronic device with electrochemical signal-enhancement effect. As a device element, a hemoglobin, the metalloprotein, contained the heme group that showed the redox property was introduced for charge storage element. For electron transfer facilitation, a silver nanoparticle was introduced for electrochemical signal facilitation, the hemoglobin was immobilized onto Au substrate using chemical linker 6-mercaptohexanoic acid (6-MHA). Then, the silver nanoparticle was immobilized onto fabricated hemoglobin/6-MHA heterolayers by layer-by-layer (LbL) method. The surface morphology and surface roughness of fabricated heterolayer were investigated by atomic force microscopy (AFM). The redox property of hemoglobin/silver nanoparticle heterolayer was investigated by a cyclic voltammetry (CV) experiment for obtaining an oxidation potential and reduction potential. Moreover, for the assessing charge storage function, a chronoamperometry (CA) experiment was conducted to hemoglobin/silver nanoparticle-modified heterolayer electrode using oxidation and reduction potentials, respectively. Based on the results, the fabricated hemoglobin/silver nanoparticle heterolayer showed that an increased charge storage effect compared to hemoglobin monolayer-modified electrode.

Analysis on particle deposition onto a heated, horizontal free-standing wafer with electrostatic effect (정전효과가 있는 가열 수평웨이퍼로의 입자침착에 관한 해석)

  • Yoo, Kyung-Hoon;Oh, Myung-Do;Myong, Hyon-Kook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.10
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    • pp.1284-1293
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    • 1997
  • The electrostatic effect on particle deposition onto a heated, Horizontal free-standing wafer surface was investigated numerically. The deposition mechanisms considered were convection, Brownian and turbulent diffusion, sedimentation, thermophoresis and electrostatic force. The electric charge on particle needed to calculate the electrostatic migration velocity induced by the local electric field was assumed to be the Boltzmann equilibrium charge. The electrostatic forces acted upon the particle included the Coulombic, image, dielectrophoretic and dipole-dipole forces based on the assumption that the particle and wafer surface are conducting. The electric potential distribution needed to calculate the local electric field around the wafer was calculated from the Laplace equation. The averaged and local deposition velocities were obtained for a temperature difference of 0-10 K and an applied voltage of 0-1000 v.The numerical results were then compared with those of the present suggested approximate model and the available experimental data. The comparison showed relatively good agreement between them.

The Effects of the Surfactant Type on the Nanofluids Stability (계면활성제 특성에 따른 나노입자 분산안정도 향상 연구)

  • Kang, Chi-Hoon;Hong, Sung-Wook;Kang, Yong-Tae;Koo, June-Mo
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.275-280
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    • 2008
  • The effects of the surfactant type, i.e., CTAB(cationic), SDS(anionic), and GA(polymeric), on the stability of 0.1 vol.% $Al_2O_3$ nanofluids were investigated. The changes in size and zeta potential of nanoparticles in nanofluids with pH, surfactant concentration, and time were experimentally observed. The nanofluids adding CTAB, which ionizes of the same charge with the bare particle surface, was found to have the best stability regardless of the surfactant concentration, whereas those with SDS became unstable under low surfactant concentration conditions, i.e. lower than the critical micellel concentration(CMC), before the charge reversal occurred. With higher SDS concentration over CMC, they became stable. Gum Arabic, which had been used often to stabilize the nanofluids, was also tested. In result, it was found that the type and concentration of surfactants to add should be selected considering pH and the sign of the bare particle surface charge.

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In-depth Investigation on Interfacial Resistance of Stainless Steel by Using Dynamic Electrochemical Impedance Spectroscopy (Dynamic Electrochemical Impedance Spectroscopy를 이용한 스테인리스 강의 계면 저항 분석)

  • Heo, Jung-Ho;Lee, Yong-Heon;Shin, Heon-Cheol
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.644-651
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    • 2009
  • The passivation (or deactivation) of a metal surface during oxide film formation has been quantitatively explored for a ferritic stainless steel by using dynamic electrochemical impedance spectroscopy (DEIS). For this purpose, the electrochemical impedance spectra were carefully examined as a function of applied potential in the active nose region of the potentiodynamic polarization curve, to separate the charge transfer resistance and oxide film resistance. From the discrepancy in the potential dependence between the experimental charge transfer resistance and the semi-empirically expected one, the degree of passivation could be quantitatively estimated. The sensitivity of passivation of the steel surface to anodic potential, which might be the measure of the quality of the oxide film formed under unit driving force or over-potential, decreased by 31% when 3.5 wt% NaCl was added to a 5 wt% $H_2SO_4$ solution.

Eloctrostatic Electrification Properties of Silicone Rubber in the Presence of Pt Flame Retardant (백금 난연제에 의한 실리콘 고무의 정전기 대전 특성)

  • Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.5
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    • pp.494-498
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    • 2022
  • In this study, SiO2 20 phr, ATH 70 phr, and platinum flame retardant were mixed with raw silicone rubber and -10 kV was applied to measure electrostatic charge attenuation voltage, surface resistance, and volume resistance, and the following conclusions were obtained. When the platinum flame retardant was 0 phr, the humidity 74.6% and the temperature was 21.8℃, the potential was half-reduced to 0.63 kV, 0.57 kV, and 0.44 kV when the applied voltage was changed from -10 kV to -8 kV, and the time halved to 50% was increased to 2.40 seconds, 2.47 seconds, and 2.61 seconds. It was confirmed that as the platinum flame retardant increased from 0.1 to 0.3 phr, the potential half-reduced to 0.67 kV, 0.60 kV, and 0.595 kV decreased, and the charge potential attenuation time half-reduced to 50% decreased to 3.44 seconds, 1.78 seconds, and 1.60 seconds. It was confirmed that the surface resistance increased as the humidity decreased, and the volume resistance decreased as the platinum flame retardant increased.

Preparation of Talc-Silica Composites by Controlling Surface Charge Behavior (표면전하 거동 조절을 이용한 탈크-실리카 복합체의 제조)

  • Yun, Ki-Hoon;Park, Min-Gyeong;Moon, Young-Jin;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.116-124
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    • 2017
  • A plate-type inorganic pigment complex was manufactured in a manner that treats the surface of the complex by adjusting zeta potential between talc, an inorganic pigment used as a material for color cosmetics, and hydrophobic silica. Talc, which is usually used in the prescription of color cosmetics, is a plate-type, white-colored inorganic substance with good application and spreadability to skin. Furthermore, it features excellent dispersibility and extensibility as well as outstanding heat tolerance, light stability, and chemical resistance. In general, silica contributes to durable makeup and stabilized formulation. This paper covers a process of manufacturing an inorganic pigment complex, where hydrophobic silica was applied to the surface of talc by using differences in zeta potential after the surface charges of talc and hydrophobic silica had been adjusted with cationic and anionic surfactants, respectively. The resulting inorganic pigment complex was composed of talc whose surface is coated hydrophobic silica to the thickness of $1{\mu}m$ or less, which developed an effective hydrophobic property. Zeta potential was measured to analyze the surface charge of an inorganic pigment, and FT-IR, used to check the functional group of a surfactant, was applied to treat the surface of the pigment. The surface of the inorganic pigment complex was observed employing SEM, EDS, and FIB, while its structure was confirmed with XRD and FT-IR.

Manipulation of Surface Carboxyl Content on TEMPO-Oxidized Cellulose Fibrils

  • Masruchin, Nanang;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.613-627
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    • 2015
  • Simple methods of conductometric titration and infrared spectroscopy were used to quantify the surface carboxyl content of cellulose fibrils isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. The effects of different cellulose sources, post or assisted-sonication oxidation treatment, and the amount of sodium hypochlorite addition on the carboxyl content of cellulose were reported. This study showed that post sonication treatment had no influence on the improvement of surface carboxyl charge of cellulose macrofibrils (CMFs). However, the carboxyl content increased for the isolated cellulose nanofibrils (CNFs). Thus the carboxyl content of CNFs is different from those of their corresponding bulk oxidized cellulose and CMFs. Filter paper as a CNF source imparted a higher surface charge than did hardwood bleached kraft pulp (HWBKP) and microcrystalline cellulose (MCC). It was considered that the crystallinity and microstructure of the initial cellulose affected oxidation efficiency. In addition, the carboxyl content of cellulose was successfully controlled by applying sonication treatment during the oxidation reaction and adjusting the amount of sodium hypochlorite.