• Title/Summary/Keyword: sulfur gas

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Removal of High Strength Hydrogen Sulfide Gas using a Bioreactor Immobilized with Acidithiobacillus ferrooxidans and a Chemical Absorption Scrubber (Acidithiobacillus ferrooxidans를 고정화한 생물반응기와 흡수탑을 이용한 고농도 황화수소 제거)

  • Ryu, Hui-Uk
    • Microbiology and Biotechnology Letters
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    • v.32 no.4
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    • pp.328-333
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    • 2004
  • To treat a waste gas containing a high strength H2S, the two-stages microbial desulfurization process that conof a bioreactor immobilized with Acidithiobacillusferrooxidans and a chemical absorption scrubber has was proposed. After 4 times repeat of batch cultures, the immobilized bioreactor has been stabilized and the rate of iron oxidation reached 0.89 kg . $m^{-3}{\cdot}m^{-1}$ at steady state. The two-stages microbial desulfurization prowas able to be operated for a long term over 54 days. The removal efficiencies of H2S were 97-99% at a space velocity of 70 h-I and a inlet concentration of 37,000 ppmv. The maximum elimination capacity of H2S was approximately 3.3 kg S . $m^{-3}{\cdot}m^{-1}$. In the bioractor, the concentrations of the $Fe^{3+}$ and the immobilzed cell were constantly maintained during the desulfurization.

Studies on the $N_2/SF_6$ Permeation Behaviors Using the Polyethersulfone Hollow Fiber Membranes (폴리이서설폰 중공사 막을 이용한 $N_2/SF_6$ 투과거동에 관한 연구)

  • Lee, Hyung-Keun;Kim, Dae-Hoon;An, Young-Mo;Jo, Hang-Dae;Park, Jong-Soo
    • Membrane Journal
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    • v.19 no.3
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    • pp.244-251
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    • 2009
  • In this research the polyethersulfone hollow fiber membrane was used to separate Sulfur Hexafluoride ($SF_6$) which is the one of the six greenhouse gases from Air ($N_2$). The effects of the non-solvent (Acetone, Ethanol) type, air-gap and post-treatment (surface silicon coating) were investigated by the structure and performance of the membranes. The structure change of the membrane was examined by scanning electron microscope. The single gas permeation using $N_2$, $SF_6$ through the membrane surface coated with silicon showed maximum 7.64 perm-selectivity improved 3.4 times.

Study of High Temperature Corrosion Behavior of Fe-Cr Steel in Sewage Sludge-(SO2-O2-H2O-bal. CO2) mixed Gas Environment (하수슬러지-(SO2-O2-H2O-bal. CO2) 혼합 가스 분위기에서 Fe-Cr 강의 고온부식거동 연구)

  • Kim, Min Jung;Park, Joo Chang;Ryu, In Sun
    • Journal of the Korean institute of surface engineering
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    • v.53 no.2
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    • pp.72-79
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    • 2020
  • Two Fe-Cr steels of T22 steel and STS430 steel were corroded at 650 and 750℃ for 100hr in sewage sludge-(0.3% SO2-6% O2-10% H2O-balance CO2) mixed gas environment. T22 steel corroded faster than STS430, indicating that the Cr content significantly influence the corrosion rates. T22 formed thick and non-protective Fe2O3 as the major oxide and Fe3O4 as the minor one. With an increase in corrosion temperature, their corrosion rates increased, being accompanied with formation of pores and cracks in the thickened oxide scales that were non-adherent. STS430 steel formed Fe2O3, Fe3O4 as the outer scale and (Fe, Cr)-O as the inner layer by which its corrosion rate is greatly reduced. Both the T22 and STS430 steel samples formed multi-layered scales by outward diffusion of Fe ions and inward diffusion of oxygen and sulfur ions at high-temperature more than 650℃.

Reaction of Natural Manganese Dioxide with Hydrogen Sulfide at High-Temperature (고온에서 천연산 망간광석과 황화수소의 반응특성)

  • Shon, Byung-Hyun;Oh, Kwang-Joong;Kim, Young-Sick
    • Clean Technology
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    • v.2 no.1
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    • pp.69-79
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    • 1996
  • Sulfur emission control in coal gasification plants implies the removal of $H_2S$ from the fuel gas in the gas clean-up system. In this study, the effects of particle size of sorbents, temperature of sulfidation and sorbent characteristics on the $H_2S$ removal efficiency of manganese ore were investigated. Experimental results showed that the removal efficiency of $H_2S$ was optimum when the temperature was about $700^{\circ}C$. And that the smaller particle size, the higher the $H_2S$ removal efficiency, but that was not effective very much. As the temperature increases, the reactivity of sorbents has lowered because agglomeration of sorbents increased the intraparticle transport resistance. This phenomenon was confirmed by SEM photographs. The equilibrium ratio ($P_{H_2O}/P_{H_2S}$) obtained by experiments is represented as a ${\log}(P_{H_2O}/P_{H_2S})=5653/T-3.7909$. It was showed that the natural manganese ore could be used as a sorbent because its capacity for $H_2S$ removal is equivalent to the eariler developed sorbents.

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Ionic Liquids as a SO2 Absorption Media (이온성액체 기반 SO2 흡수제 개발 동향)

  • Choi, Ji-Shik;Johari, Suzaimi;Lee, Sang-Deuk;Lee, Hyun-Joo
    • Clean Technology
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    • v.18 no.1
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    • pp.22-30
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    • 2012
  • Separation of $SO_2$ from the flue gases of fossil fuel power plants are important issue because of its strong environmental impact. Industrially, $SO_2$ is being removed with a slurry of limestone, lime or aqueous caustic soda. However, these scrubbing processes possess several drawbacks such as the generation of huge amount of wastewater and the production of metal salts. Recently, ionic liquids have gained increasing interest as an absorbent for acid gas, $CO_2$ and $SO_2$. In this review, we have introduced the recent progress of ionic liquids as a $SO_2$ absorbent.

Quantitative Analysis of Allylmethyl Sulfide, Dimethyl Disulfide, and Dipropyl Sulfide in Biopesticides Containing Allium sativum Extract Using Gas Chromatography Mass Spectrometry-Head Space Sampler (Head-space GC-MS를 활용한 마늘추출물 함유 유기농자재 중 Allylmethyl Sulfide, Dimethyl Disulfide 및 Dipropyl Sulfide 분석)

  • Lim, Sung-Jin;Oh, Young-Tak;Kim, Jin-Hyo;Choi, Geun-Hyoung;Park, Byung-Jun
    • Korean Journal of Environmental Agriculture
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    • v.34 no.3
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    • pp.217-222
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    • 2015
  • BACKGROUND: Garlic (Allium sativum) contains polyphenols and sulfur compounds that are recognized as antioxidant, antithrombotic, anticancer, antibacterial, antimicrobial, nematicidal, and insecticidal activity. For this reason, the Environmentally-friendly Agriculture Promotion Act allowed the garlic extract as commercial biopesticide material for crop protection, nine commercial biopesticides containing A. sativum extract have been marketed in Korea. METHODS AND RESULTS: The determination of allylmethyl sulfide (AMS), dimethyl disulfide (DMDS), and dipropyl sulfide (DPS) in biopesticides containing A. sativum extract was developed and validated by gas chromatography (GC) mass spectrometry (MS) with head-space sampler. The developed method was validated, and the limit of quantification (LOQ) and recovery rates of AMS, DMDS, and DPS were 0.08, 0.32, and 0.09 mg/L and 90.3-91.3, 86.2-88.3, and 87.6-89.5%, respectively. From the nine commercial biopesticide samples, contents of AMS, DMDS, and DPS were analyzed using the developed method and results showed

A Study on the Property and Performance Characteristics of Different Kind Engine Oil by Endurance Test of Heavy-duty Diesel Engine (대형 디젤엔진 내구 시험에 의한 다른 종류 엔진오일의 물성 및 성능 특성에 관한 연구)

  • Lee, Minho;Kim, Jeonghwan;Song, Hoyoung;Kim, Giho;Ha, Jonghan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.48-56
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    • 2014
  • Engine oil is an oil used for lubrication of various internal combustion engines. The main function is to reduce wear on moving parts; it also cleans, inhibits corrosion, improves sealing, and cools the engine by carrying heat away from moving parts. In engines, there are parts which move against each other. Otherwise, the friction wastes the useful power by converting the kinetic energy to heat. Those parts were worn away, which could lead to lower efficiency and degradation of the engine. It increases fuel consumption, decreases power output, and can induce the engine failure. This study was conducted to evaluate the relation between engine oil property changes and engine performance for the diesel engine. This test was performed by using 12L, 6 cylinder, heavy duty engines. Low SAPS 10W30 engine oil (two type engine oils) was used. Test procedure and method was in accordance with the modified CEC L-57-T97 (OM441LA) method. In this study, TAN, TBN, KV and metal components, engine power, blowby gas, A_F were presented to evaluate the relation with engine oil property changes and engine performance. TAN, TBN, KV and metal We found that the components were generally increased but engine performance did not change. This results mean that property changes did not affect on engine performance because those were not enough to affect engine performance.

Enhanced Resistance to Sulfur Dioxide Gas in Transgenic Petunia by Stacking both SOD2 and NDPK2 Genes (SOD2와 NDPK2 유전자 집적에 의한 페튜니아의 아황산가스 저항성 증진)

  • Lee, Su Young;Cheon, Kyeong-Seong;Kim, So Young;Kwon, O Hyeon;Lee, Hye Jin;Kim, Won Hee;Yoo, Bong Sik
    • Horticultural Science & Technology
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    • v.34 no.1
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    • pp.154-162
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    • 2016
  • The aim of this study was to develop a transgenic petunia with enhanced resistance to sulfur dioxide ($SO_2$) gas by stacking two genes, SOD2 and NDPK2, which are both known to confer resistance to abiotic stresses. The first-generation hybrids ($TF_1$) were obtained through reciprocal crosses between an SOD2-transgenic line SOD2-2-1-1-35($T_4$)[S($T_4$)] and an NDPK2-transgenic line NDPK2-7-1($T_2$)[N7-1($T_2$)]. Approximately 32.1-73.0% of the first-generation hybrids ($TF_1$) carried both SOD2 and NDPK2 genes. These hybrids showed 2.6 and 5.1 times less damage than hybrids carrying only SOD2 or NDPK2 genes, respectively, when they were treated with $SO_2$ gas at 30 ppm. This confirmed that the heterozygous hybrids were more resistant to $SO_2$ than the hybrids carrying either one of the resistance genes. Second-generation hybrids ($TF_2$) were obtained by selfing the $TF_1$ individuals. We confirmed the expression of the stacked genes in the $TF_2$ hybrids by phenotypic observation of their response to $SO_2$ gas at 30 ppm as well as using RT-qPCR and photosynthetic efficiency.

Optimization and Flavor Quality of Enzymatic Hydrolysate from Dark Muscle of Skipjack

  • Jang, H.J.;Kim, M.C.;Jung, E.M.;Shin, E.C.;Lee, S.H.;Lee, S.J.;Kim, S.B.;Lee, Y.B.
    • Preventive Nutrition and Food Science
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    • v.10 no.1
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    • pp.11-16
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    • 2005
  • Enzymatic hydrolysis of dark muscle of skipjack was optimized by using response surface methodology. Three factors of independent values were pH (4.2 to 9.8), time (0.6 to 3.4 hrs) and temperature (34℃ to 76℃), and independent values were optical density and brix. The optimum conditions for enzymatic hydrolysis were pH 7.0 to 8.0, 55℃ and 3 hrs. The headspace volatile compounds of reaction flavors using the enzymatic hydrolysate, cysteine and xylose were identified by using the combination of a canister system, gas chromatography and mass selective detector. Among 67 compounds, we identified 8 sulfur-containing compounds and 7 furans which were thought to be highly related to meat-like flavors.

Simultaneous Removal Characteristics of Particulate and Elemental Mercury in Convergence Particulate Collector (융합형여과집진장치에서의 먼지입자와 원소수은의 제거 성능 특성)

  • Park, Young Ok;Jeong, Ju Yeong
    • Particle and aerosol research
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    • v.6 no.4
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    • pp.173-183
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    • 2010
  • The high temperature pleated filter bags which were used during this study were made of pleated nonwoven fabric of heat and acid resistant polysulfonate fibers which can withstand the heat up to $300^{\circ}C$ and have a filtration area which is 3 to 5 times larger than the conventional round filter bags. Cartridge module packed with 3 kind of the sulfur impregnated activated-carbon based sorbents were inserted in the inner of the pleated filter bag. This type of pleated filter bag was designed to remove not only the particulate matter but also the gaseous elemental mercury. The electrostatic precipitator part can enhance the particulate removal efficiency and reduce the pressure drop of the pleated filter bag by agglomerated particles to form a more porous dust layer on the surface of the pleated bag which is increased the filter bag cleaning efficiency. In addition, the most of particles are separated from the flue gas stream through the cyclone and the electrostatic precipitator part which were installed at the lower part and main body part of the convergence particulate collector, respectively. Thus reduce particulate loading of the high temperature pleated filter bags were applied in this study to analyze the removal characteristics of particulate matter and gaseous elemental mercury.