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http://dx.doi.org/10.5338/KJEA.2015.34.3.28

Quantitative Analysis of Allylmethyl Sulfide, Dimethyl Disulfide, and Dipropyl Sulfide in Biopesticides Containing Allium sativum Extract Using Gas Chromatography Mass Spectrometry-Head Space Sampler  

Lim, Sung-Jin (Chemical Safety Division, Agro-Food Safety & Crop Protection Department, National Academy of Agricultural Science, Rural Development Administration)
Oh, Young-Tak (Chemical Safety Division, Agro-Food Safety & Crop Protection Department, National Academy of Agricultural Science, Rural Development Administration)
Kim, Jin-Hyo (Chemical Safety Division, Agro-Food Safety & Crop Protection Department, National Academy of Agricultural Science, Rural Development Administration)
Choi, Geun-Hyoung (Chemical Safety Division, Agro-Food Safety & Crop Protection Department, National Academy of Agricultural Science, Rural Development Administration)
Park, Byung-Jun (Chemical Safety Division, Agro-Food Safety & Crop Protection Department, National Academy of Agricultural Science, Rural Development Administration)
Publication Information
Korean Journal of Environmental Agriculture / v.34, no.3, 2015 , pp. 217-222 More about this Journal
Abstract
BACKGROUND: Garlic (Allium sativum) contains polyphenols and sulfur compounds that are recognized as antioxidant, antithrombotic, anticancer, antibacterial, antimicrobial, nematicidal, and insecticidal activity. For this reason, the Environmentally-friendly Agriculture Promotion Act allowed the garlic extract as commercial biopesticide material for crop protection, nine commercial biopesticides containing A. sativum extract have been marketed in Korea. METHODS AND RESULTS: The determination of allylmethyl sulfide (AMS), dimethyl disulfide (DMDS), and dipropyl sulfide (DPS) in biopesticides containing A. sativum extract was developed and validated by gas chromatography (GC) mass spectrometry (MS) with head-space sampler. The developed method was validated, and the limit of quantification (LOQ) and recovery rates of AMS, DMDS, and DPS were 0.08, 0.32, and 0.09 mg/L and 90.3-91.3, 86.2-88.3, and 87.6-89.5%, respectively. From the nine commercial biopesticide samples, contents of AMS, DMDS, and DPS were analyzed using the developed method and results showed
Keywords
Allium sativum; Allylmethyl sulfide; Dimethyl disulfide; Dipropyl sulfide; Head-space;
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