• Title/Summary/Keyword: sulfate immersion test

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Sulfate Resistance of Concrete using Ground Granulated Blast-furnace Slag for Recycling

  • Moon, Han-Young;Lee, Seung-Tae;Kim, Hong-Sam
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.508-513
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    • 2001
  • Recently, ground granulated blast-furnace slag (GGBFS) has been increasingly used as additive for concrete. Many researchers reported that concrete using GGBFS had a better resistance under severe environments, such as marine or sulfate-rich soils, than Portland type cement concrete. The aim, therefore, of this study is to evaluate on the effectiveness of concrete using GGBFS when the concrete exposes to sulfate-rich environment. The detailed items for experiments show 2 series consisted of sulfate immersion test with mortar and sulfate diffusion test with concrete. The sulfate immersion test was performed for 400 days and contained reduction of compressive strength, length change and XRD analysis. For sulfate diffusion test, sulfate ions diffusivity was calculated on tile consideration of electrochemical theory by the diffusion cell test. As the results of this study, it was found that the concrete using GGBFS as additive was superior to portland type cement concrete. Consequently, the use of concrete with GGBFS for recycling may expect the durable and economical benefits.

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Evaluation on the Sulfate Attack Resistance of Shotcrete with Aluminate Accelerator (알루미네이트계 급결제를 사용한 숏크리트의 황산염침식 저항성 평가)

  • Kim, Seoung-Su;Kim, Hong-Sam;Lee, Gyu-Phil;Kim, Dong-Gyou;Yoon, Ha-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.527-530
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    • 2005
  • Shotcrete have become a deterioration which is used in the underground such as groundwater and soil in sulfate ion. Sulfate attack on concrete structures in service is not widespread, and the amount of laboratory-based research seems. to be disproportionately large. In this study, immersion test using $Na_2SO_4$ solution($1,2,5\%$) was performed to evalute the resistance of shotcrete. From the results of the immersion test for 112 days of exposure. In order to understand the deterioration mechanism due to seawater attack, test using scanning electron microscopy(SEM) analysis and X-ray diffraction showed that the deterioration mechanism due to sulfate attack in shotcrete.

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Evaluation on Sulfate Attack for Concrete Structures of Nuclear Power Plants (원자력발전소 콘크리트 구조물의 황산염 침식 평가)

  • Lee, Jong-Suk;Moon, Han-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.3
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    • pp.169-176
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    • 2004
  • The Mechanistic model, considering expansion stress, coefficient of diffusion etc. to time, is applied to predict the deterioration of concrete structures of the nuclear power plant(NPP) due to sulfate attack. Mix design for the test was three kinds of specified compressive strength 385, 280 and $210kgf/cm^2$ which are used to construct NPPs and cement was type I and V. The immersion test was performed with 10% $Na_2SO_4$ solution to cement type and strength for a year. The coefficient of diffusion on each concrete mix is calculated based on the results of immersion test, and it is used for predicting the sulfate attack of the concrete structures of NPP. The coefficient of diffusion of the target concrete ranged $0.5763{\sim}3.9002{\times}10^{-12}m^2/sec.$, and the sulfate attack rate of concrete structures of the NPP was predicted as 0.1~7.1 mm/year.

A Study on the Sulfate Attack of Concrete Using in Crushed Aggregates (부순모래 콘크리트의 황산염해에 관한 연구)

  • Kim, Kwang-Yuil;Kim, Kang-Min;Beak, Dong-Il;Kim, Myung-Sik;Kim, Jong-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.217-220
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    • 2005
  • As this study is to test effects of sulfate attack on deterioration of concrete using in crushed aggregates. Besides tests have been carried out with concrete by river sand and crushed sand by fine sand, concrete mixes various proportions of slica fume and fly ash(up to 15$\%$ by weight fo cement) were prepared and immersed in pure water, sodium sulfate solution for 28 and 60days. Test on the change in the weight and compressive strength of concrete according to the duration of immersion time and the content of slica fume and fly ash was performed.

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Influence of Cement types on the Resistance to Acid and Sulfate (산 및 황산염 저항성에 미치는 시멘트 종류의 영향)

  • Park, Jae-Im;Bae, Su-Ho;Yu, Kyung-Geun;Lee, Kwang-Myong;Cha, Soo-Won;Chol, Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.421-424
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    • 2008
  • The purpose of this experimental research is to investigate the influence of cement types on the resistance to acid and sulfate. For this purpose, concrete specimens with three types of cement such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) were made for water-binder(W/B) ratios of 32% and 43%, and then according to JSTM C 7401, the appearance change and ratio of mass change of them were estimated through the immersion tests by 5% sulfuric acid, 10% sodium sulfate, and 10% magnesium sulfate solution, respectively. It was observed from the test result that the resistance against acid and sulfate increased with decreasing W/B ratio and those of BBC and TBC concretes were better than the case of OPC concrete from immersion tests of 91 days.

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Resistance to Acid and Sulfate of Concrete Containing Mineral Admixtures (광물질 혼화재를 혼입한 콘크리트의 산 및 황산염 저항성)

  • Park, Jae-Im;Bae, Su-Ho;Lee, Kwang-Myong;Cha, Soo-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.281-282
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    • 2009
  • The purpose of this experimental research is to investigate the influence of mineral admixtures on the resistance to acid and sulfate. For this purpose, concrete specimens with types of mineral admixtures such as ground granulated blast-furnace slag, fly ash, and silica fume were made for water-binder ratios of 32% and 43%. It was observed from the test result that the resistance against acid and sulfate of the concretes containing mineral admixtures were much better than the case of plain concrete from immersion tests of 182 days.

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Sea Water Resistance of the Concrte Deteriorated by Repeat of Immersing and Drying in Sea Water (해수의 건습반복 촉진열화에 따른 콘크리트의 내해수성)

  • 박춘근;김병권;최재웅;고만기
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.307-312
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    • 1997
  • The sea water resistance of cement and concrete must be compared when it used for construction in the ocean. The sea water resistance of the concrete specimens using three types of cements such as ordinary Portland cement, sulfate resistance Portland cement, blastfurnace slag cement were studied. In this study, an accelerated test for access sea water resistance by subjecting the concrete specimens to repeated cycles of concentrated sea water immersion and hot wind drying was employed. This study proved that sulfate resistance Portland cement had higher resistance for sea water.

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Sulfate Attack Resistance of Crushed Sand Cement Mortars Containing Mineral Admixture (광물질 혼화재료를 혼입한 부순모래 시멘트 모르터의 황산염 침해 저항성)

  • Kim, Myung-Sik;Jang, Hui-Suk;Beak, Dong-Il;Kim, Kang-Min
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.821-824
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    • 2006
  • As this study is to estimate long term resistance of cement mortars using crushed sand under chemical attacks. Besides tests have been carried out with cement mortars by river sand and crushed sand by fine sand, cement mortars mix various proportions of silica fume and fly ash(up to 15% and 50% by weight for cement) were prepared and immersed in pure water, sodium sulfate solution, magnesium sulfate solution, seawater for 28days, 90days, 180days, 365days. Test on the change in the weight and compressive strength of cement mortars according to the duration of immersion time and the content of silica fume and fly ash was performed.

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Chemical Attack Resistance Characteristics of Cement Mortars U sing in Crushed Sand (부순모래를 사용한 시멘트 모르타르의 화학적 침해 저항 특성)

  • Kim Kang Min;Baek Dong Il;Kim Myung Sik;Jang Hui Suk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.519-522
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    • 2005
  • As this study is to test effects of chemical attack on deterioration of cement mortars using in crushed sand. Besides tests have been carried out with cement mortars by river sand and crushed sand by fine sand, cement mortars mix various proportions of slica fume and fly ash(up to $15\%$ and $50\%$ by weight for cement) were prepared and immersed in pure water, sodium sulfate solution, magnesium sulfate solution, seawater for 28days. Test on the change in the weight and compressive strength of cement mortars according to the duration of immersion time and the content of slica fume and fly ash was performed.

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A Study on the Adhesion Improvement of Immersion Copper Coatings using Complexing Agent (착화제를 이용한 치환동 도금층의 밀착력 향상에 관한 연구)

  • Koo, Seokbon;Jeon, Jumi;Hur, Jinyoung;Lee, Hongkee
    • Journal of the Korean institute of surface engineering
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    • v.48 no.1
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    • pp.1-6
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    • 2015
  • Amino-carboxyl acid as a complexing agent in acid copper sulfate solution was utilized to improve the adhesion of immersion copper layer for steel wire. According to the tape test results, regardless of alloy composition of the wire, the adhesion of immersion copper layer was improved with the addition of amino-carboxyl acid. The incorporation of H and Fe in the plating layer was analyzed by TOF-SIMS. The H and Fe were detected at the entire coating layer without any addition of amino-carboxyl acid. However, with addition of amino-carboxyl acid, the H and Fe were scarcely detected at the coating layer.