• Title/Summary/Keyword: substrate effects

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Sidewall effect in a stress induced method for Spontaneous growth of Bi nanowires

  • Kim, Hyun-Su;Ham, Jin-Hee;Lee, Woo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.95-95
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    • 2009
  • Single-crystalline Bi nanowires have motivated many researchers to investigate novel quasi-one-dimensional phenomena such as the wire-boundary scattering effect and quantum confinement effects due to their electron effective mass (~0.001 me). Single crystalline Bi nanowires were found to grow on as-sputtered films after thermal annealing at $270^{\circ}C$. This was facilitated by relaxation of stress between the film and the thermally oxidized Si substrate that originated from a mismatch of the thermal expansion. However, the method is known to produce relatively lower density of nanowires than that of other nanowire growth methods for device applications. In order to increase density of nanowire, we propose a method for enhancing compressive stress which is a driving force for nanowire growth. In this work, we report that the compressive stress can be controlled by modifying a substrate structure. A combination of photolithography and a reactive ion etching technique was used to fabricate patterns on a Si substrate. It was found that the nanowire density of a Bi film grown on $100{\mu}m{\times}100{\mu}m$ pattern Si substrate increased over seven times higher than that of a Bi sample grown on a normal substrate. Our results show that density of nanowire can be enhanced by sidewall effect in optimized proper pattern sizes for the Bi nanowire growth.

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Detergency of PET Film Having Various Surface Free Energy : Part II The Work of Detergency and the Washability of Triolein from MAA Grafted PET Film (Polyethylene terephthalate 필름의 표면에너지 변화에 따른 세척성(제이보) MAA그라프트 PET필름에서 triolein의 세척일과 세척성)

  • Chung Hae-Won;Kim Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.12 no.2 s.27
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    • pp.225-235
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    • 1988
  • The effects of surface free energy of substrates on the soiling and on the detergency of the oily soil were studied. The surface tension consisted of dispersion force and polar force components of substrate, oily soil and surfactant solutions were calculated by extended Fowkes' equation. From these values, work of adhesion($W_a$), work of detergency($W_D$), ana residual work of detergency($W_{D,R}$) were calculated. The correlations between these theoretical values of the works and detergency were discussed. MAA grafted PET film was used as substrate, triolein as oily soil and nonylphenol polyoxyethylene ether(NPE) having various mole numbers of oxyethylene adducts and dodecylbenzene sulfonate (DBS) as surfactants. Detergency was estimated by means of radioactive tracer method using $C^{14}-triolein$. The results showed that $W_a$ was decreased with the increase of surface free energy of substrate. In water, $W_D\;and\;W_{D,R}$ were decreased and detergency of tiolein was increased with the increase of surface free energy of substrate. In surfactant solutions, the lower the surface free energy of substrate and the lower oxyethylene adducts of NPE were the more effective on detergency. The detergency of DBS solution was the lowest in the case of ungrafted PET film, but even small increase in surface free energy by grafting showed much increase in detergency.

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Behavioral Response of Tubifex tubifex to Changes of Water Temperature and Substrate Composition (수온 및 하상 변화에 대한 참실지렁이 (Tubifex tubifex)의 행동 반응)

  • Kang, Hyejin;Bae, Mi-Jung;Park, Young-Seuk
    • Korean Journal of Ecology and Environment
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    • v.50 no.3
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    • pp.355-361
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    • 2017
  • In this study, we investigated the response of freshwater oligochaete, Tubifex tubifex, to the water temperature changes and the differences of substrate composition in a laboratory condition. The changes of body shape were observed in a test cage according to the water temperature change ranging from $10^{\circ}C$ to $30^{\circ}C$ with $2^{\circ}C$ interval every 10 minutes. The substrate preference was observed with four different substrate composition from silt-clay to coarse sand. Our results displayed that T. tubifex preferred substrates with the smallest particle size (<0.063 mm). The water temperature influenced on the activity and body shape of T. tubifex, showing low activity with the coiled and constricted body shapes at lower temperature and high activity with relaxed linear body shapes at higher temperature.

Durability of the Expanded Rice Hull as a Hydroponic Culture Medium (양액재배용 팽연화 왕겨의 적정 사용기간)

  • 임상현;김경희;안문섭;유근창
    • Journal of Bio-Environment Control
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    • v.10 no.2
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    • pp.106-110
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    • 2001
  • In an effort to evaluate the economic value and durability of the expanded rice hull as substrates, changes in the physical and chemical properties of material and plant growth in that substrate were studied. Using and electron microscope, the structure of used and new expanded rice hull substrate was examined. Considerable decomposition was found in the substrate which had been used one to three times. Compactness and lowered porosity in the used substrates were probably caused by decomposition. The results of cation analysis showed the possible destruction of cell wall of rice hulls. Abundant $Ca^{2+}$ in the substrates used for two to three times also indicated the possibility of decomposition. In tomato yield comparison, 15.2% more yield of tomato fruit in a new substrates indicated the negative effects of decomposition of one-time used substrates. Yield decreased in the substrates used for three times. if perlite substrates is used for three years before renewal and the cost of the perlite renewal is counted. 65.3% saving in the cost will be realized with the use of an expanded rice hull substrate. Another positive effect of the expanded rice hull substrate is the decrease of environmental contamination.n.

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Properties of Ga-doped ZnO transparent conducting oxide fabricated on PET substrate by RF magnetron sputtering (RF 마그네트론 스퍼터링 공정으로 PET 기판 위에 제조한 Ga-doped ZnO 투명전도막의 특성)

  • Kim, Jeong-Yeon;Kim, Byeong-Guk;Lee, Yong-Koo;Kim, Jae-Hwa;Woo, Duck-Hyun;Kweon, Soon-Yong;Lim, Dong-Gun;Park, Jae-Hwan
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.1
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    • pp.19-24
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    • 2010
  • The effects of $O_2$ plasma pretreatment on the properties of Ga-doped ZnO films on PET substrate were studied. GZO films were fabricated by RF magnetron sputtering process. To improve surface energy and adhesion between the PET substrate and the GZO film, $O_2$ plasma pretreatment process was used prior to GZO sputtering. As the RF power and the treatment time increased, the crystallinity increased and the contact angle decreased significantly. When the RF power was 100 W and the treatment time was 600 sec in $O_2$ plasma pretreatment process, the resistivity of GZO films on the PET substrate was $1.90{\times}10^{-3}{\Omega}-cm$.

Upcycling the Spent Mushroom Substrate of the Grey Oyster Mushroom Pleurotus pulmonarius as a Source of Lignocellulolytic Enzymes for Palm Oil Mill Effluent Hydrolysis

  • Yunan, Nurul Anisa Mat;Shin, Tan Yee;Sabaratnam, Vikineswary
    • Journal of Microbiology and Biotechnology
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    • v.31 no.6
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    • pp.823-832
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    • 2021
  • Mushroom cultivation along with the palm oil industry in Malaysia have contributed to large volumes of accumulated lignocellulosic residues that cause serious environmental pollution when these agroresidues are burned. In this study, we illustrated the utilization of lignocellulolytic enzymes from the spent mushroom substrate of Pleurotus pulmonarius for the hydrolysis of palm oil mill effluent (POME). The hydrolysate was used for the production of biohydrogen gas and enzyme assays were carried out to determine the productivities/activities of lignin peroxidase, laccase, xylanase, endoglucanase and β-glucosidase in spent mushroom substrate. Further, the enzyme cocktails were concentrated for the hydrolysis of POME. Central composite design of response surface methodology was performed to examine the effects of enzyme loading, incubation time and pH on the reducing sugar yield. Productivities of the enzymes for xylanase, laccase, endoglucanase, lignin peroxidase and β-glucosidase were 2.3, 4.1, 14.6, 214.1, and 915.4 U g-1, respectively. A maximum of 3.75 g/lof reducing sugar was obtained under optimized conditions of 15 h incubation time with 10% enzyme loading (v/v) at a pH of 4.8, which was consistent with the predicted reducing sugar concentration (3.76 g/l). The biohydrogen cumulative volume (302.78 ml H2.L-1 POME) and 83.52% biohydrogen gas were recorded using batch fermentation which indicated that the enzymes of spent mushroom substrate can be utilized for hydrolysis of POME.

Influence of Substrate Phase and Inclination Angle on Heat Transfer Characteristics in Vicinity of Hastelloy X Regions Deposited on S45C via Directed Energy Deposition (DED 공정을 이용한 S45C 위 Hastelloy X 분말 적층 시 기저부 상과 경사각이 적층부 인근 열전달 특성에 미치는 영향에 관한 연구)

  • Baek, Sun-Ho;Lee, Kwang-Kyu;Ahn, Dong-Kyu;Kim, Woo-Sung;Lee, Ho-Jin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.10
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    • pp.27-37
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    • 2021
  • The use of additive manufacturing processes for the repair and remanufacturing of mechanical parts has attracted considerable attention because of strict environmental regulations. Directed energy deposition (DED) is widely used to retrofit mechanical parts. In this study, finite element analyses (FEAs) were performed to investigate the influence of the substrate phase and inclination angle on the heat transfer characteristics in the vicinity of Hastelloy X regions deposited via DED. FE models that consider the bead size and hatch distance were designed. A volumetric heat source model with a Gaussian distribution in a plane was adopted as the heat flux model for DED. The substrate and the deposited powder were S45C structural steel and Hastelloy X, respectively. Temperature-dependent thermal properties were considered while performing the FEAs. The effects of the substrate phase and inclination angle on the temperature distributions and depth of the heat-affected zone (HAZ) in the vicinity of the deposited regions were examined. Furthermore, the influence of deposition paths on depths of the HAZ were investigated. The results of the analyses were used to determine the suitable phase and inclination angle of the substrate as well as the appropriate deposition path.

Influence of Substrate Concentration and Hydraulic Retention Time on the Hydrogen Production Using Anaerobic Microflora (혐기성 미생물을 이용한 수소생산에 있어서 기질농도 및 수리학적 체류시간의 영향)

  • Ko, In-Beom;Shin, Hang-Sik;Lee, Yong-Doo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.911-916
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    • 2006
  • The influence of substrate concentration and hydraulic retention time(HRT) on the hydrogen production by anaerobic microflora was investigated by conducting three series of continuous experiments the individual influences of substrate concentration and HRT. In series I, substrate concentration was increased from 3 to 27 g-glucose/L keeping HRT at 8 hr. Series II and III carried out same condition with series I at HRT of 16 hr and 24 hr, respectively. The effects of HRT and substrate concentration on the hydrogen production yield were analyzed by quadratic model. The maximum hydrogen production yield of 2.05 mol $H_2/mol$ glucose was found at the HRT of 9.6 hr and the substrate concentration of 15.4 g/L. The relationship between HRT and substrate concentration on hydrogen production yield as displayed a saddle shape in the response surface plot. Optimum HRT and substrate concentration are observed at in the range of 5 and 14 hr, at between 13 and 17 g/L, respectively, for the hydrogen production yield being 2 mol $H_2/mol$ glucose. The concentrations of organic acids increased with the increase of the amount of glucose consumption. Acetic acid and butyric acid were the main by-products from the glucose degradation.

Cometabolic Biodegradation of Fuel Additive Methyl tert-Butyl Ether(MTBE) by Propane- and Butane-Oxidizing Microorganisms (프로판 및 부탄 이용 미생물에 의한 휘발유 첨가제 MTBE의 동시분해)

  • 장순웅
    • Journal of Soil and Groundwater Environment
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    • v.8 no.4
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    • pp.45-52
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    • 2003
  • A gas-substrate degrading bacterium, Nocardia SW3, was isolated from the gasoline contaminated aquifer using propane and butane as carbon and energy sources. We have examined the effects of substrate concentration, temperature and pH on the gas substrate degradation as well as MTBE cometabolic degradation. The result for the effect of substrate concentration showed that the maximum degradation rates of propane and butane were 30.6 and 25.4 (n㏖/min/mg protein) at 70 $\mu$㏖, respectively. The optimum temperature and pH for the degradation of gas substrate were $30^{\circ}C$ and 7, respectively. Substrate degradation activity, however, was still active in broad range of pH from 5 to 8 and temperature between $15^{\circ}C$and$35^{\circ}C$. The degradation activity of Nocardia SW3 for the MTBE was similar to the both substrates. The observed maximal transformation yields ($T_y$) were 46.7 and 35.0 (n㏖ MTBE degraded $\mu$㏖ substrate utilized), and the maximal transformation capacities ($T_c$) were 320 and 280 (n㏖MTBE degraded/mg biomass used) for propane and butane oxidizing activity on MTBE, respectively. And also, TBA was detected as by-product of MTBE and it was continuously degraded further.

The Study of Steering Effect in Multilayer Growth (두꺼운 박막 성장시 Steering 효과 연구)

  • Seo J.;Kim J.S.
    • Journal of the Korean Vacuum Society
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    • v.15 no.4
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    • pp.410-420
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    • 2006
  • The dynamic effects, such as the steering and the screening effects during deposition on an epitaxial growth is studied by kinetic Monte Carlo simulation. In the simulation, we incorporates molecular dynamic simulation to rigorously take the interaction of the deposited atom with the substrate atoms into account, We find three characteristic features of the surface morphology developed by grazing angle deposition: (1) enhanced surface roughness, (2) asymmetric mound, and (3) asymmetric slopes of mound sides, Regarding their dependence on both deposition angle and substrate temperature, a reasonable agreement of the simulated results with the previous experimental ones is found. The characteristic growth features by grazing angle deposition are mainly caused by the inhomogeneous deposition flux due to the steering and screening effects, where the steering effects play the major role rather than the screening effects. Newly observed in the present simulation is that the side of mound in each direction is composed of various facets instead of all being in one selected mound angle even if the slope selection is attained, and that the slope selection does not necessarily mean the facet selection.