• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.22-28
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• 2019

To maximize the oxygen evolution reaction (OER) in the electrolysis of water, nano-grade $IrO_2$ powder with a low specific surface was prepared as a catalyst for a solid polymer electrolyte (SPE) system, and a membrane electrode assembly (MEA) was prepared with a catalyst loading as low as $2mg\;cm^{-2}$ or less. The $IrO_2$ catalyst was composed of heterogeneous particles with particle sizes ranging from 20 to 70 nm, having a specific surface area of $3.8m^2g^{-1}$. The anode catalyst layer of about $5{\mu}m$ thickness was coated on the membrane (Nafion 117) for the MEA by the decal method. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) confirmed strong adhesion at the interface between the membrane and the catalyst electrode. Although the loading of the $IrO_2$ catalyst was as low as $1.1-1.7mg\;cm^{-2}$, the SPE cell delivered a voltage of 1.88-1.93 V at a current density of $1A\;cm^{-2}$ and operating temperature of $80^{\circ}C$. That is, it was observed that the over-potential of the cell for the oxygen evolution reaction (OER) decreased with increasing $IrO_2$ catalyst loading. The electrochemical stability of the MEA was investigated in the electrolysis of water at a current density of $1A\;cm^{-2}$ for a short time. A voltage of ~2.0 V was maintained without any remarkable deterioration of the MEA characteristics.

• Membrane Journal
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• v.29 no.3
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• pp.183-189
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• 2019

Amphiphilic PCZ-r-PEG random copolymer assisted solvothermal process is used to prepare mesoporous $TiO_2$ microspheres generated from nanoparticles by self-assembly method. Synthesized PCZ-r-PEG is characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), gel permeation chromatography (GPC) and transmission electron microscopy (TEM). The mesoporous $TiO_2$ are prepared by PCZ-r-PEG, glucose, water in tertrahydrofuran solution at $150^{\circ}C$ for 12 h and the $TiO_2$ microspheres are calcined at $550^{\circ}C$ for 30 min to further crystallize and organic residue are removed. Morphology and crystallization phase is characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) respectively. The mesoporous $TiO_2$ crystallized in pure anatase phase with diameter of $300{\pm}20nm$.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.7
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• pp.84-90
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• 2022

The purpose of the cover housing component of a car door is to protect the terminals of the plug housing that connects the electric control unit on the door side to the car body. Therefore, for a smooth assembly with the plug housing and to prevent contaminants from penetrating into the gaps that occur after assembly, the warpage of the cover housing should be minimized. In this study, to minimize the warpage of the cover housing, optimization was performed for design factors related to the mold and processes based on the injection molding simulation. These design factors include gate location, gate diameter, injection time, resin temperature, mold temperature, and packing pressure. To optimize the design factors, Taguchi's approach to the design of experiments was adopted. The optimal combination of the design factors and levels that minimize warpage was predicted through L₁₈-orthogonal array experiments and main effects analysis. Moreover, the warpage under the optimal design was estimated by the additive model, and it was confirmed through the simulation experiment that the estimated result was quite consistent with the experimental result. Additionally, it was found that the warpage under the optimal design was significantly improved compared to both the warpage under the initial design and the best warpage among the orthogonal array experimental results, which numerically decreased by 36.9% and 23.4%, respectively.

• Nuclear Engineering and Technology
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• v.53 no.6
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• pp.1834-1845
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• 2021

Liquid lead-bismuth cooled fast reactor is one of the most promising reactor types among the fourth-generation nuclear energy systems. The flow and heat transfer characteristics of lead-bismuth eutectic (LBE) are completely different from ordinary fluids due to its special thermal properties, causing that the traditional Reynolds analogy is no longer recommended and appropriate. More accurate turbulence flow and heat transfer model for the liquid metal lead-bismuth should be developed and applied in CFD simulation. In this paper, a specific CFD solver for simulating the flow and heat transfer of liquid lead-bismuth based on the k - 𝜀 - k_𝜃 - 𝜀_𝜃 model was developed based on the open source platform OpenFOAM. Then the advantage of proposed model was demonstrated and validated against a set of experimental data. Finally, the simulation of LBE turbulent flow and heat transfer in a 7-pin wire-wrapped rod bundle with the k - 𝜀 - k_𝜃 - 𝜀_𝜃 model was carried out. The influence of wire on the flow and heat transfer characteristics and the three-dimensional distribution of key thermal hydraulic parameters such as temperature, cross-flow velocity and Nusselt number were studied and presented. Compared with the traditional SED model with a constant Pr_t = 1.5 or 2.0, the k - 𝜀 - k_𝜃 - 𝜀_𝜃 model is more accurate on predicting the turbulence flow and heat transfer of liquid lead-bismuth. The average relative error of the k - 𝜀 - k_𝜃 - 𝜀_𝜃 model is reduced by 11.1% at most under the simulation conditions in this paper. This work is meaningful for the thermal hydraulic analysis and structure design of fuel assembly in the liquid lead-bismuth cooled fast reactor.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.230-230
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• 2012

Graphene have showed promising performance as electrodes of organic devices such as organic transistors, light-emitting diodes, and photovoltaic solar cells. In particular, among various organic materials of graphene-based organic devices, pentacene has been regarded as one of the promising organic material because of its high mobility, chemical stability. In the bottom-contact device configuration generally used as graphene based pentacene devices, the morphology of the organic semiconductors at the interface between a channel and electrode is crucial to efficient charge transport from the electrode to the channel. For the high quality morphology, understanding of initial stages of pentacene growth is essential. In this study, we investigate self-assembly of pentacene molecules on graphene formed on a 6H-SiC (0001) substrate by scanning tunneling microscopy. At sub-monolayer coverage, adsorption of pentacene molecules on epitaxial graphene is affected by $6{\times}6$ pattern originates from the underlying buffer layer. And the orientation of pentacene in the ordered structure is aligned with the zigzag direction of the edge structure of single layer graphene. As coverage increased, intermolecular interactions become stronger than molecule-substrate interaction. As a result, herringbone structures the consequence of higher intermolecular interaction are observed.

• Journal of Institute of Convergence Technology
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• v.3 no.1
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• pp.51-54
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• 2013

Cadmium telluride(CdTe) nanowires were successfully synthesized from individual nanoparticles via self-assembly and the evolutionary process was investigated. The oxidation of tellurium ions on CdTe nanoparticles resulted in the organization of individual nanoparticle into twisted-nanoribbons. The nanoparticles self-assembled to twisted ribbons under light while nanoparticles under dark transformed to straight nanowires made of several layers of individual nanoparticles. The images of nanoribbons were analysed based on transmission electron microscopy and scanning electron microscopy. The photoluminescence was blue-shifted from 555 to 545nm.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.43-46
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• 2002

The HANARO, multi-purpose research reactor, 30 MWth open-tank-in-pool type, is under 24 MWth of power operation since it reached to the initial critical in February, 1995. Many useful experiments should be safely performed to activate the utilization of the HANARO, but there is a radioactive risk of using the HANARO. To reduce the risk, a test facility, which is not reacted by nuclear fuel, is being developed to simulate similar flow characteristics with the HANARO. This paper describes the computational flow analysis to determine each shape of simulating fuels for simulating the flow similarities of 36 elements hexagonal fuels assembly and 18 elements circulating fuels assembly loaded in HANARO. The shares of orifices were determined by the trial and error method and the structural integrities of them were verified by the finite element method assuming that the flow rate and pressure differences of reactor core are constant. The analysis results will be verified with the results of the flow test to be performed after the installation of this test facility.

• Transactions of Materials Processing
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• v.18 no.8
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• pp.607-616
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• 2009

There are three sub-processes associated with the assembly of the valve seat and cylinder head; heat fitting, cold fitting, and shrink fitting. In the heat fitting stage, the cylinder head is heated to a specified temperature and then squeezed toward the outer diameter of the valve seat. The cold fitting process cools the valve seat and safely squeezes it toward the inner diameter of cylinder head. However, these methods increased the installations & running cost and curtailed productivity. To address these problems, we analyzed the shrink fitting process using the contact pressure caused by fitting interference between the outer diameter of the valve seat and the inner diameter of the cylinder head. In this study, a closed form equation for predicting the contact pressure and fitting load is proposed. For quality control of the assembly line, principal factors of the shrink fitting process influenced in contact pressure were simulated by the FEM. Actual loads measured in the field showed good agreement with the results obtained by theoretical and finite element analysis.

• Korean Journal of Computational Design and Engineering
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• v.4 no.4
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• pp.327-338
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• 1999

In this paper, we propose the framework of an integrated design system as a CAD system of a new concept that can incorporate the design information. Current CAD systems are powerful in representing the shape of a product with solid models but cannot provide the design information that is used or created in designing the product. Therefore an integrated design system is proposed to enable the storage and usage of the design information in addition to the shape manipulation. In order to represent the design information, we define element object that represents design element such as a part, a sub-assembly or an assembly by using object-oriented methodology. The element object carries various design information such as design parameters, documents, catalogues, functions, and behaviors as well as shapes. By using the stored information, the system can provide a designer with some functions to assist design activity such as interrogating necessary information, setting design parameters and goals, and constructing constraints among design elements. A mailing system is also constructed among element objects to assist a collaborative design. In addition, an evolutionary design method using genetic algorithms is realized within the proposed framework.

• Journal of the Korean Society of Industry Convergence
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• v.7 no.2
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• pp.193-198
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• 2004

This is the dissertation of the study of design characteristics about the practical flexible manufacturing system (PFMS). The basic ideas to analyze the manufacturing system which is the automatically operated is dependant on the various manufacturing procedures in factory. PFMS is the very useful equipment for students and trainee of production lines. This system is composed of hardware and software sub systems i.e. control and test unit and personal computer with software. The PFMS can be developed with design concepts and approved the capability of first article with functional tests. The PFMS module will be very useful for the manufacturing drill system in universities and practical fields. The flexible manufacturing systems have various subsystems appropriated for the final manufacturing products. Therefore the systems have the various kinds of hard wares as well as softwares. We study the software for the practical flexible manufacturing system designed in the Halla University and specially the design concept and using specification of the SCARA (Selective Compliance Assembly Robot Arm) robot which is used for the movement of the product is analyzed and introduced in this dissertation.