• E2M - 전기 전자와 첨단 소재
• /
• 제10권3호
• /
• pp.239-246
• /
• 1997

The ZnO is stabilize dielectric constant over a broad temperature range because its addition makes the relaxation time short. In this study, the composite oxide material (B $a_{0.85}$ $Ca_{0.15}$)Ti $O_{3}$ was mixed by ZnO additive material and the dielectric polarization characteristics was studied. The relative density was over 90[%] at all specimen in the structural characteristics. Among of the specimen, the relative density of (B $a_{0.85}$ $Ca_{0.15}$)Ti $O_{3}$ with ZnO (0.4mol) has a 95[%]. The grain size of composite oxide material with an increasing ZnO increased and it was 1.0[.mu.m]-1.22[.mu.m]. In the electrical characteristics, the charge and discharge current was increased by ZnO addition. The dielectric relaxation time was increased by space charge polarization at above 110[.deg. C] and the dielectric relaxation time was fixed by space charge polarization of para-dielectric layer at below 110[.deg. C]. The dielectric relaxation time was maximum when the grain size was small. The dielectric relaxation time is decreased with an additive material ZnO and interface polarization, existing void at the grain and grain boundary. The remnant polarization is increased and the coercive electric field is decreased by ZnO.

• 한국자기공명학회논문지
• /
• 제18권1호
• /
• pp.15-23
• /
• 2014

The structural properties and relaxation processes of $MCsSO_4$ (M = Na, K, or Rb) crystals were investigated by measuring the NMR spectra and spin-lattice relaxation rates $1/T_1$ of their $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei. According to the NMR spectra, the $MCsSO_4$ crystals contain two crystallographically inequivalent sites each for the M and Cs ions. Further, the relaxation rates of all these nuclei do not change significantly over the investigated temperature range, indicating that no phase transitions occur in these crystals in this range. The variations in the $1/T_1$ values of the $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei in these three crystals with increasing temperature are approximately proportional to $T^2$, indicating that Raman processes may be responsible for the relaxation. Therefore, for nuclear quadrupole relaxation of the $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei, Raman processes with n = 2 are more effective than direct processes.

• 한국전산구조공학회:학술대회논문집
• /
• 한국전산구조공학회 1999년도 봄 학술발표회 논문집
• /
• pp.268-275
• /
• 1999

The purpose of this study is to propose the method of determining the initial pneumatic membrane structures surface and stresses and displacements. Tension structure such as pneumatic membrane structures is stabilized by their initial prestress and air pressure. The process to find initial structural overall shape of tension structures produced by initial prestress called shape finding. One of the most important factor for the design of membrane structures is to search initial smooth surface, because unlike steel or concrete building elements which resist loads in bending, all tension structure forces are carried within the surface by membrane stress. The result for initial surface of pneumatic membrane element and maximum displacement in large deformation in analysis is compared with well-known nonlinear numerical method such as Newton-raphson method and dynamic relaxation method

• 한국전산구조공학회:학술대회논문집
• /
• 한국전산구조공학회 2000년도 가을 학술발표회논문집
• /
• pp.331-338
• /
• 2000

In this paper, a non-linear finite element formulation for the spatial cable-net structures is simulated and using this formulation, the characteristics of structural behaviors for the elastic catenary cable are examined In the simulating procedure for the elastic catenary cable, nodal forces and tangential stiffness matrices are derived using catenary parameters of the exact solutions by a governing differential equation of catenary cable, cable self-weights and unstressed cable length. Dynamic Relaxation Method that considers kinetic damping is used for the structure analysis and Newton Raphson Method is used to verify the accuracy of solutions. In the analysis of two dimensional cable, the results obtain from the elastic catenary elements are shown more accurate than does of truss elements and in the case of spatial cable-net structures, Dynamic Relaxation Method is more stable to be converged than Newton Raphson Method.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2000년도 봄 한국섬유공학회 학술발표회 논문집(Proceedings of the Korean Textile Conference)
• /
• pp.77-80
• /
• 2000

• 한국자기공명학회논문지
• /
• 제17권1호
• /
• pp.24-29
• /
• 2013

The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.

• 전산구조공학
• /
• 제11권1호
• /
• pp.179-190
• /
• 1998

두개의 케이블요소를 이용한 3차원 케이블망의 정적 비선형 유한요소해석기법을 제시한다. 먼저, 공간 트러스요소와 탄성현수선 케이블요소(elastic catenary cable element)의 접선강도행렬과 질량행렬을 유도하는 과정을 간략히 요약한다. 지점 변위를 일으키고 자중을 받는 케이블망의 초기평형 상태를 결정하기 위하여, Newton-Raphson 반복법에 근거한 하중증분법과 현수케이블요소를 적용하는 경우에 viscous damping을 고려한 dynamic relaxation법을 제시한다. 또한 초기의 정적평형상태를 기준으로 추가하중에 대한 케이블망의 정적 비선형해석을 수행한다. 지점변위와 외력을 받는 케이블 구조에 대하여 비선형해석을 수행하고, 해석결과들을 기존의 문헌의 결과와 비교, 검토하므로써 본 논문에서 제시한 이론 및 해석방법의 타당성을 입증한다.

• 한국자기공명학회논문지
• /
• 제17권2호
• /
• pp.86-91
• /
• 2013

Detailed information about the structural nature of three-coordinate borons in ${\beta}-BaB_2O_4$ is obtained through $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR. The three-coordinate $BO_3$ of the two borons B(1) and B(2) in ${\beta}-BaB_2O_4$ were distinguished. The spin-lattice relaxation time in the laboratory frame $T_1$ for B(1) and B(2) slowly decreases with increasing temperature, whereas the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for B(1) and B(2), which differs from $T_1$, is nearly constant. The B(1) and B(2) of the two types were distinguished by $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR.

• Macromolecular Research
• /
• 제12권6호
• /
• pp.559-563
• /
• 2004

Both the ultrasonic velocity at 3 MHz and the absorption coefficient in the frequency range from 0.2 to 2 MHz were measured for aqueous solutions of poly(sodium 4-styrenesulfonate) over the concentration range from 5 to $25\%$ (by weight). The pulse echo overlap method was employed to measure the ultrasonic velocity over the temperature range from 10 to $90^{\circ}C;$ the high-Q ultrasonic resonator method was used for the measurement of the absorption coefficient at $20^{\circ}C.$ The velocities exhibited their maximum values at ca. 55, 59, 63, 67, and $71^{\circ}C.$ for the 25, 20, 15, 10, and $5\%$ solutions, respectively. The velocity increased with respect to the poly(sodium 4-styrene-sulfonate) concentration at a given temperature. A study of the concentration dependence of the both the relaxation frequency and amplitude indicated that the relaxation at ca. 200 kHz is related to structural fluctuations of the polymer molecules, such as the segmental motions of the polymer chains and that the relaxation at ca. 1 MHz resulted from the proton transfer reactions of the oxygen sites of $SO_3.$ Both the absorption and the shear viscosity increase upon increasing the polymer concentration, but they decrease upon increasing the temperature.

• 한국공간구조학회:학술대회논문집
• /
• 한국공간구조학회 2006년도 춘계 학술발표회 논문집 제3권1호(통권3호)
• /
• pp.58-65
• /
• 2006

대공간 구조 시스템의 대변형 거동 산정법으로 최근 동적이완법의 적용에 대한 연구가 진행되고 있다. 동적이완법에서는 접선 강성 매트릭스의 수식 계산이 필요하지 않고, 단지 벡터량을 이용함으로써 해로 수렴하며, 전체 계산 과정에서 강성 매트릭스는 필요하지 않다. 동적이완법의 이점을 평가하기 위해 많은 대공간 구조 시스템에 대해 적용하였고, 이는 대공간 구조 시스템의 후좌굴 거동을 추적하는데 있어서 동적이완법 사용의 타당성을 규명할 수 있다.